N-Benzyl-N,N-dibutylbutan-1-aminium fluoride | 60436-02-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Benzyl-N,N-dibutylbutan-1-aminium fluoride
• 英文别名: benzyl(tributyl)azanium;fluoride
• CAS: 60436-02-4
• 化学式: C19H34FN
• 分子量: 295.5
• InChiKey: PRAANDQMEYFSAE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.41
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Photoinitiator, novel compound, and photocurable composition
  申请人：Lachowicz Artur

  公开号：US20050256218A1

  公开（公告）日：2005-11-17

  A photoinitiator is provided which exhibits excellent photosensitivity, yields colorless products, and is usable in thick layer UV curable coating. A novel chemical compound is also provided which is usable for the photoinitator. Photocurable composition is also provided which has these properties. The photoinitiator consists essentially of a compound having a molecular weight of 1000 or less, and having a chemical structure represented by the following formula (1), wherein R 3 and R 4 independently denote a specific alkyl group, and R 1 and R 2 independently denote an electron attracting group or a specific alkyl group, and weight percentage of a chemical structure element represented by the following formula (2), which is expressed in formula (1) based on the total molecular weight of the compound, is 17% to 54% by mass.

  提供了一种光引发剂，其具有优异的光敏度，产物无色，并可用于厚层紫外线固化涂层。还提供了一种新的化合物，可用于制备光引发剂。同时提供了具有这些特性的光固化组合物。该光引发剂基本上由分子量小于或等于1000的化合物组成，其化学结构由以下公式（1）表示，其中R3和R4独立地表示特定的烷基，R1和R2独立地表示电子吸引基团或特定的烷基，根据化合物的总分子量，以下公式（2）所表示的化学结构元素的重量百分比在17%至54%之间。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Gem-disubstituted cyclohexadienones and their production
  申请人：ETHYL CORPORATION

  公开号：EP0336371A2

  公开（公告）日：1989-10-11

  Gem-disubstituted cyclohexadienone in which the gem substituents are a perfluoroalkyl group and a trihydrocar­bylsiloxy group are prepared by perfluoroalkylating a quinone with a perfluoroalkyltrihydrocarbylsilane in the presence of an active catalyst under essentially anhydrous conditions, preferably in a suitable liquid phase reaction medium, most preferably in a dipolar aprotic solvent. These gem-disubstituted compounds are readily convertible to perfluoroalkyl-substituted aromatics and thus provide a means of circumventing the traditional need for photo-­chlorination followed by halogen exchange in the prepara­tion of such products.

  宝石二取代环己二烯酮（其中宝石取代基为全氟烷基和三氢羰基硅氧烷基）的制备方法是：在活性催化剂存在下，在基本上无水的条件下，最好是在合适的液相反应介质中，最理想的是在二极性无水溶剂中，用全氟烷基三氢羰基硅烷对醌进行全氟烷基化反应。这些 gem-二取代化合物很容易转化为全氟烷基取代的芳烃，因此提供了一种方法来避免在制备这类产品时需要先进行光氯化再进行卤素交换的传统做法。
• Composition for a resin
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0936233A2

  公开（公告）日：1999-08-18

  A composition comprising a compound having one or more episulfide groups and/or epoxy groups in one molecule and a compound having one or more isocyanate groups and/or thioisocyanate groups in one molecule. The composition for a resin comprising a sulfur-containing compound exhibits an excellent balance between a refractivity index and an Abbe number and has a large impact resistance.

  一种组合物，包含在一个分子中含有一个或多个环硫基团和/或环氧基团的化合物，以及在一个分子中含有一个或多个异氰酸酯基团和/或硫代异氰酸酯基团的化合物。 包含含硫化合物的树脂组合物在折射率和阿贝数之间表现出极佳的平衡，并具有很强的抗冲击性。
• Process for producing a novel resin for optical materials having excellent color tone and transparency
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0950905A2

  公开（公告）日：1999-10-20

  A process for producing a resin used for optical materials which process comprises curing a composition comprising an ultraviolet light absorbent and an epithio compound by polymerization in the presence of a catalyst, wherein amounts of the ultraviolet light absorbent and the catalyst each expressed as parts by weight per 100 parts by weight of the total amount of the epithio compound, the ultraviolet light absorbent and the catalyst satisfy both of the following relations (a) and (b):(a)0.001 ≦ ultraviolet light absorbent ≦ 1. 000(b).0.001 ≦ catalyst ≦ 5.000 Coloration and clouding of the material of a lens obtained by polymerization of an epithio compound caused by addition of an ultraviolet light absorbent can be prevented.

  一种生产光学材料用树脂的工艺，该工艺包括在催化剂存在下通过聚合固化由紫外光吸收剂和表硫基化合物组成的组合物，其中紫外光吸收剂和催化剂的量分别以表硫基化合物、紫外光吸收剂和催化剂总量每100重量份的重量份数表示，满足以下关系(a)和(b)：(a)0.001 ≦ 紫外线吸收剂 ≦ 1. 000(b).0.001 ≦ 催化剂 ≦ 5.000 可防止因添加紫外线吸收剂而使表硫醇化合物聚合得到的镜片材料变色和混浊。