申请人:OISHI Jitsuo
公开号:US20100187719A1
公开(公告)日:2010-07-29
A method for producing a colorless transparent resin film by a solution flow casting method containing: flow-casting an organic solvent solution of a polyamic acid or a polyimide on a support; and drying, the method containing at least the following step (1), step (2) and step (3) in this order, and an apparatus therefor:
(1) a step of flow-casting an organic solvent solution of a polyamic acid or polyamide on a support,
(2) a step of evaporating the organic solvent while blowing a gas having an oxygen content of from 0.001 to 15% by volume at a temperature of from 100 to 170° C. onto the flow-cast material, and releasing as a self-supporting film from the support, and
(3) a step of performing the following step (3-1) and step (3-2) in this order:
(3-1) a step of lowering a residual ratio of the organic solvent in the self-supporting film while blowing a gas having an oxygen content of 15% by volume or less at a temperature of from 100 to 250° C. onto the film by using at least one dryer of a type of blowing a heated gas, and
(3-2) a step of lowering the residual ratio of the organic solvent in the self-supporting film while blowing a gas having an oxygen content of 5% by volume or less at a temperature of from 150 to 400° C. onto the film by using at least one dryer of a type of blowing a heated gas.
一种通过溶液流铸法制备无色透明树脂薄膜的方法,包括:在支撑物上流铸聚酰胺酸或聚酰亚胺的有机溶剂溶液;并干燥,该方法至少包括以下步骤(1)、步骤(2)和步骤(3),并提供相应的设备:(1)在支撑物上流铸聚酰胺酸或聚酰亚胺的有机溶剂溶液;(2)在向流铸材料吹送氧含量为0.001至15%体积的气体的同时,蒸发有机溶剂,温度在100至170°C之间,从支撑物上释放为自支撑膜;(3)按照以下步骤(3-1)和步骤(3-2)的顺序执行:(3-1)在使用至少一种吹送加热气体的干燥器的情况下,以15%体积以下的氧含量的气体在100至250°C的温度下吹送,降低自支撑膜中有机溶剂的残留比率;(3-2)在使用至少一种吹送加热气体的干燥器的情况下,以5%体积以下的氧含量的气体在150至400°C的温度下吹送,降低自支撑膜中有机溶剂的残留比率。