Azaoxa heterocyclic compound and method of preparing the same
申请人:——
公开号:US20040068084A1
公开(公告)日:2004-04-08
Disclosed is an azaoxa heterocyclic compound represented by the following formula (I):
1
(wherein, each symbol is defined the same as in the specification) and a method for preparing the same. This compound of the present invention is prepared by the reaction of a phenolic compound, an aromatic diamine compound and an aldehyde compound. The azaoxa heterocyclic compound of the present invention can be used as a hardening resin or a hardener for an epoxy resin, polyether and a resin containing active hydrogen atoms, wherein the composition formed by the azaoxa heterocyclic compound and the epoxy resin is useful in the application of laminates, adhesive, semiconductor packaging materials and phenolic resin forming materials.
A resin comprises a structural unit derived from a compound represented by the formula (aa)
wherein T represents a C
4
to C
36
alicyclic hydrocarbon group, the hydrogen atom contained in the alicyclic hydrocarbon group may be replaced by a halogen atom, a hydroxyl group, a C
1
to C
12
alkyl group optionally substituted with a halogen atom or a hydroxyl group, a C
1
to C
12
alkoxyl group, a C
6
to C
12
aryl group, a C
7
to C
12
aralkyl group, a glycidyloxy group, a C
2
to C
4
acyl group, an alkoxycarbonyl group, an alkanoyloxyalkyl group or a cyano group, and the —CH
2
— contained in the alicyclic hydrocarbon group is replaced by at least one —SO
2
— and furthermore may be replaced by —CO—, —O—, —S—, —SO
2
— or —N(R
c
)—; R
c
represents a hydrogen atom or a C
1
to C
6
alkyl group; R
1
represents a hydrogen atom, a halogen atom, or a C
1
to C
6
alkyl group that may optionally has halogen atoms; and Z
1
represents an optionally substituted C
1
to C
17
saturated hydrocarbon group, and the —CH
2
— contained in the saturated hydrocarbon group may be replaced by —CO—, —O—, —S— or —N(R
c
)—.