2,6-dimethyl-N,N-bis-oxiranylmethyl-aniline | 95796-27-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-dimethyl-N,N-bis-oxiranylmethyl-aniline
• 英文别名: 2,6-Dimethyl-N,N-bis[(oxiran-2-yl)methyl]aniline；2,6-dimethyl-N,N-bis(oxiran-2-ylmethyl)aniline
• CAS: 95796-27-3
• 化学式: C₁₄H₁₉NO₂
• 分子量: 233.31
• InChiKey: RXQVGXQHXIUBPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  28.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,6-dimethyl-N,N-bis-oxiranylmethyl-aniline 在 sodium sulfide 作用下， 以 甲醇 为溶剂， 生成 1-<2,6-Dimethyl-phenyl>-1-aza-5-thia-cyclooctan-3,7-diol
  参考文献：
  名称：

  烷基2,3-环氧丙胺：环二聚化及相关的八元闭环

  摘要：

  改进的程序产生了新的烷基-2，3-环氧丙胺（2），其范围从非常不稳定的（正烷基）到异常稳定的（叔烷基）类型。讨论了与2的稳定性有关的动力学和其他数据。

  DOI：

  10.1016/0040-4020(67)80045-0

文献信息

• Fortified epoxy resin compositions and process for the preparation thereof
  申请人：Canadian Patents and Development Limited Société Canadienne des Brevets et d'Exploitation Limitée

  公开号：EP0103392A1

  公开（公告）日：1984-03-21

  Heat curable epoxy resin compositions comprising a resin-forming polyepoxide and an amine curing agent are fortified (i. e. given increased strength and modulus but without consequent brittleness) by incorporating into the resin mix prior to curing up to 40 parts by weight per hundred parts of resin of a fortifying agent which is the reaction product of an aromatic amine, e. g. aniline, with a mono- or di-epoxide, the fortifier thus obtained optionally further being reacted with an isocyanate or nitrile prior to incorporation into the resin mix.

  热固化环氧树脂组合物由树脂形成的多环氧化物和胺固化剂组成，在固化前，在树脂混合物中加入每百份树脂重量不超过 40 份的强化剂，强化剂是芳香胺（如苯胺）与一环氧化物或二环氧化物的反应产物，可强化环氧树脂组合物（即增加强度和模量，但不会因此而脆化）。这种强化剂是芳香胺（如苯胺）与一元环氧化物或二元环氧化物的反应产物。
• Fortifier or strengthener for anhydridecured epoxy resins and anhydride curable epoxy resins containing it
  申请人：NATIONAL RESEARCH COUNCIL OF CANADA

  公开号：EP0283199A2

  公开（公告）日：1988-09-21

  An anhydride-cured epoxy resin (epoxy resin plus anhydride curing agent plus catalyst) may be fortified (i.e. increased in strength and modulus without being made brittle) by the addition of a fortifying agent comprising a mixture of a carboxylic acid and the reaction product of a carboxylic acid anhydride and a substituted aromatic amine.

  在酸酐固化的环氧树脂（环氧树脂加酸酐固化剂加催化剂）中加入一种由羧酸和羧 酸酐与取代芳香胺的反应产物的混合物组成的强化剂，可对其进行强化（即在不变脆 的情况下增加强度和模量）。
• EPOXY RESIN COMPOSITION, FIBER-REINFORCED COMPOSITE MATERIAL AND METHOD FOR PRODUCING THE SAME
  申请人：Toray Industries, Inc.

  公开号：EP2256163A1

  公开（公告）日：2010-12-01

  Disclosed herein are an epoxy resin composition for fiber-reinforced composite materials which has low viscosity, high Tg, high elastic modulus, and excellent fracture toughness and a fiber-reinforced composite material using such an epoxy resin composition which has excellent thermal properties, compressive strength, impact resistance, fatigue resistance, and open-hole tensile strength and which is suitable for producing structural parts of aircraft and the like. The epoxy resin composition comprises at least a given bifunctional epoxy resin as a component (A), a liquid aromatic diamine curing agent as a component (B), and core-shell polymer particles as a component (C), wherein the core-shell polymer particles as the component (C) contain epoxy groups in their shell and have a volume-average particle size of 50 to 300 nm.

  本文公开了一种用于纤维增强复合材料的环氧树脂组合物，该组合物具有低粘度、高 Tg、高弹性模量和优异的断裂韧性；还公开了一种使用这种环氧树脂组合物的纤维增强复合材料，该材料具有优异的热性能、抗压强度、抗冲击性能、抗疲劳性能和开孔拉伸强度，适用于生产飞机等的结构部件。该环氧树脂组合物至少包括作为组分（A）的给定双官能环氧树脂、作为组分（B）的液态芳香族二胺固化剂和作为组分（C）的芯壳聚合物颗粒，其中作为组分（C）的芯壳聚合物颗粒在其外壳中含有环氧基团，其体积平均粒径为 50 至 300 纳米。
• Fortifier for epoxy resins, method for the preparation thereof and fortified epoxy resin compositions containing same
  申请人：Canadian Patents and Development Limited Société Canadienne des Brevets et d'Exploitation Limitée

  公开号：EP0103968B1

  公开（公告）日：1987-07-22
• HIGH TEMPERATURE RESISTANT COATING COMPOSITION AND METHOD OF USING THEREOF
  申请人：H.B. Fuller Company

  公开号：EP1071729A1

  公开（公告）日：2001-01-31