10-(4-Butylphenyl)-10H-phenoxazine | 713761-15-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-(4-Butylphenyl)-10H-phenoxazine
• 英文别名: 10-(4-butylphenyl)phenoxazine
• CAS: 713761-15-0
• 化学式: C₂₂H₂₁NO
• 分子量: 315.4
• InChiKey: DMMIIDVHNJDVBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三(邻甲基苯基)磷 、 吩噁嗪 、 对丁基溴苯 、 sodium t-butanolate 、 盐酸 在 醋酸钯 甲苯 、 Toluol, Methanol 作用下， 以 甲苯 为溶剂， 反应 16.33h， 以to obtain N-(4-n-butylphenyl)phenoxazine的产率得到10-(4-Butylphenyl)-10H-phenoxazine
  参考文献：
  名称：

  COPOLYMER AND POLYMER LIGHT EMITTING DEVICE USING THE SAME

  摘要：

  一种共聚物，包含如下式(1)的重复单元和如下式(2)的重复单元：（其中，环A和环B各自独立地表示具有取代基的芳香环。X是-O-、-S-、-S（═O）-、-S（═O）2-、-Si（R1）2-Si（R1）2-、-Si（R1）2-、-、-B（R1）-、-P（R1）-、-P（═O）（R1）-、-O-C（R1）2-或-N═C（R1）-，R1表示一个取代基。当在同一式中有两个或更多的R1时，它们可以相同或不同。）（其中，Y是-O-、-S-或-C（═O）-。Ar1表示一个具有取代基的芳基团或一个具有取代基的单价杂环基团，并且没有取代基连接到Ar1的环上的原子，这些原子相邻于公式中连接到氮原子的Ar1的原子。R3表示一个取代基，n表示从0到3的整数。当在公式中有两个或更多的R2时，它们可以相同或不同。）

  公开号：

  US20100176376A1

文献信息

• Tricyclic arylamine containing polymers and electronic devices therefrom
  申请人：——

  公开号：US20040127666A1

  公开（公告）日：2004-07-01

  A composition comprising a polymer comprising a repeat unit of Formula I.: 1 wherein R 1 is independently in each occurrence H, C 1-40 hydrocarbyl or C 3-40 hydrocarbyl containing one or more S, N, O, P or Si atoms, or both of R 1 together with the 9-carbon on the fluorene, may form a C 5-20 ring structure which may contain one or more S, N, or O atoms; R2 is independently in each occurrence C 1-20 hydrocarbyl, C 1-20 hydrocarbyloxy, C 1-20 thioether, C 1-20 hydrocarbyloxycarbonyl, C 1-20 hydrocarbylcarbonyloxy, or cyano; a is independently in each occurrence, 0 or 1; X is O, S, SO 2 , C(R 3 ) 2 or N—R 3 wherein R 3 is aryl or substituted aryl of C 6 to C 40 , aralkyl of C 6 to C 24 , or alkyl of C 1 to C 24 . Preferably R 3 is aryl of C 6 to C 24 and more preferably R 3 is an alkylated aryl group of C 6 to C 24 ; Ar is an aryl or heteroaryl group of C 6 to C 40 or substituted aryl or heteroaryl group of C 6 to C 40 , preferably C 6 -C 24 , and most preferably C 6 -C 14 . Y is a conjugated moiety that can vary in each occurrence of the repeat unit.

  一种组合物，包括聚合物，其包含化学式I中的重复单元：1其中R1在每次出现时独立地为H、C1-40烃基或含有一个或多个S、N、O、P或Si原子的C3-40烃基，或R1与芴上的第9个碳共同形成一个C5-20环结构，该环结构可以包含一个或多个S、N或O原子；R2在每次出现时独立地为C1-20烃基、C1-20烃氧基、C1-20硫醚、C1-20烃氧羰基、C1-20烃基羰基氧基或氰基；a在每次出现时独立地为0或1；X为O、S、SO2、C(R3)2或N—R3，其中R3为C6到C40的芳基或取代芳基、C6到C24的芳基烷基或C1到C24的烷基。优选的是，R3为C6到C24的芳基，更优选的是R3为C6到C24的烷基化芳基基团；Ar为C6到C40的芳基或杂环芳基基团或取代的C6到C40的芳基或杂环芳基基团，优选为C6-C24，最优选为C6-C14。Y为共轭基团，在重复单元的每次出现中可以变化。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Soga Masayuki

  公开号：US20120199825A1

  公开（公告）日：2012-08-09

  An organic electroluminescent device comprising an anode, a cathode, a light emitting layer that is disposed between the anode and the cathode and contains a first light emitting layer material containing a phosphorescent compound and a second light emitting layer material containing a charge transporting polymer compound (that is, a light emitting layer containing a first light emitting layer material and a second light emitting layer material), and a hole transporting layer that is disposed between the anode and the light emitting layer so as to be adjacent to the light emitting layer and is composed of a hole transporting polymer compound, wherein the lowest excitation triplet energy T1 e (eV) of the first light emitting layer material, the lowest excitation triplet energy T1 h (eV) of the second light emitting layer material and the lowest excitation triplet energy T1 t (eV) of the hole transporting polymer compound satisfy the following formulae (A) and (B): T 1 e ≦T 1 h (A) T 1 t −T 1 e ≦0.10  (B). An organic electroluminescent device comprising an anode and a cathode, and a hole transporting layer and a light emitting layer disposed between the anode and the cathode, wherein the hole transporting layer contains 1) a mixture of 2,2′-bipyridine and/or 2,2′-bipyridine derivative and a non-2,2′-bipyridinediyl group-containing hole transporting polymer compound, 2) a 2,2′-bipyridinediyl group-containing polymer compound having a constitutional unit composed of an unsubstituted or substituted 2,2′-bipyridinediyl group, and at least one constitutional unit selected from the group consisting of constitutional units composed of a divalent aromatic amine residue and constitutional units composed of an unsubstituted or substituted arylene group, or a combination thereof.

  一种有机电致发光器件，包括阳极、阴极、位于阳极和阴极之间且含有第一发光层材料和第二发光层材料的发光层（即含有第一发光层材料和第二发光层材料的发光层），其中第一发光层材料含有磷光化合物，第二发光层材料含有电荷传输聚合物化合物，以及位于阳极和发光层之间以与发光层相邻的方式设置的孔传输层，由孔传输聚合物化合物组成，其中第一发光层材料的最低激发三重态能量T1e（eV）、第二发光层材料的最低激发三重态能量T1h（eV）和孔传输聚合物化合物的最低激发三重态能量T1t（eV）满足以下公式（A）和（B）：T1e≦T1h（A）T1t−T1e≦0.10（B）。一种有机电致发光器件，包括阳极和阴极、孔传输层和发光层，位于阳极和阴极之间，其中孔传输层包含1）2,2′-联吡啶和/或2,2′-联吡啶衍生物的混合物和不含2,2′-联吡啶基团的孔传输聚合物化合物，2）具有由未取代或取代的2,2′-联吡啶基团组成的构成单元和至少选自由双价芳香胺残基和由未取代或取代的芳基烃基组成的构成单元之一的构成单元的2,2′-联吡啶基团含量聚合物化合物，或其组合。
• COPOLYMER AND POLYMER LIGHT EMITTING DEVICE USING THE SAME
  申请人：Suzuki Tomoyuki

  公开号：US20100176376A1

  公开（公告）日：2010-07-15

  A copolymer comprising a repeating unit of the following formula (1) and a repeating unit of the following formula (2): (wherein, a ring A and ring B represent each independently an aromatic ring optionally having a substituent. X is —O—, —S—, —S(═O)—, —S(═O) 2 —, —Si(R 1 ) 2 —Si(R 1 ) 2 —, —Si(R 1 ) 2 —, —, —B(R 1 )—, —P(R 1 )—, —P(═O)(R 1 )—, —O—C(R 1 ) 2 — or —N═C(R 1 )—, and R 1 represents a substituent. When there are two or more R 1 s in the same formula, they may be the same or different.) (wherein, Y is —O—, —S— or —C(═O)—. Ar 1 represents an aryl group optionally having a substituent or a monovalent heterocyclic group optionally having a substituent, and there is no substituent connected to atoms of the ring of Ar 1 , the atoms being adjacent an atom of Ar 1 connected to a nitrogen atom in the formula. R 3 represents a substituent, and n represents an integer of from 0 to 3. When there are two or more R 2 s in the formula, they may be the same or different.).

  一种共聚物，包含如下式(1)的重复单元和如下式(2)的重复单元：（其中，环A和环B各自独立地表示具有取代基的芳香环。X是-O-、-S-、-S（═O）-、-S（═O）2-、-Si（R1）2-Si（R1）2-、-Si（R1）2-、-、-B（R1）-、-P（R1）-、-P（═O）（R1）-、-O-C（R1）2-或-N═C（R1）-，R1表示一个取代基。当在同一式中有两个或更多的R1时，它们可以相同或不同。）（其中，Y是-O-、-S-或-C（═O）-。Ar1表示一个具有取代基的芳基团或一个具有取代基的单价杂环基团，并且没有取代基连接到Ar1的环上的原子，这些原子相邻于公式中连接到氮原子的Ar1的原子。R3表示一个取代基，n表示从0到3的整数。当在公式中有两个或更多的R2时，它们可以相同或不同。）
• Biscarbazol-9-Yl-Substituted Triarylamine-Containing Polymers and Electronic Devices
  申请人：Yu Wanglin

  公开号：US20080265755A1

  公开（公告）日：2008-10-30

  A conjugated or partially conjugated polymer including a structural unit of Formula (I); where T is an aryl or heteroaryl group that may be substituted or unsubstituted, or a C1-C24 alkyl group; R1 is alkyl, alkoxy, aryl group, cyano, or F; and a and b are independently selected from 1, 2 or 3. In addition, a composition of Formula (IV); wherein X is a halogen or a boronate group.

  一种共轭或部分共轭聚合物，包括式（I）的结构单元;其中T是取代或未取代的芳基或杂芳基基团，或C1-C24烷基基团;R1是烷基，烷氧基，芳基，氰基或F; a和b分别选择为1、2或3。此外，还包括式（IV）的组合物;其中X是卤素或硼酸酯基团。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2492988A1

  公开（公告）日：2012-08-29

  An organic electroluminescent device comprising an anode, a cathode, a light emitting layer that is disposed between the anode and the cathode and contains a first light emitting layer material containing a phosphorescent compound and a second light emitting layer material containing a charge transporting polymer compound (that is, a light emitting layer containing a first light emitting layer material and a second light emitting layer material), and a hole transporting layer that is disposed between the anode and the light emitting layer so as to be adjacent to the light emitting layer and is composed of a hole transporting polymer compound, wherein the lowest excitation triplet energy T1e (eV) of the first light emitting layer material, the lowest excitation triplet energy T1h (eV) of the second light emitting layer material and the lowest excitation triplet energy T1t (eV) of the hole transporting polymer compound satisfy the following formulae (A) and (B): An organic electroluminescent device comprising an anode and a cathode, and a hole transporting layer and a light emitting layer disposed between the anode and the cathode, wherein the hole transporting layer contains 1) a mixture of 2,2'-bipyridine and/or 2,2'-bipyridine derivative and a non-2,2'-bipyridinediyl group-containing hole transporting polymer compound, 2) a 2,2'-bipyridinediyl group-containing polymer compound having a constitutional unit composed of an unsubstituted or substituted 2,2'-bipyridinediyl group, and at least one constitutional unit selected from the group consisting of constitutional units composed of a divalent aromatic amine residue and constitutional units composed of an unsubstituted or substituted arylene group, or a combination thereof.

  一种有机电致发光器件，包括阳极、阴极、位于阳极和阴极之间并包含含有磷光化合物的第一发光层材料和含有电荷传输聚合物化合物的第二发光层材料的发光层（即包含第一发光层材料和第二发光层材料的发光层）、以及一个空穴传输层，该层设置在阳极和发光层之间，与发光层相邻，由空穴传输高分子化合物组成，其中第一发光层材料的最低激发三重能 T1e（eV）、第二发光层材料的最低激发三重能 T1h（eV）和空穴传输高分子化合物的最低激发三重能 T1t（eV）满足下式（A）和（B）： 一种有机电致发光器件，包括阳极和阴极，以及设置在阳极和阴极之间的空穴传输层和发光层，其中空穴传输层包含 1) 2,2'-联吡啶和/或 2,2'-联吡啶衍生物与非 2,2'-联吡啶二基含空穴传输聚合物化合物的混合物，2) 2、2)一种含 2,2'-联吡啶二基的聚合物化合物，具有一个由未取代或取代的 2,2'-联吡啶二基组成的构型单元，以及至少一个选自由二价芳香族胺残基组成的构型单元和由未取代或取代的芳烯基组成的构型单元组成的组的构型单元，或它们的组合。