Propan-2-yl phenyl(2,4,6-trimethylbenzoyl)phosphinate | 91920-04-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Propan-2-yl phenyl(2,4,6-trimethylbenzoyl)phosphinate
• 英文别名: [phenyl(propan-2-yloxy)phosphoryl]-(2,4,6-trimethylphenyl)methanone
• CAS: 91920-04-6
• 化学式: C₁₉H₂₃O₃P
• 分子量: 330.4
• InChiKey: QSZJAPUVYYDAPU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] PROCESS AND INTERMEDIADES FOR THE PREPARATION OF 7-ALKYLATED STEROIDS<br/>[FR] PROCÉDÉ ET INTERMÉDIAIRES POUR LA PRÉPARATION DE STÉROÏDES 7-ALKYLÉS
  申请人：CRYSTAL PHARMA SAU

  公开号：WO2015181116A1

  公开（公告）日：2015-12-03

  A process for preparing compounds of formula (I), or a salt, solvate or stereoisomer thereof, including Fulvestrant, which process comprises free radical to a compound of formula (III), or a salt, solvate or stereoisomer thereof. The invention also refers to intermediates of said process.

  一种制备式(I)化合物的方法，或者其盐、溶剂合物或立体异构体，包括富马酸苯甲酸酯（Fulvestrant）的方法，该方法包括自由基向式(III)化合物转化的步骤，或者其盐、溶剂合物或立体异构体。该发明还涉及所述方法的中间体。
• COPOLYMERS INCLUDING A TRIAZINE GROUP AND COMPOSITIONS INCLUDING THEM
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20170198119A1

  公开（公告）日：2017-07-13

  An ultraviolet light-absorbing oligomer that includes a first divalent unit represented by formula (I): and a second divalent unit represented by formula (II): Each R 1 is independently hydrogen or methyl; V is O or NH; X is bond or X is alkylene or alkyleneoxy group having from 1 to 10 carbon atoms and optionally interrupted by one or more —O— groups and optionally substituted by a hydroxyl group; and R2 is alkyl having from 1 to 22 carbon atoms. Compositions that include fluoropolymers and the oligomers are disclosed. The composition can be an extruded film. Compositions that include pressure sensitive adhesives and these oligomers are disclosed.

  一种包括由式(I)表示的第一二价单元和由式(II)表示的第二二价单元的紫外光吸收寡聚物：每个R1独立地是氢或甲基；V为O或NH；X为键或X为含有1至10个碳原子的烷基或烷氧基团，并且可以被一个或多个—O—基团中断，并且可以被一个羟基取代；R2是具有1到22个碳原子的烷基。公开了包括氟聚合物和这些寡聚物的组合物。该组合物可以是挤压薄膜。公开了包括压敏胶粘剂和这些寡聚物的组合物。
• [EN] BENZOTHIAZOL-2-YLAZO-PHENYL COMPOUND AS DYE, COMPOSITIONS INCLUDING THE DYE, AND METHOD OF DETERMINING DEGREE OF CURE OF SUCH COMPOSITIONS<br/>[FR] COMPOSÉ DE BENZOTHIAZOL-2-YLAZO-PHÉNYLE EN TANT QUE COLORANT, COMPOSITIONS INCLUANT LE COLORANT, ET PROCÉDÉ DE DÉTERMINATION DU DEGRÉ DE DURCISSEMENT DE CES COMPOSITIONS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2014151708A1

  公开（公告）日：2014-09-25

  A compound represented by formula: is disclosed. R is hydrogen or alkyl; X is alkylene; Y is a bond, ether, thioether, amine, amide, ester, thioester, carbonate, thiocarbonate, carbamate, thiocarbamate, urea, thiourea, alkylene, arylalkylene, alkylarylene, or arylene, wherein alkylene, arylalkylene, alkylarylene, and arylene are optionally at least one of interrupted or terminated by at least one of an ether, thioether, amine, amide, ester, thioester, carbonate, thiocarbonate, carbamate, thiocarbamate, urea, or thiourea; and Z is an acrylate, a methacrylate, an acrylamide, a methacrylamide, a styrenyl, or a terminal alkenylene having at least three carbon atoms. A composition including the compound, and a method of determining the degree of cure of a curable polymeric resin are also disclosed.

  揭示了一种由以下公式表示的化合物。R是氢或烷基；X是烷基；Y是键合，醚，硫醚，胺，酰胺，酯，硫酯，碳酸酯，硫代碳酸酯，氨基甲酸酯，硫代氨基甲酸酯，脲，硫代脲，烷基，芳基烷基，烷基芳基，或芳基，其中烷基，芳基烷基，烷基芳基和芳基可以选择至少一个被醚，硫醚，胺，酰胺，酯，硫酯，碳酸酯，硫代碳酸酯，氨基甲酸酯，硫代氨基甲酸酯，脲或硫代脲中的至少一个中断或终止；Z是丙烯酸酯，甲基丙烯酸酯，丙烯酰胺，甲基丙烯酰胺，苯乙烯基，或至少有三个碳原子的末端烯烃基。还公开了包含该化合物的组合物和确定可固化聚合物树脂固化程度的方法。
• COMPOSITIONS INCLUDING A POLYTHIOL, AN UNSATURATED COMPOUND, AND A DYE AND METHODS RELATING TO SUCH COMPOSITIONS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160319106A1

  公开（公告）日：2016-11-03

  A curable composition having a polythiol; at least one unsaturated compound comprising two or more carbon-carbon double bonds, carbon-carbon triple bonds, or a combination thereof; and a dye compound represented by formula: A crosslinked composition prepared from the curable composition, a method for indicating curing in a curable composition, and a method of stabilizing a curable composition comprising a polythiol and at least one unsaturated compound comprising two or more carbon-carbon double bonds, carbon-carbon triple bonds, or a combination thereof are also disclosed.

  本发明涉及一种可治愈组合物，其中包括聚硫醇；至少一种包含两个或多个碳-碳双键、碳-碳三键或其组合的不饱和化合物；以及由公式表示的染料化合物：制备自可治愈组合物的交联组合物，一种指示可治愈组合物中固化的方法，以及一种稳定聚硫醇和至少一种包含两个或多个碳-碳双键、碳-碳三键或其组合的不饱和化合物的可治愈组合物的方法也被揭示。
• METHODS OF USING STABLE HYDROCARBON FOAMS
  申请人：Savu Patricia M.

  公开号：US20100025038A1

  公开（公告）日：2010-02-04

  A method of treating a subterranean geological formation comprising hydrocarbons comprising injecting a foam into the formation at a rate and pressure sufficient to open at least one fracture therein and a method of completing a well in a subterranean geological formation penetrated by a well bore comprising introducing a foam into the well bore of the subterranean geological formation and carrying out a completion operation in the well bore of the subterranean geological formation. The foam comprises a liquid hydrocarbon and a nonionic polymeric surfactant comprising fluorinated repeating units, wherein the fluorinated repeating units have up to 5 perfluorinated carbon atoms, and wherein a one weight percent solution of the nonionic polymeric surfactant in kerosene has a foam half-life at 22° C. of at least 10 minutes.

  一种处理含有碳氢化合物的地下地质形成物的方法，包括以足够的速率和压力向该形成物中注入泡沫，以打开至少一个其中的裂缝；以及一种在被井孔穿透的地下地质形成物中完成井的方法，包括将泡沫引入该地下地质形成物的井孔中，并在该地下地质形成物的井孔中进行完井操作。该泡沫包括液态碳氢化合物和一种非离子型聚合物表面活性剂，其中所述的氟重复单元具有最多5个全氟碳原子，并且在煤油中的1重量％溶液在22°C下的泡沫半衰期至少为10分钟。