申请人:MINNESOTA MINING AND MANUFACTURING COMPANY
公开号:EP0098112A2
公开(公告)日:1984-01-11
A mono-component toner powder composition which exhibits reduced sensitivity to machine conditions and provides copies whose images are sharply defined having substantially reduced backgrounding and good image density. The composition comprises a plurality of discrete particles each comprising a thermoplastic binder, a magnetically responsive material and carbon black, in which:
(a) the binder comprises from 40 to 70 weight percent of the composition and is selected from the group consisting of (i) polyester resins, (ii) copolymers of styrene monomers and at least one monomer selected from acrylate and methacrylate monomers, (iii) a wax component having a melting point in the range of from 45 to 150°C, and (iv) a blend of the wax component and a thermoplastic organic resin, in which the weight ratio of the wax component to the thermoplastic organic resin is in the range of from 1:0.1 to 1:1;
(b) the magnetically responsive material comprises from 30 to 60 weight percent of the composition, the magnetically responsive material being dispersed in the binder;
(c) from 0.05 to 2 weight percent of the composition of a fluorine-modified alkyl siloxane dispersed in the binder, and
(d) the carbon black comprises from 0.005 to 0.3 weight percent of the composition and is attached to the exterior surface of the particles thereof.
一种单组分调色剂粉末组合物,可降低对机器条件的敏感性,并可提供图像清晰的复印件,同时大幅降低背景干扰和良好的图像密度。该组合物由多个离散颗粒组成,每个颗粒都包含热塑性粘合剂、磁响应材料和炭黑,其中:
(a) 粘结剂占组合物的 40%至 70%,选自以下组别:(i) 聚酯树脂;(ii) 苯乙烯单体和至少一种选自丙烯酸酯和甲基丙烯酸酯单体的共聚物;(iii) 熔点在 45 至 150°C 范围内的蜡组分;(iv) 蜡组分和热塑性有机树脂的混合物,其中蜡组分和热塑性有机树脂的重量比在 1:0.1 至 1:1;
(b) 磁响应材料占组合物的 30%至 60%,磁响应材料分散在粘结剂中;
(c) 分散在粘合剂中的氟改性烷基硅氧烷占组合物的 0.05%至 2%,以及
(d) 炭黑占该组合物的 0.005 至 0.3 重量百分比,并附着在其颗粒的外表面。