2,2-Bis-(4-oxy-3-methylphenyl)-adamantan | 52211-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-Bis-(4-oxy-3-methylphenyl)-adamantan
• 英文别名: 2,2-Bis-(4-hydroxy-3-methylphenyl)-adamantan；2,2-Bis-(4-hydroxy-3-methylphenyl)adamantane；4-[2-(4-hydroxy-3-methylphenyl)-2-adamantyl]-2-methylphenol
• CAS: 52211-75-3
• 化学式: C₂₄H₂₈O₂
• 分子量: 348.485
• InChiKey: VFKXDIJGCZABJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• METHOD FOR PRODUCING BISCHLOROFORMATE COMPOUND, POLYCARBONATE OLIGOMER HAVING SMALL NUMBER OF MONOMERS AND SOLUTION CONTAINING BISCHLOROFMATE COMPOUND
  申请人：Hikosaka Takaaki

  公开号：US20120101292A1

  公开（公告）日：2012-04-26

  A dihydric phenol compound represented by the following formula (2), a phosgene compound, and an aliphatic tertiary amine are mixed together using a hydrophobic organic solvent to produce bischloroformate that is represented by the following formula (1) and has an average number of repeating units (n) of 1.99 or less. In the formulae (1) and (2), Ar is a divalent aromatic group.

  使用疏水性有机溶剂混合以下化学式（2）表示的二元酚化合物、光气化合物和脂肪族三级胺，以产生以下化学式（1）表示的双氯甲酸酯，其平均重复单元数（n）为1.99或更少。在化学式（1）和（2）中，Ar是二价芳香族基。
• ADAMANTANE DERIVATIVE, COMPOSITION COMPRISING THE DERIVATIVE, AND OPTICAL AND ELECTRONIC MEMBER USING THE COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1985617A1

  公开（公告）日：2008-10-29

  To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions. An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Yrepresentsagrouprepresented by the formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16-m) and p and q are each an integer of 1 to 5.

  为提供一种金刚烷衍生物、一种具有金刚烷骨架的化合物、含有它们的组合物，可提供具有优异光学性能（如透明度和耐光性）、长期耐热性和电特性（如介电常数）的固化产品以及使用这些组合物的光电子元件。该金刚烷衍生物由通式（I）表示，具有金刚烷骨架的化合物由通式（VII）或（VIII）表示，含有它们的组合物以及使用树脂组合物的光电子元件。在公式中，W代表氢原子，X代表由通式（II）表示的基团，Y代表由公式（V）或（VI）表示的基团，R1代表甲基基团或乙基基团，R2代表含有O或S的C1至C10烃基团，m为2至4的整数，k为0至（16-m）的整数，p和q均为1至5的整数。
• POLYCARBONATE POLYMER, COATING LIQUID, AND ELECTROPHOTOGRAPHIC PHOTOSENSITIVE BODY
  申请人：Hikosaka Takaaki

  公开号：US20100233603A1

  公开（公告）日：2010-09-16

  A polycarbonate polymer includes: a monomer unit represented by a formula (1A) below; and a monomer unit represented by a formula (2). A haze of a solution that is obtained by dissolving the polycarbonate polymer in THF (tetrahydrofuran) at a concentration of 10 mass % is 5% or less (according to JIS K7105, optical path length of 10 mm). In the formula (1A), R and R′ each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 12 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms; n1 is an integer in a range of 2 to 4; and n2 is an integer in a range of 25 to 220; and in the formula (2), Ar represents a divalent aromatic group.

  一种聚碳酸酯聚合物包括：由以下式（1A）表示的单体单位；和由式（2）表示的单体单位。将聚碳酸酯聚合物以10质量％的浓度在THF（四氢呋喃）中溶解得到的溶液的浑浊度小于或等于5％（根据JIS K7105，光程为10毫米）。在式（1A）中，R和R'各自独立表示氢原子，卤素原子，具有1到12个碳原子的烷基或具有6到12个碳原子的取代或未取代芳基基团；n1是2到4之间的整数；n2是25到220之间的整数；在式（2）中，Ar表示二价芳香基团。
• POLYCARBONATE COPOLYMER, COATING LIQUID USING SAME, AND ELECTROPHOTOGRAPHIC PHOTOSENSITIVE BODY
  申请人：Hikosaka Takaaki

  公开号：US20120100474A1

  公开（公告）日：2012-04-26

  A polycarbonate copolymer includes a repeating unit represented by a formula (1) below and a molar copolymer composition represented by Ar 2 /(Ar 1 +Ar 2 ) in a range of 25 mol % to 50 mol %. In the formula (1): Ar 1 and Ar 2 represent a divalent aromatic group; a chain end is terminated by a monovalent aromatic group or a monovalent fluorine-containing aliphatic group; and n represents an average repeating number of an Ar 1 block and is a numeral of 1.0 to 3.0, provided that Ar 1 and Ar 2 are not the same.

  一种聚碳酸酯共聚物，包括由下式（1）表示的重复单元和在Ar2/（Ar1+Ar2）范围内的摩尔共聚物组成，该组成在25摩尔％至50摩尔％之间。在式（1）中：Ar1和Ar2表示二价芳香基；链端由一价芳香基或含氟一价脂肪基终止；n表示Ar1块的平均重复次数，是1.0到3.0的数字，前提是Ar1和Ar2不相同。
• AROMATIC POLYCARBONATE RESIN PROCESS FOR PRODUCING THE SAME OPTICAL PART MOLDINGMATERIAL AND OPTICAL PART
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1469026A1

  公开（公告）日：2004-10-20

  The present invention relates to an aromatic polycarbonate resin which comprises repetitive units originating in residual groups of a 2,2-bis(4-hydroxyphenyl)adamantane compound and a 1,3-bis(4-hydroxyphenyl)adamantane compound having a substituent on an aromatic ring and which is excellent in a transparency, a heat resistance and a mechanical strength and has a good moldability and a production process for the aromatic polycarbonate resin described above in which the adamantane compounds described above are reacted with a carbonic ester-forming compound. Further, it relates to an aromatic polycarbonate resin which is excellent in an optical characteristic and an optical part prepared by molding the same.

  本发明涉及一种芳香族聚碳酸酯树脂，该树脂由源自 2,2-双（4-羟基苯基）金刚烷化合物和 1,3-双（4-羟基苯基）金刚烷化合物残基的重复单元组成，该化合物在芳香环上具有取代基，具有优异的透明度、耐热性和机械强度，并具有良好的成型性，本发明还涉及上述芳香族聚碳酸酯树脂的生产工艺，在该生产工艺中，上述金刚烷化合物与碳酸酯形成化合物发生反应。此外，本发明还涉及一种光学特性优异的芳香族聚碳酸酯树脂以及通过模塑该树脂制备的光学部件。