5-methyl-5-phenylnonanedinitrile | 63438-97-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-methyl-5-phenylnonanedinitrile
• CAS: 63438-97-1
• 化学式: C₁₆H₂₀N₂
• 分子量: 240.348
• InChiKey: CYCJDEQMGWRWBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-methyl-5-phenylnonanedinitrile 、 叔丁醇 在 氨 作用下， 以 水 为溶剂， 生成 5-cyclohexyl-5-methyl-1,9-nonanediamine
  参考文献：
  名称：

  US4288625

  摘要：

  公开号：

文献信息

• Polyamide from cycloaliphatic substituted nonane diamine
  申请人：Phillips Petroleum Company

  公开号：US04408037A1

  公开（公告）日：1983-10-04

  Aralkylenediamines such as 5-phenyl-5-methyl-1,9-nonanediamine, or cycloalkylalkylenediamines such as 5-cyclohexyl-5-methyl-1,9-nonanediamine, are polymerized with dicarboxylic acids such as adipic or azelaic acid, optionally with a tricarboxylic acid such as benzene tricarboxylic acid, to produce tough clear colorless polyamide resins useful for molding and fibers.

  阿拉基烷二胺（例如5-苯基-5-甲基-1,9-壬二胺）或环烷基烷二胺（例如5-环己基-5-甲基-1,9-壬二胺）与二羧酸（例如己二酸或癸二酸），可选地与三羧酸（例如苯三羧酸）共聚，生产出坚韧、透明、无色的聚酰胺树脂，适用于模塑和纤维制造。
• Polyamide resin from aralkylene diamine
  申请人：Phillips Petroleum Company

  公开号：US04465824A1

  公开（公告）日：1984-08-14

  Polyamides, prepared from aralkylenediamines, such as 5-phenyl-5-methyl-1,9-nonanediamine and dicarboxylic acids such as adipic or azelaic acid are tough, clear resins useful for molding and fibers.

  聚酰胺是由芳基亚烷二胺制备而成的，例如5-苯基-5-甲基-1,9-壬二胺和二羧酸，如己二酸或癸二酸，是坚韧、透明的树脂，适用于模塑和纤维制造。
• Polyamide from aralkylene diamine, dicarboxylic acid and tricarboxylic
  申请人：Phillips Petroleum Company

  公开号：US04465822A1

  公开（公告）日：1984-08-14

  Polyamides, prepared from aralkylenediamines such as 5-phenyl-5-methyl-1,9-nonanediamine and dicarboxylic acids such as adipic or azelaic acid, optionally with a tricarboxylic acid for branching such as benzene tricarboxylic acid, are tough, clear resins useful for molding and fibers.

  聚酰胺是从芳基亚乙二胺（例如5-苯基-5-甲基-1,9-壬二胺）和二羧酸（例如己二酸或癸二酸）制备而成的，可选用三羧酸（例如苯三羧酸）进行分支，制备出的聚酰胺是坚韧、透明的树脂，适用于模塑和纤维制品。
• Copolyamide from cycloaliphatic substituted nonane diamine
  申请人：Phillips Petroleum Company

  公开号：US04495344A1

  公开（公告）日：1985-01-22

  Polyamides, prepared from cycloalkylalkylenediamines such as 5-cyclohexyl-5-methyl-1,9-nonanediamine and dicarboxylic acids such as adipic or azelaic acid, plus a tricarboxylic acid for branching such as benzene tricarboxylic acid, are tough, clear resins useful for molding and fibers.

  聚酰胺是由环状烷基亚烷基二胺（例如5-环己基-5-甲基-1,9-非安二胺）和二羧酸（例如己二酸或莪术二酸）以及用于分支的三羧酸（例如苯三羧酸）制备的，是一种坚韧、透明的树脂，适用于模塑和纤维制品。
• Dinitriles, diamines, and polyamides
  申请人：Phillips Petroleum Co.

  公开号：US04288625A1

  公开（公告）日：1981-09-08

  Unsaturated dinitriles are reacted with an aromatic compound such as benzene in the presence of a Lewis acid such as aluminum chloride to yield novel aralkylenedinitriles, such as 5-methyl-5-phenylnonanedinitrile and isomers thereof. The aralkylenedinitriles can be reduced to novel aralkylenediamines or novel cycloalkylalkylenediamines. Polymerization of the aralkylenediamines or cycloalkylalkylenediamines with polycarboxylic acids provides novel polyamides of tough, clear, colorless character.

  不饱和二腈与芳香族化合物（如苯）在Lewis酸（如氯化铝）的存在下反应，得到新型的芳基亚烷基二腈，如5-甲基-5-苯基壬二腈及其异构体。这些芳基亚烷基二腈可以还原为新型的芳基亚烷基二胺或新型的环烷基亚烷基二胺。将这些芳基亚烷基二胺或环烷基亚烷基二胺与多羧酸聚合，可以制备出具有坚韧、透明、无色特性的新型聚酰胺。