4-Ethenyl-N,N,I+/--trimethylbenzenemethanamine | 84092-62-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Ethenyl-N,N,I+/--trimethylbenzenemethanamine
• 英文别名: 1-(4-ethenylphenyl)-N,N-dimethylethanamine
• CAS: 84092-62-6
• 化学式: C₁₂H₁₇N
• 分子量: 175.27
• InChiKey: PVJAOSOVWWTFHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• COSMETIC POLYMER COMPOSITION AND COSMETIC
  申请人：HIWATASHI Tomoaki

  公开号：US20070166250A1

  公开（公告）日：2007-07-19

  The present invention discloses a cosmetic polymer composition containing a straight-chain block copolymer, where the copolymer having a unit derived from a compound having an ethylenic unsaturated bond, having a number-average molecular weight of 1.0×10 3 to 1.0×10 6 , and having at least two or more glass transition points or melting points; a hair cosmetic polymer composition containing a copolymer a copolymer capable of forming a film having a Young's modulus of 50 MPa or larger and a fracture-point elongation of 100% or larger, and dispersible into water and/or alcohol; and a cosmetic material containing these compositions.

  本发明揭示了一种化妆品聚合物组合物，其中包含一种直链嵌段共聚物，该共聚物具有从具有乙烯不饱和键的化合物导出的单元，具有1.0×103至1.0×106的数均分子量，并且具有至少两个或更多的玻璃转变点或熔点；一种头发化妆品聚合物组合物，其中包含一种共聚物，该共聚物能够形成具有50 MPa或更大的杨氏模量和100％或更大的断裂点延伸的膜，并且能够分散到水和/或酒精中；以及包含这些组合物的化妆品材料。
• AMPHIPHILIC MACROMOLECULAR EMULSIFIER WITH SWITCHABLE SURFACE ACTIVITY AND USE THEREOF IN PREPARATION OF POLYMER LATEX
  申请人：ZHEJIANG UNIVERSITY

  公开号：US20140316049A1

  公开（公告）日：2014-10-23

  A macromolecular emulsifier with switchable surface activity, and use thereof for preparation of polymer latex is disclosed. By using the macromolecular emulsifier with switchable surface activity as an emulsifier, a reversibly coagulable and re-dispersible polymer latex can be prepared by emulsion polymerization. The polymer latex can achieve the coagulation of latex particles by heating and aerating with nitrogen, air, inert gas and/or adding a small amount of alkali solution; the coagulated latex particles can be restored and re-dispersed into stable latex by aerating with carbon dioxide and/or adding a small amount of acid solution. The coagulation and re-dispersion process is reversible and is easy to control.

  本发明涉及一种具有可切换表面活性的高分子乳化剂，以及其用于制备聚合物乳液。通过使用具有可切换表面活性的高分子乳化剂作为乳化剂，可以通过乳液聚合制备可逆凝固和可再分散的聚合物乳液。该聚合物乳液可以通过加热和通入氮气、空气、惰性气体和/或添加少量碱溶液来实现乳胶颗粒的凝固；通过通入二氧化碳和/或添加少量酸溶液来恢复和重新分散凝固的乳胶颗粒为稳定的乳液。凝固和重新分散过程是可逆的，并且易于控制。
• Temporary wet strength resins with nitrogen heterocyclic nonnucleophilic functionalities and paper products containing same
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0350276A2

  公开（公告）日：1990-01-10

  Temporary wet strength resins, and paper products containing same, having a molecular weight of from about 20,000 to about 200,000, most preferably from about 30,000 to about 95,000, having the formula: wherein: A is and X is -0-, -NH-, or -NCH3-, and R is a substituted or unsubstituted aliphatic group; Yi and Y2 are independently -H, -CH3, or a halogen; W is a nonnucleophilic, water-soluble nitrogen heterocyclic moiety; and Q is a cationic monomeric unit. The mole percent of "a" ranges from about 30% to about 70%, preferably from about 45% to about 55%; the mole percent of "b" ranges from about 30% to about 70%, preferably from about 45% to about 55%; and the mole percent of "c" ranges from about 10/0 to about 400/0, most preferably from about 2% to about 8%.

  临时湿强度树脂和含有这种树脂的纸制品，其分子量约为 20,000 至约 200,000 之间，最优选的分子量约为 30,000 至约 95,000 之间，具有以下式子： 其中A 是 X是-0-、-NH-或-NCH3-，R是取代或未取代的脂肪族基团；Yi和Y2独立地是-H、-CH3或卤素；W是非亲核、水溶性氮杂环分子；Q是阳离子单体单元。a "的摩尔百分比范围为约 30%至约 70%，优选约 45%至约 55%；"b "的摩尔百分比范围为约 30%至约 70%，优选约 45%至约 55%；"c "的摩尔百分比范围为约 10/0 至约 400/0，最优选约 2%至约 8%。
• Process of producing hydroxyalkanal
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0713853A1

  公开（公告）日：1996-05-29

  Unsaturated aldehydes are hydrated in solution in the presence of various substituted carboxylic acid-based resins to produce corresponding hydroxyalkanals. These heat-resistant catalysts make it possible to increase the reaction rate by heating, and produce hydroxyalkanals at high selectivity and yield from industrially advantageous high-density unsaturated aldehyde solutions.

  不饱和醛在各种取代的羧酸基树脂存在下在溶液中水合，生成相应的羟基烷烃。这些耐热催化剂可以通过加热提高反应速率，并从具有工业优势的高密度不饱和醛溶液中以高选择性和高产率生产羟基烷烃。
• Graft copolymer and process for production thereof
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0939090A1

  公开（公告）日：1999-09-01

  The present invention discloses a graft copolymer comprising an olefin polymer or a block copolymer, and an ionic group-containing polymer grafted to the olefin polymer or the block copolymer by a bridging group whose bridging chain has 4 or more atoms. The invention also discloses a process for producing the graft copolymer, which comprises reacting a radical polymerizable unsaturated compound (b) with a modified olefin polymer (a1) or a modified block copolymer (a2) to form a radical polymerizable olefin polymer (c1) or a radical polymerizable block copolymer (c2), the modified olefin polymer (a1) or the radical polymerizable block copolymer (c2) having a functional group selected from the group consisting of a hydroxyl group, a carboxyl group, an anhydrous carboxyl group, an epoxy group, and an isocyanate group, and the radical polymerizable unsaturated compound (b) having a functional group reactive with the above functional group; and then radical copolymerizing a radical polymerizable unsaturated compound (d) having an ionic group with the radical polymerizable olefin polymer (c1) or the radical polymerizable block copolymer (c2). When applied to a surface of a molded product of a thermoplastic resin or the like, the graft copolymer of the invention can impart coating properties, printing properties and antistatic properties to the molded product while maintaining sufficient adhesion to the molded product.

  本发明公开了一种接枝共聚物，包括烯烃聚合物或嵌段共聚物，以及通过桥接基（其桥接链具有 4 个或更多原子）接枝到烯烃聚合物或嵌段共聚物上的含离子基团聚合物。本发明还公开了一种生产接枝共聚物的工艺，包括将可自由基聚合的不饱和化合物（b）与改性烯烃聚合物（a1）或改性嵌段共聚物（a2）反应，形成可自由基聚合的烯烃聚合物（c1）或可自由基聚合的嵌段共聚物（c2）、改性烯烃聚合物（a1）或可自由基聚合的嵌段共聚物（c2）具有选自羟基、羧基、无水羧基、环氧基和异氰酸酯基的官能团，以及可自由基聚合的不饱和化合物（b）具有与上述官能团反应的官能团；然后将具有离子基团的可自由基聚合的不饱和化合物 (d) 与可自由基聚合的烯烃聚合物 (c1) 或可自由基聚合的嵌段共聚物 (c2) 进行自由基共聚。将本发明的接枝共聚物涂抹到热塑性树脂或类似材料的模制产品表面时，可赋予模制产品涂层性能、印刷性能和抗静电性能，同时与模制产品保持足够的粘附性。