申请人:Takebe Yoko
公开号:US20050234206A1
公开(公告)日:2005-10-20
A fluoropolymer (A) having units derived from monomer units formed by cyclopolymerization of at least one fluorinated diene selected from a fluorinated diene represented by the formula (1) and a fluorinated diene represented by the formula (2), and units derived from monomer units formed by cyclopolymerization of a fluorinated diene represented by the formula (3):
CF
2
═CFCF
2
—C(CF
3
)(OR
1
)—CH
2
CH═CH
2
(1)
CF
2
═CFCH
2
—CH((CH
2
)
n
C(CF
3
)
2
(OR
1
))—CH
2
CH═CH
2
(2)
CF
2
═CFCH
2
—CH(COOR
2
)—CH
2
CH═CH
2
(3)
wherein R
1
represents a hydrogen atom, a blocked group of a hydroxyl group capable of being converted into a hydrogen atom by an acid, or a blocked carboxyl group-containing organic group capable of being converted into a carboxyl group-containing organic group by an acid, R
2
represents a hydrocarbon group having at most 20 carbon atoms, and n represents 0 or 1.
一种含氟聚合物 (A),具有由至少一种选自式 (1) 所示含氟二烯和式 (2) 所示含氟二烯的含氟二烯环聚合而成的单体单元衍生的单元,以及由式 (3) 所示含氟二烯环聚合而成的单体单元衍生的单元:
CF
2
═CFCF
2
-C(CF
3
)(或
1
)-CH
2
CH═CH
2
(1)
CF
2
═CFCH
2
-CH((CH
2
)
n
C(CF
3
)
2
(或
1
))-CH
2
CH═CH
2
(2)
CF
2
═CFCH
2
-CH(COOR
2
)-CH
2
CH═CH
2
(3)
其中 R
1
代表氢原子、能被酸转化为氢原子的羟基封端基团或能被酸转化为含羧基有机基团的含羧基封端基团, R
2
代表最多具有 20 个碳原子的烃基,n 代表 0 或 1。