(3-Ethenylphenyl)methanethiol | 113538-78-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-Ethenylphenyl)methanethiol
• CAS: 113538-78-6
• 化学式: C₉H₁₀S
• 分子量: 150.24
• InChiKey: HJTQTAIMPQUEDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Novel resin for optical material
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0874016A2

  公开（公告）日：1998-10-28

  A resinous composition is herein disclosed which comprises a compound having, in one molecule, one or more of structures represented by the formula (1)    wherein R1 is a hydrocarbon having 1 to 10 carbon atoms; R2, R3 and R4 are each hydrogen or a hydrocarbon group having 1 to 10 carbon atoms; and X is S or O, and an existing ratio of S is 50% or more on the average with respect to the total of S and O constituting a three-membered ring, and another compound having one or more SH groups in one molecule. According to the present invention, a novel sulfur-containing compound having an episulfide structure can be polymerized to obtain a resin for an optical material whose oxidation resistance is improved.

  本发明公开了一种树脂组合物，该树脂组合物包含一种化合物，该化合物在一个 分子中具有一个或多个由式(1)表示的结构 其中 R1 是具有 1 至 10 个碳原子的碳氢化合物；R2、R3 和 R4 分别是氢或具有 1 至 10 个碳原子的碳氢化合物基团；X 是 S 或 O，且相对于构成三元环的 S 和 O 的总和，S 的现有比例平均为 50%或以上、 以及在一个分子中含有一个或多个 SH 基团的另一种化合物。 根据本发明，具有表硫化物结构的新型含硫化合物可以通过聚合得到一种抗氧化性得到改善的光学材料树脂。
• Epoxy/episulfide resin compositions for optical materials
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0921417A2

  公开（公告）日：1999-06-09

  A composition for a resin which comprises a compound having one or more active hydrogen atoms in one molecule and a compound having one or more structures represented by the following formula (1) in one molecule: wherein R1 represents a hydrocarbon group having 1 to 10 carbon atoms, R2, R3 and R4 each represents hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, X represents S or O and an average number of S represented by X is about 50% or more of a total number of S and O constituting the three-member ring. A resin obtained from the novel sulfur-containing compound has an excellent tint performance.

  一种树脂组合物，它包括在一个分子中具有一个或多个活性氢原子的化合物和在一个分子中具有一个或多个下式(1)所代表结构的化合物： 其中 R1 代表具有 1 至 10 个碳原子的烃基，R2、R3 和 R4 各代表氢原子或具有 1 至 10 个碳原子的烃基，X 代表 S 或 O，且 X 所代表的 S 的平均数目约为构成三元环的 S 和 O 总数的 50%或以上。 由新型含硫化合物制得的树脂具有优异的着色性能。
• Process for tinting a resin having a large refractivity index and optical material tinted by the process
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0928802A2

  公开（公告）日：1999-07-14

  A process for tinting a resin comprising dipping the resin into a liquid containing at least one compound selected from the group consisting of polar inorganic compounds and polar organic compounds and subsequently tinting the resin, wherein the resin is obtained by curing by polymerization of a compound alone or a composition comprising the compound, the compound having in the molecule thereof one or more structures represented by the following formula (1): wherein R1 represents a hydrocarbon group having 1 to 10 carbon atoms, R2, R3 and R4 each represents hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, Y represents S or O and n represents 0 or 1. A novel resin comprising the compound having sulfur can be tinted in accordance with the present process.

  一种树脂着色工艺，包括将树脂浸入含有至少一种选自由极性无机化合物和极性有机化合物组成的组中的化合物的液体中，然后对树脂进行着色，其中树脂是通过单独的化合物或含有该化合物的组合物的聚合固化而得到的，该化合物在其分子中具有下式(1)所代表的一个或多个结构： 其中 R1 代表具有 1 至 10 个碳原子的烃基，R2、R3 和 R4 各自代表氢原子或具有 1 至 10 个碳原子的烃基，Y 代表 S 或 O，n 代表 0 或 1。 包含含硫化合物的新型树脂可根据本工艺进行着色。
• Composition for a resin
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP0936233A2

  公开（公告）日：1999-08-18

  A composition comprising a compound having one or more episulfide groups and/or epoxy groups in one molecule and a compound having one or more isocyanate groups and/or thioisocyanate groups in one molecule. The composition for a resin comprising a sulfur-containing compound exhibits an excellent balance between a refractivity index and an Abbe number and has a large impact resistance.

  一种组合物，包含在一个分子中含有一个或多个环硫基团和/或环氧基团的化合物，以及在一个分子中含有一个或多个异氰酸酯基团和/或硫代异氰酸酯基团的化合物。 包含含硫化合物的树脂组合物在折射率和阿贝数之间表现出极佳的平衡，并具有很强的抗冲击性。