1-benzyl-1,2,2-tribromocyclopropane | 455272-06-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-benzyl-1,2,2-tribromocyclopropane
• 英文别名: 1,2,2-tribromo-1-benzylcyclopropane；(1,2,2-tribromocyclopropyl)methylbenzene
• CAS: 455272-06-7
• 化学式: C₁₀H₉Br₃
• 分子量: 368.893
• InChiKey: CHSIOQMKWIXXAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-benzyl-1,2,2-tribromocyclopropane 生成 1-benzylcyclopropene
  参考文献：
  名称：

  Cyclopropane precursors of ethylene response inhibitors in plants

  摘要：

  公开号：

  EP1388529B1

文献信息

• Method to inhibit ethylene responses in plants
  申请人：Jacobson Martin Richard

  公开号：US20050065033A1

  公开（公告）日：2005-03-24

  The present invention generally relates to methods of inhibiting ethylene responses in plants and plant materials, and particularly relates to methods of inhibiting various ethylene responses including plant maturation and degradation, by exposing plants to cyclopropene derivatives and compositions thereof wherein: 1) at least one substituent on the cyclopropene ring contains a carbocyclic or heterocyclic ring, or 2) . a substituent contains silicon, sulfur, phosphorous, or boron, or 3) least one substituent contains from one to four non-hydrogen atoms and at least one substituent contains more than four non-hydrogen atoms.

  本发明一般涉及抑制植物和植物材料中乙烯反应的方法，特别涉及通过将植物暴露于环丙烯衍生物和其组合物中来抑制各种乙烯反应，包括植物成熟和降解，其中：1）环丙烯环上至少一个取代基含有碳环或杂环，或2）一个取代基含有硅、硫、磷或硼，或3）至少一个取代基含有一到四个非氢原子，且至少一个取代基含有多于四个非氢原子。
• Stable ethylene inhibiting compounds and methods for their preparation
  申请人：——

  公开号：US20040077502A1

  公开（公告）日：2004-04-22

  A method to inhibit the ethylene response in plants with cyclopropene compounds by first generating stable cyclopropane precursor compounds and then converting these compounds to the gaseous cyclopropene antagonist compound by use of a reducing or nucleophilic agent.

  一种通过首先生成稳定的环丙烷前体化合物，然后通过使用还原剂或亲核试剂将这些化合物转化为气态环丙烯拮抗剂化合物，以抑制植物中乙烯反应的方法。
• Stable Ethylene Inhibiting Compounds and Methods for Their Preparation
  申请人：Jacobson Richard Martin

  公开号：US20100184600A1

  公开（公告）日：2010-07-22

  A method to inhibit the ethylene response in plants with cyclopropene compounds by first generating stable cyclopropane precursor compounds and then converting these compounds to the gaseous cyclopropene antagonist compound by use of a reducing or nucleophilic agent.

  一种抑制植物乙烯响应的方法，首先生成稳定的环丙烷前体化合物，然后通过还原或亲核试剂将这些化合物转化为气态的环丙烯拮抗剂化合物。
• METHOD TO INHIBIT ETHYLENE RESPONSES IN PLANTS
  申请人：Jacobson Richard Martin

  公开号：US20110190137A1

  公开（公告）日：2011-08-04

  The present invention generally relates to methods of inhibiting ethylene responses in plants and plant materials, and particularly relates to methods of inhibiting various ethylene responses including plant maturation and degradation, by exposing plants to cyclopropene derivatives and compositions thereof wherein: 1) at least one substituent on the cyclopropene ring contains a carbocyclic or heterocyclic ring, or 2) a substituent contains silicon, sulfur, phosphorous, or boron, or 3) least one substituent contains from one to four non-hydrogen atoms and at least one substituent contains more than four non-hydrogen atoms.

  本发明通常涉及抑制植物和植物材料中乙烯反应的方法，特别涉及通过将植物暴露于环丙烯衍生物和其组合物中来抑制各种乙烯反应，其中：1）环丙烯环上的至少一个取代基包含一个碳环或杂环，或2）取代基包含硅、硫、磷或硼，或3）至少一个取代基含有一到四个非氢原子，且至少一个取代基含有超过四个非氢原子。
• STABLE ETHYLENE INHIBITING COMPOUNDS AND METHODS FOR THEIR PREPARATION
  申请人：Jacobson Richard Martin

  公开号：US20130172191A1

  公开（公告）日：2013-07-04

  A method to inhibit the ethylene response in plants with cyclopropene compounds by first generating stable cyclopropane precursor compounds and then converting these compounds to the gaseous cyclopropene antagonist compound by use of a reducing or nucleophilic agent.

  一种使用环丙烯化合物抑制植物乙烯反应的方法，首先生成稳定的环丙烷前体化合物，然后通过还原剂或亲核试剂将这些化合物转化为气态环丙烯拮抗剂化合物。