6,13-dihydro-6,13-methanopentacene-15-one | 904913-36-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 并四苯
• 英文名称: 6,13-dihydro-6,13-methanopentacene-15-one
• 英文别名: 6,13-Dihydro-6,13-methanopentacen-15-one；hexacyclo[10.10.1.02,11.04,9.013,22.015,20]tricosa-2,4,6,8,10,13,15,17,19,21-decaen-23-one
• CAS: 904913-36-6
• 化学式: C₂₃H₁₄O
• 分子量: 306.364
• InChiKey: NOXKGSQPEBYYNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6,13-dihydro-6,13-methanopentacene-15-one 反应 1.0h， 生成 并五苯
  参考文献：
  名称：

  A new type of soluble pentacene precursor for organic thin-film transistors

  摘要：

  我们合成了一种新型的可溶性并五苯前体，它在 150 °C 下加热时会挤出一个单位的 CO，从而以接近定量的产量生成并五苯。

  DOI：

  10.1039/b616511g
• 作为产物：
  描述：

  6,13-dihydro-6,13-methano-15-tert-butoxypentacene 在 硫酸 、 水 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 、 二甲基亚砜 为溶剂， 反应 60.5h， 生成 6,13-dihydro-6,13-methanopentacene-15-one
  参考文献：
  名称：

  A new type of soluble pentacene precursor for organic thin-film transistors

  摘要：

  我们合成了一种新型的可溶性并五苯前体，它在 150 °C 下加热时会挤出一个单位的 CO，从而以接近定量的产量生成并五苯。

  DOI：

  10.1039/b616511g

文献信息

• SYNTHESIS AND APPLICATIONS OF SOLUBLE PENTACENE PRECURSORS AND RELATED COMPOUNDS
  申请人：CHOW Tahsin J.

  公开号：US20130017497A1

  公开（公告）日：2013-01-17

  The present disclosure relates to methods and systems for synthesis of bridged-hydropentacene, hydroanthracene and hydrotetracene from the precursor compounds pentacene derivatives, tetracene derivatives, and anthracene derivatives. The invention further relates to methods and systems for forming thin films for use in electrically conductive assemblies, such as semiconductors or photovoltaic devices.

  本公开涉及从前体化合物戊芴衍生物、四芴衍生物和蒽衍生物合成桥式水合五环芴、水合蒽和水合四环芴的方法和系统。本发明还涉及用于制备用于电导组件中的薄膜的方法和系统，例如半导体或光伏器件。
• A Large Starphene Comprising Pentacene Branches
  作者：Jan Holec、Beatrice Cogliati、James Lawrence、Alejandro Berdonces‐Layunta、Pablo Herrero、Yuuya Nagata、Marzena Banasiewicz、Boleslaw Kozankiewicz、Martina Corso、Dimas G. Oteyza、Andrej Jancarik、Andre Gourdon

  DOI：10.1002/anie.202016163

  日期：2021.3.29

  compounds for organic electronics and optics. However, the instability and low solubility of larger starphene homologs make their synthesis extremely challenging. Herein, we present a new strategy leading to pristine [16]starphene in preparative scale. Our approach is based on a synthesis of a carbonyl‐protected starphene precursor that is thermally converted in a solid‐state form to the neat [16]starphene

  由于苯乙炔具有独特的理化特性，因此它们是有吸引力的化合物，使它们成为有机电子和光学的有趣化合物。然而，较大的星形酚同系物的不稳定性和低溶解度使它们的合成极具挑战性。在本文中，我们提出了一种在制备规模上导致原始[16]星酚的新策略。我们的方法基于羰基保护的STarphene前体的合成，该前体以固态形式热转化为纯净的[16] STarphene，然后通过多种分析方法对其进行表征，例如13C CP‐MAS NMR，TGA，MS MALDI，UV / Vis和FTIR光谱 此外，高分辨率STM实验清楚地证实了其预期的结构，并揭示了并五苯臂之间的适度电子离域。还计算了独立于核的化学位移NICS（1）来调查其芳香特性。
• Type of soluble pentacene precursor
  申请人：Chow J. Tahsin

  公开号：US20070190254A1

  公开（公告）日：2007-08-16

  A novel soluble pentacene (C 22 H 14 ) precursor 6,13-dihydro-6,13-methanopentacene-15-one, a method for its production and intermediates therefor as well as pentacene films and coated surfaces. Thermolysis of the precursor at 150° C. to 350° C. induces an expulsion of carbon monoxide to generate pentacene in high yield. The high solubility of the precursor compound, as well as its production of non-contaminated pentacene, makes it an excellent material in the application of organic thin film transistors on surfaces.

  一种新型可溶性五环芘（C22H14）前体6,13-二氢-6,13-甲基五环芘-15-酮，以及其制备方法和中间体，以及五环芘薄膜和涂层表面。在150℃至350℃的温度下热解前体会引起一氧化碳的挥发，从而高产率地生成五环芘。前体化合物的高溶解度以及其产生无污染的五环芘，使其成为在表面上应用有机薄膜晶体管的优秀材料。
• Systems, structures and materials for electrochemical device thermal management
  申请人：Global Web Horizons, LLC

  公开号：US10431858B2

  公开（公告）日：2019-10-01

  This disclosure provides casings and materials for the thermal management and protection of an electrochemical cell. The casing may also comprise a composite polymeric material for electrochemical cell thermal management, the composite polymeric material comprising a crosslinked polyether polyol phase change material configured to be in physical contact with at least a portion of an electrochemical cell.

  本公开提供了用于电化学电池热管理和保护的外壳和材料。外壳还可包括用于电化学电池热管理的复合聚合材料，复合聚合材料包括交联聚醚多元醇相变材料，该材料被配置为与电化学电池的至少一部分进行物理接触。
• THERMAL MANAGEMENT FILMS CONTAINING PHASE CHANGE MATERIALS
  申请人：Outlast Technologies, LLC

  公开号：US20160223269A1

  公开（公告）日：2016-08-04

  A method is provided for manufacturing a polymeric film with thermal management capabilities. The method comprises mixing at least three compounds, wherein a first compound comprises a polymeric phase change material, a second compound comprises an additive, and a third compound comprises a molecule that, in its liquid form, acts as a solvent of the first and second compounds, and which is curable into a solid form as a polymer. Then, the method comprises applying a mixture of the first, second, and third compounds in a liquid form to a substrate, and curing the mixture into a solid state.