3,7-dibromo-N-(4-n-butylphenyl)phenoxazine | 536762-20-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,7-dibromo-N-(4-n-butylphenyl)phenoxazine
• 英文别名: 3,7-Dibromo-10-(4-butylphenyl)-10h-phenoxazine；3,7-dibromo-10-(4-butylphenyl)phenoxazine
• CAS: 536762-20-6
• 化学式: C₂₂H₁₉Br₂NO
• 分子量: 473.207
• InChiKey: YIUXVMNZXOLRHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,7-dibromo-N-(4-n-butylphenyl)phenoxazine 、 联硼酸频那醇酯 在 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 作用下， 生成 10-(4-Butylphenyl)-3,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxazine
  参考文献：
  名称：

  KR101581491

  摘要：

  公开号：

文献信息

• [EN] AROMATIC MONOMER-AND CONJUGATED POLYMER-METAL COMPLEXES<br/>[FR] COMPLEXES METALLIQUES A BASE DE MONOMERE AROMATIQUE ET DE POLYMERE CONJUGUE
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2005016945A1

  公开（公告）日：2005-02-24

  A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.

  描述了一种用于制备电子设备（如发光二极管(LED)设备）聚合物的卤代芳香单体-金属复合物。该芳香单体-金属复合物设计包括一个破坏共轭的连接基团，从而有利地减少或防止芳香单体片段与金属复合物片段之间的电子共轭。破坏共轭通常是为了保留从芳香单体-金属复合物形成的聚合物中金属复合物的磷光发射特性。由此产生的共轭电致发光聚合物具有精确控制的金属配合和电子性质，这些性质与聚合物主链的性质基本或完全独立。
• DICARBAZOLE AROMATIC AMINE POLYMERS AND ELECTRONIC DEVICES
  申请人：Yu Wanglin

  公开号：US20090066224A1

  公开（公告）日：2009-03-12

  A conjugated or partially conjugated polymer comprising a structural unit of Formula I: I Wherein Ar1 is an aromatic group which contains one or more heteroatoms, or an aromatic group which comprises one or more fused aromatic or non-aromatic rings, said aromatic group may be substituted or unsubstituted; and R1 is alkyl, alkoxy, and aryl group, cyano, or F.

  一种包含结构单元 Formula I 的共轭或部分共轭聚合物：I 其中 Ar1 是含有一个或多个杂原子的芳香基团，或者是包含一个或多个融合芳香环或非芳香环的芳香基团，所述芳香基团可以是取代或未取代的；而 R1 是烷基、烷氧基和芳基、氰基或 F。
• METHOD FOR PRODUCING AROMATIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20150322101A1

  公开（公告）日：2015-11-12

  A method is provided for producing an aromatic compound, including a step of mixing a compound represented by formula (A) and a compound represented by formula (B): in the presence of at least one phosphine compound selected from the group consisting of a phosphine represented by formula (C) and a phosphonium salt represented by formula (F): a base, a palladium compound, and an aprotic organic solvent.

  提供一种生产芳香化合物的方法，包括以下步骤：在至少一种磷化物化合物的存在下，将由化学式(A)表示的化合物与由化学式(B)表示的化合物混合；所述磷化物化合物选择自由化学式(C)表示的磷化物和由化学式(F)表示的磷酸盐；还包括碱、钯化合物和无水有机溶剂。
• [EN] HALOGENATED BISDIARYLAMINOPOLYCYLIC AROMATIC COMPOUNDS AND POLYMERS THEREOF<br/>[FR] COMPOSES AROMATIQUES POLYCYCLIQUES BISDIARYLAMINO HALOGENES ET LEURS POLYMERES
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2005049546A1

  公开（公告）日：2005-06-02

  A halogenated bisdiarylaminopolycyclic aromatic compound, polymers made therefrom, and polymeric light emitting diode devices using the polymers are described. The halogenated compound is represented by formula (I), wherein Ar and Ar' are each independently substituted or unsubstituted aryl groups and Z is a polycyclic arylene group, wherein at least one of the Ar' groups is a haloaryl group. Devices using polymers prepared from the halogenated compound exhibit improved performance and longer lifetime, presumably as a result of the presence of the geometrically constrained diarylaminopolycyclic aromatic groups in the polymer backbone.

  描述了一种卤代双二芳胺多环芳香化合物，以及由此制成的聚合物和使用这些聚合物的聚合物发光二极管器件。卤代化合物由式(I)表示，其中Ar和Ar'分别是取代或未取代的芳基，Z是多环芳基，其中至少一个Ar'基团是卤代芳基。使用从该卤代化合物制备的聚合物的器件表现出改善的性能和更长的寿命，可能是由于聚合物骨架中存在几何约束的双芳胺多环芳香基团。
• Tricyclic arylamine containing polymers and electronic devices therefrom
  申请人：——

  公开号：US20040127666A1

  公开（公告）日：2004-07-01

  A composition comprising a polymer comprising a repeat unit of Formula I.: 1 wherein R 1 is independently in each occurrence H, C 1-40 hydrocarbyl or C 3-40 hydrocarbyl containing one or more S, N, O, P or Si atoms, or both of R 1 together with the 9-carbon on the fluorene, may form a C 5-20 ring structure which may contain one or more S, N, or O atoms; R2 is independently in each occurrence C 1-20 hydrocarbyl, C 1-20 hydrocarbyloxy, C 1-20 thioether, C 1-20 hydrocarbyloxycarbonyl, C 1-20 hydrocarbylcarbonyloxy, or cyano; a is independently in each occurrence, 0 or 1; X is O, S, SO 2 , C(R 3 ) 2 or N—R 3 wherein R 3 is aryl or substituted aryl of C 6 to C 40 , aralkyl of C 6 to C 24 , or alkyl of C 1 to C 24 . Preferably R 3 is aryl of C 6 to C 24 and more preferably R 3 is an alkylated aryl group of C 6 to C 24 ; Ar is an aryl or heteroaryl group of C 6 to C 40 or substituted aryl or heteroaryl group of C 6 to C 40 , preferably C 6 -C 24 , and most preferably C 6 -C 14 . Y is a conjugated moiety that can vary in each occurrence of the repeat unit.

  一种组合物，包括聚合物，其包含化学式I中的重复单元：1其中R1在每次出现时独立地为H、C1-40烃基或含有一个或多个S、N、O、P或Si原子的C3-40烃基，或R1与芴上的第9个碳共同形成一个C5-20环结构，该环结构可以包含一个或多个S、N或O原子；R2在每次出现时独立地为C1-20烃基、C1-20烃氧基、C1-20硫醚、C1-20烃氧羰基、C1-20烃基羰基氧基或氰基；a在每次出现时独立地为0或1；X为O、S、SO2、C(R3)2或N—R3，其中R3为C6到C40的芳基或取代芳基、C6到C24的芳基烷基或C1到C24的烷基。优选的是，R3为C6到C24的芳基，更优选的是R3为C6到C24的烷基化芳基基团；Ar为C6到C40的芳基或杂环芳基基团或取代的C6到C40的芳基或杂环芳基基团，优选为C6-C24，最优选为C6-C14。Y为共轭基团，在重复单元的每次出现中可以变化。