N~1~,N~4~-Bis(4-methoxyphenyl)-N~1~,N~4~-diphenylbenzene-1,4-diamine | 124526-50-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N~1~,N~4~-Bis(4-methoxyphenyl)-N~1~,N~4~-diphenylbenzene-1,4-diamine
• 英文别名: 1-N,4-N-bis(4-methoxyphenyl)-1-N,4-N-diphenylbenzene-1,4-diamine
• CAS: 124526-50-7
• 化学式: C₃₂H₂₈N₂O₂
• 分子量: 472.6
• InChiKey: MVTMDAWNEPFGEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N'-二苯基-1,4-苯二胺 、 4-mono-iodo-benzyl ether 、 potassium carbonate 、 18-冠醚-6 在 铜 丙酮 作用下， 以 正己烷 、 邻二氯苯 为溶剂， 反应 24.0h， 以afforded 55.7 g (66 percent) of a tan-colored crystal的产率得到N~1~,N~4~-Bis(4-methoxyphenyl)-N~1~,N~4~-diphenylbenzene-1,4-diamine
  参考文献：
  名称：

  Crosslinkable or chain extendable polyarylpolyamines and films thereof

  摘要：

  该发明涉及具有多个芳基基团的聚（三级二元或聚芳基胺），所述芳基基团进一步被取代为可进行链延伸或交联的基团。在另一个方面，该发明涉及具有多个芳基基团的聚（三级二元或聚芳基胺），所述芳基基团进一步被取代为可进行链延伸或交联的基团，这些聚合物部分或完全交联或链延伸。该发明还涉及从这种链延伸或交联的聚（三级二元或聚芳基胺）制备的薄膜。该发明还涉及电子照相设备和电致发光设备，例如含有这种薄膜的聚合物发光二极管。

  公开号：

  US05929194A1

文献信息

• Poly (arylamines) and films thereof
  申请人：The Dow Chemical Company

  公开号：US05728801A1

  公开（公告）日：1998-03-17

  A poly(arylamine) composition comprising one or more compounds of Formula (I): ##STR1## wherein: R is independently in each occurrence a C.sub.1-24 hydrocarbyl, C.sub.1-24 hydrocarboxy, C.sub.1-24 hydrocarbylthiooxy, or C.sub.1-24 hydrocarbylcarboxyl; Ar.sup.1 and Ar.sup.2 are independently in each occurrence a C.sub.6-18 aryl moiety optionally substituted with a C.sub.1-12 hydrocarbyl, C.sub.1-12 hydrocarbyloxy, C.sub.1-12 hydrocarbylthiooxy, or C.sub.1-12 hydrocarbylcarboxyl; A is independently in each occurrence hydrogen or a halogen; x is independently in each occurrence a positive number from 0 to 1; n is independently in each occurrence a whole number of from 0 to 4; and m is a number of from about 5 to about 1000.

  一种聚芳胺组合物，包括一个或多个化合物，其化学式为（I）：##STR1## 其中：R在每次出现时独立地是C.sub.1-24烃基、C.sub.1-24烃基羧基、C.sub.1-24烃基硫氧基或C.sub.1-24烃基羧酸基；Ar.sup.1和Ar.sup.2在每次出现时独立地是C.sub.6-18芳基基团，可选地取代为C.sub.1-12烃基、C.sub.1-12烃氧基、C.sub.1-12烃硫氧基或C.sub.1-12烃基羧酸基；A在每次出现时独立地是氢或卤素；x在每次出现时独立地是0到1之间的正数；n在每次出现时独立地是0到4之间的整数；m是大约5到大约1000的数字。
• Doping methods for hole injection and transport layers
  申请人：Plextronics, Inc.

  公开号：US20130092887A1

  公开（公告）日：2013-04-18

  A method including combining at least one first compound in a neutral form with at least one ionic dopant in a first solvent system to provide a first doped reaction product, isolating the first doped reaction product in solid form, and combining the isolated first doped reaction product with at least one conjugated polymer in neutral form in a second solvent system to form a second doped reaction product including an oxidized form of the conjugated polymer a neutral form of the first compound. Advantages include better stability, ease of use, and lower metal content. Applications include organic electronic devices including OLEDs.

  一种方法包括将至少一种第一化合物以中性形式与至少一种离子掺杂剂在第一溶剂体系中结合以提供第一掺杂反应产物，将第一掺杂反应产物以固体形式分离，并将分离的第一掺杂反应产物以中性形式与至少一种共轭聚合物在第二溶剂体系中结合以形成第二掺杂反应产物，其中包括共轭聚合物的氧化形式和第一化合物的中性形式。优点包括更好的稳定性、易于使用和较低的金属含量。应用包括有机电子器件，包括OLED。
• Heat-resistant organic electroluminescent device
  申请人：Hewlett-Packard Company

  公开号：EP0827366A2

  公开（公告）日：1998-03-04

  An organic electroluminescent device that comprises a substrate (203), a transparent first conductive layer (201) next to the substrate, an electron-transporting and light-emitting layer (209), a hole-transporting layer (205) sandwiched between the first conductive layer and the electron-transporting and light-emitting layer, and a second conductive layer (211) next to the electron-transporting and light-emitting layer and remote from the hole-transporting layer. The hole-transporting layer comprises a poly(arylamine) including at least one compound of one or more compounds of from about 5 to about 1000 of monomer. The monomers useful in the preparation of the poly(arylamines) comprise two amino moieties in which each amino moiety is bound to three aryl moieties in which two halo moieties are optionally bound to the monomer.

  一种有机电致发光器件，包括基底（203）、紧靠基底的透明第一导电层（201）、电子传输和发光层（209）、夹在第一导电层和电子传输和发光层之间的空穴传输层（205）以及紧靠电子传输和发光层并远离空穴传输层的第二导电层（211）。空穴传输层包括聚（芳基胺），其中包括至少一种单体含量约为 5 至 1000 的一种或多种化合物。在制备聚芳基胺时有用的单体包括两个氨基，其中每个氨基与三个芳基结合，其中两个卤基可选地与单体结合。
• ORGANIC LIGHT-EMITTING APPARATUS
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3211681A1

  公开（公告）日：2017-08-30

  An organic light-emitting apparatus includes an organic light-emitting device and a magnetic field-applying member that applies a magnetic field to the organic light-emitting device. The organic light-emitting device includes a host and a dopant.

  一种有机发光装置包括一个有机发光器件和一个向有机发光器件施加磁场的磁场施加部件。有机发光器件包括主机和掺杂剂。
• Organic light-emitting device and method of operating the same
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US10366653B2

  公开（公告）日：2019-07-30

  An organic light-emitting device including a magnetoresistive element including a first magnetic layer, a second magnetic layer, and a separation layer disposed between the first magnetic layer and the second magnetic layer, an organic light-emitting element electrically connected to the magnetoresistive element, wherein the organic light-emitting element comprises a first electrode, a second electrode, and an organic light-emission layer disposed between the first electrode and the second electrode, a magnetic field applying unit configured to apply a magnetic field to at least the magnetoresistive element, and optionally, to the organic light-emitting element, a power source configured to supply a current between the magnetoresistive element and the organic light-emitting element, and a current source configured to apply a current between both terminals of the organic light-emitting element, wherein light-emission characteristics of the organic light-emitting device are changed depending on a direction and intensity of a current passing through the magnetoresistive element due to the power source and a direction and intensity of a current passing through the organic light-emitting element due to the power source and the current source.

  一种有机发光器件，包括磁阻元件，该磁阻元件包括第一磁层、第二磁层以及设置在第一磁层和第二磁层之间的分离层；与磁阻元件电连接的有机发光元件，其中有机发光元件包括第一电极、第二电极以及设置在第一电极和第二电极之间的有机发光层；磁场施加单元，该磁场施加单元被配置为至少向磁阻元件施加磁场，并且可选地、配置为在磁阻元件和有机发光元件之间提供电流的电源，以及配置为在有机发光元件的两个端子之间施加电流的电流源，其中有机发光器件的发光特性的改变取决于电源导致的通过磁阻元件的电流方向和强度，以及电源和电流源导致的通过有机发光元件的电流方向和强度。