heptadecyldiethylamine | 66326-18-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: heptadecyldiethylamine
• 英文别名: N,N-Diethylheptadecan-1-amine
• CAS: 66326-18-9
• 化学式: C₂₁H₄₅N
• 分子量: 311.595
• InChiKey: PKCBOINYQMFSKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  22
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  、 十六碳烯 、 二乙胺 、 乙醇 在 amine 、 十六碳烯 、 二乙胺 作用下， 生成 、 heptadecyldiethylamine
  参考文献：
  名称：

  Process for preparing tertiary amines

  摘要：

  三级胺是通过在特定溶剂存在下，将长链烯烃与一氧化碳、氢气和一次或二次胺反应，使用由含有铑和/或钌的化合物组成的催化剂，随后进行反应产物的相分离而制备的。该过程有助于回收和再利用昂贵的催化剂。

  公开号：

  US04448996A1

文献信息

• Catalyst and process for producing a rigid polyurethane foam
  申请人：Tosoh Corporation

  公开号：EP1382624A1

  公开（公告）日：2004-01-21

  The present invention relates to: (1) a catalyst for producing a rigid polyurethane foam by means of at least one blowing agent selected from the group consisting of 1,1,1,3,3-pentafluoropropane (HFC-245fa), 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and a low boiling point hydrocarbon, which comprises: (A) an aliphatic amine compound and at least one amine compound selected from the group consisting of triethylenediamine, N,N,N',N'-tetramethyl-1,6-hexanediamine and N,N-dimethylcyclohexylamine: or (B) an amine compound having an alkyl ether group and/or an aryl ether group in its molecule; (2) a catalyst for producing a rigid polyisocyanurate foam by means of at least one blowing agent selected from the group consisting of 1,1,1,3,3-pentafluoropropane (HFC-245fa), 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and a low boiling point hydrocarbon, which comprises an aliphatic amine compound and a polyisocyanurate catalyst and (3) a process for producing a rigid polyurethane foam excellent in the adhesive strength and flame retardancy of the foam and (4) a process for producing a rigid polyisocyanurate foam excellent in the flame retardancy, adhesive strenght and dimensional stability of the foam.

  本发明涉及 (1) 用至少一种发泡剂生产硬质聚氨酯泡沫塑料的催化剂，该发泡剂选自 1,1,1,3,3-五氟丙烷(HFC-245fa)、1,1,1,3,3-五氟丁烷(HFC-365mfc)和低沸点碳氢化合物组成的组，该催化剂包括 (A) 脂肪族胺化合物和至少一种选自三乙二胺、N,N,N',N'-四甲基-1,6-己二胺和 N,N-二甲基环己胺的胺化合物：或 (B) 分子中含有烷基醚基和/或芳基醚基的胺化合物； (2) 通过至少一种发泡剂生产硬质聚异氰脲酸酯泡沫塑料的催化剂，该发泡剂选 自 1,1,1,3,3-五氟丙烷(HFC-245fa)、1,1,1,3,3-五氟丁烷(HFC-365mfc)和低沸点碳氢化合物组成的 组，其中包括脂肪族胺化合物和聚异氰脲酸酯催化剂，以及 (3) 生产粘合强度和阻燃性能优异的硬质聚氨酯泡沫塑料的工艺，以及 (4) 生产硬质聚异氰脲酸酯泡沫塑料的工艺，泡沫塑料的阻燃性、粘合强度和 尺寸稳定性极佳。
• RAPID CURING THIOL EPOXY RESIN WITH IMPROVED COMPRESSION STRENGTH PERFORMANCE
  申请人：The Boeing Company

  公开号：EP3165561A1

  公开（公告）日：2017-05-10

  Aspects described herein generally describe epoxy resins and methods of epoxy resin formation. In some embodiments, a resin includes the reaction product of one or more polythiols, one or more polyepoxides, one or more fillers and one or more amine catalysts. Polythiols have between two and about ten thiol moieties. Polyepoxides have between two and about ten epoxy moieties. One or more amine catalysts of the formula NR1R2R3, wherein each of R1, R2, and R3 is independently linear or branched C1-20 alkyl or two or more of R1, R2, and R3 combine to form cycloalkyl. The resin has a compressive strength of at least 14 ksi at 2% offset at 70°F and at least 8 ksi at 2% offset at 190°F.

  本文所述各方面一般描述环氧树脂和环氧树脂的形成方法。在某些实施例中，树脂包括一种或多种聚硫醇、一种或多种聚环氧化物、一种或多种填料和一种或多种胺催化剂的反应产物。聚硫醇具有两个到十个硫醇分子。聚环氧化物有两个到十个环氧基。一种或多种式 NR1R2R3 的胺催化剂，其中 R1、R2 和 R3 中的每一个都是独立的直链或支链 C1-20 烷基，或两个或两个以上的 R1、R2 和 R3 结合形成环烷基。该树脂在 70°F 时，偏移 2% 时的抗压强度至少为 14 ksi，在 190°F 时，偏移 2% 时的抗压强度至少为 8 ksi。
• AQUEOUS SOLUTION COMPOSITION CONTAINING ORGANOSILICON COMPOUND
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP4108297A1

  公开（公告）日：2022-12-28

  An aqueous solution composition containing a hydrolysate or a hydrolytic condensate of an organosilicon compound of formula (1), or both the hydrolysate and the hydrolytic condensate: wherein R1 and R2 are each independently an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, R3 is an alkyl group having 12 to 24 carbon atoms, R4 and R5 are each independently an alkyl group having 1 to 6 carbon atoms, X is a halogen atom, m is an integer of 4 to 20, and n is an integer of 1 to 3.

  一种水溶液组合物，含有式（1）有机硅化合物的水解物或水解缩合物，或水解物和水解缩合物： 其中 R1 和 R2 各自独立地是具有 1 至 10 个碳原子的烷基或具有 6 至 10 个碳原子的芳基，R3 是具有 12 至 24 个碳原子的烷基，R4 和 R5 各自独立地是具有 1 至 6 个碳原子的烷基，X 是卤素原子，m 是 4 至 20 的整数，n 是 1 至 3 的整数。
• AQUEOUS SOLUTION COMPOSITION CONTAINING ORGANOSILICON COMPOUNDS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP4108085A1

  公开（公告）日：2022-12-28

  An aqueous solution composition containing a co-hydrolysate or a co-hydrolytic condensate of an organosilicon compound of formula (1) and an organosilicon compound of formula (2), or both the co-hydrolysate and the co-hydrolytic condensate: wherein R1 and R2 are each independently an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, R3 is an alkyl group having 12 to 24 carbon atoms, R4 and R5 are each independently an alkyl group having 1 to 6 carbon atoms, X is a halogen atom, m is an integer of 1 to 20, and n is an integer of 1 to 3.

  一种水溶液组合物，含有式（1）的有机硅化合物和式（2）的有机硅化合物的共水解物或共水解缩合物，或者共水解物和共水解缩合物： 其中 R1 和 R2 各自独立地为具有 1 至 10 个碳原子的烷基或具有 6 至 10 个碳原子的芳基，R3 为具有 12 至 24 个碳原子的烷基，R4 和 R5 各自独立地为具有 1 至 6 个碳原子的烷基，X 为卤素原子，m 为 1 至 20 的整数，n 为 1 至 3 的整数。
• Rapid curing thiol epoxy resin with improved compression strength performance
  申请人：THE BOEING COMPANY

  公开号：US10035873B2

  公开（公告）日：2018-07-31

  Aspects described herein generally describe epoxy resins and methods of epoxy resin formation. In some embodiments, a resin includes the reaction product of one or more polythiols, one or more polyepoxides, one or more fillers and one or more amine catalysts. Polythiols have between two and about ten thiol moieties. Polyepoxides have between two and about ten epoxy moieties. One or more amine catalysts of the formula NR1R2R3, wherein each of R1, R2, and R3 is independently linear or branched C1-20 alkyl or two or more of R1, R2, and R3 combine to form cycloalkyl. The resin has a compressive strength of at least 14 ksi at 2% offset at 70° F. and at least 8 ksi at 2% offset at 190° F.

  本文所述各方面一般描述环氧树脂和环氧树脂的形成方法。在某些实施例中，树脂包括一种或多种聚硫醇、一种或多种聚环氧化物、一种或多种填料和一种或多种胺催化剂的反应产物。聚硫醇具有两个到十个硫醇分子。聚环氧化物有两个到十个环氧基。一种或多种式 NR1R2R3 的胺催化剂，其中 R1、R2 和 R3 中的每一个都是独立的直链或支链 C1-20 烷基，或两个或两个以上的 R1、R2 和 R3 结合形成环烷基。该树脂在华氏 70 度、偏移 2% 时的抗压强度至少为 14 ksi，在华氏 190 度、偏移 2% 时的抗压强度至少为 8 ksi。