3-[4-(4-Chlorophenyl)-2,6-dimethylphenyl]-4-hydroxyspiro[4.5]dec-3-en-2-one | 241144-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[4-(4-Chlorophenyl)-2,6-dimethylphenyl]-4-hydroxyspiro[4.5]dec-3-en-2-one
• CAS: 241144-74-1
• 化学式: C₂₄H₂₅ClO₂
• 分子量: 380.914
• InChiKey: RQHZEQMLGMTMEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-[4-(4-Chlorophenyl)-2,6-dimethylphenyl]-4-hydroxyspiro[4.5]dec-3-en-2-one 、 氯甲基乙醚 在 三乙胺 作用下， 以 乙酸乙酯 为溶剂， 反应 8.0h， 以88%的产率得到3-[4-(4-Chlorophenyl)-2,6-dimethylphenyl]-4-(ethoxymethoxy)spiro[4.5]dec-3-en-2-one
  参考文献：
  名称：

  Biphenyl-substituted cyclic ketoenols as pesticides

  摘要：

  本发明涉及新颖的具有以下结构的双苯基取代的环状酮烯醇（I）：其中W代表氢、卤素、烷基、烷氧基、烯基氧基、卤代烷基、卤代烷氧基、卤代烯基氧基、硝基或氰基，X代表卤素、烷基、烷氧基、烯基氧基、烷硫基、烷基砜基、烷基磺酰基、卤代烷基、卤代烷氧基、卤代烯基氧基、硝基、氰基或在每种情况下可选择取代的苯基、苯氧基、苯硫基、苯烷氧基或苯烷硫基，Y代表在每种情况下可选择取代的环烷基、芳基或杂环烷基，Z代表氢、卤素、烷基、烷氧基、卤代烷基或卤代烷氧基，CKE代表下列之一：其中A、B、D、L、M、Q1、Q2、Q3、Q4、Q5和Q6如描述中所定义，用于制备及其作为杀虫剂和除草剂的用途。

  公开号：

  US06642180B1

文献信息

• Arylphenyl-substituted cyclic keto-enols
  申请人：Lieb Folker

  公开号：US20080081807A1

  公开（公告）日：2008-04-03

  The present invention relates to novel arylphenyl-substituted cyclic ketoenols of the formula (I) in which X represents halogen, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl, halogenoalkoxy, halogenoalkenyloxy, nitro, cyano or in each case optionally substituted phenyl, phenoxy, phenylthio, phenylalkoxy or phenylalkylthio, Y represents in each case optionally substituted cycloalkyl, aryl or hetaryl, Z represents hydrogen, halogen, alkyl, alkoxy, alkenyloxy, halogenoalkyl, halogenoalkoxy, halogenoalkenyloxy, nitro or cyano, CKE represents one of the groups in which A, B, D, G and Q 1 to Q 6 are each as defined in the description, to a plurality of processes for their preparation and to their use as pesticides and herbicides.
• ARYLPHENYL-SUBSTITUTED CYCLIC KETO-ENOLS
  申请人：Lieb Folker

  公开号：US20100087320A1

  公开（公告）日：2010-04-08

  The present invention relates to novel arylphenyl-substituted cyclic ketoenols of the formula (I) in which X represents halogen, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl, halogenoalkoxy, halogenoalkenyloxy, nitro, cyano or in each case optionally substituted phenyl, phenoxy, phenylthio, phenylalkoxy or phenylalkylthio, Y represents in each case optionally substituted cycloalkyl, aryl or hetaryl, Z represents hydrogen, halogen, alkyl, alkoxy, alkenyloxy, halogenoalkyl, halogenoalkoxy, halogenoalkenyloxy, nitro or cyano, CKE represents one of the groups in which A, B, D, G and Q 1 to Q 6 are each as defined in the description, to a plurality of processes for their preparation and to their use as pesticides and herbicides.
• US7288676B2
  申请人：——

  公开号：US7288676B2

  公开（公告）日：2007-10-30
• US7718706B2
  申请人：——

  公开号：US7718706B2

  公开（公告）日：2010-05-18
• US8058210B2
  申请人：——

  公开号：US8058210B2

  公开（公告）日：2011-11-15