Bisphenol A phosphite (1:2) | 25058-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bisphenol A phosphite (1:2)
• 英文别名: [4-[2-(4-dihydroxyphosphanyloxyphenyl)propan-2-yl]phenyl] dihydrogen phosphite
• CAS: 25058-17-7
• 化学式: C₁₅H₁₈O₆P₂
• 分子量: 356.25
• InChiKey: SJFVAXDVZIQNMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  99.4
• 氢给体数：
  4
• 氢受体数：
  6

文献信息

• POLYCARBONATE DIOL, PROCESS FOR PRODUCING SAME, AND POLYURETHANE AND ACTINIC-ENERGY-RAY-CURABLE POLYMER COMPOSITION BOTH FORMED USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2559718A1

  公开（公告）日：2013-02-20

  The present invention provides a novel polycarbonate diol and a polyurethane using the polycarbonate diol as raw materials. The novel polycarbonate diol produces polycarbonate diol-based polyurethane which has a high degree of hardness, superior abrasion resistance, and superior hydrophilicity, and is usable for an application such as a paint, a coating agent, a synthetic leather, an artificial leather, and a highly-functional elastomers, or the like. The present invention also provides an active-energy radiation curable polymer composition giving a cured film having a superior contamination resistance and high degree of hardness. The present invention is obtained, for example, by reacting specific two types of diols with diester carbonate in the presence of a transesterification catalyst being a compound using a metal of Group 1 or 2 on the periodic table. The present invention provides a polycarbonate diol wherein the metal content of the transesterification catalyst is 100 weight ppm or less, a polyurethane obtainable by using this polycarbonate diol and an active-energy radiation curable polymer composition containing the urethane(meth)acrylate oligomer which is obtained from the polycarbonate diol.

  本发明提供了一种新型聚碳酸酯二元醇和一种以该聚碳酸酯二元醇为原料的聚氨酯。这种新型聚碳酸酯二元醇生产的聚碳酸酯二元醇基聚氨酯具有高硬度、优异的耐磨性和亲水性，可用于涂料、涂层剂、合成革、人造革和高功能弹性体等应用。本发明还提供了一种活性能量辐射固化聚合物组合物，其固化膜具有优异的抗污染性和高硬度。例如，本发明是通过使特定的两种二元醇与碳酸二酯在转酯化催化剂（使用元素周期表中第 1 或第 2 族金属的化合物）存在下发生反应而获得的。本发明提供了一种聚碳酸酯二元醇（其中酯交换催化剂的金属含量为 100 重量ppm 或更少）、一种可通过使用这种聚碳酸酯二元醇获得的聚氨酯，以及一种含有从聚碳酸酯二元醇中获得的聚氨酯（甲基）丙烯酸酯低聚物的主动能辐射固化聚合物组合物。
• POLYCARBONATE DIOL AND PRODUCING METHOD THEREOF, AND POLYURETHANE AND ACTIVE ENERGY RAY-CURABLE POLYMER COMPOSITION BOTH FORMED USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3459987A1

  公开（公告）日：2019-03-27

  The present invention provides a novel polycarbonate diol and a polyurethane using the polycarbonate diol as raw materials. The novel polycarbonate diol produces polycarbonate diol-based polyurethane which has a high degree of hardness, superior abrasion resistance, and superior hydrophilicity, and is usable for an application such as a paint, a coating agent, a synthetic leather, an artificial leather, and a highly-functional elastomers, or the like. The present invention also provides an active-energy radiation curable polymer composition giving a cured film having a superior contamination resistance and high degree of hardness. The present invention is obtained, for example, by reacting specific two types of diols with diester carbonate in the presence of a transesterification catalyst being a compound using a metal of Group 1 or 2 on the periodic table. The present invention provides a polycarbonate diol wherein the metal content of the transesterification catalyst is 100 weight ppm or less, a polyurethane obtainable by using this polycarbonate diol and an active-energy radiation curable polymer composition containing the urethane(meth)acrylate oligomer which is obtained from the polycarbonate diol.

  本发明提供了一种新型聚碳酸酯二元醇和一种以该聚碳酸酯二元醇为原料的聚氨酯。这种新型聚碳酸酯二元醇生产的聚碳酸酯二元醇基聚氨酯具有高硬度、优异的耐磨性和亲水性，可用于涂料、涂层剂、合成革、人造革和高功能弹性体等应用。本发明还提供了一种活性能量辐射固化聚合物组合物，其固化膜具有优异的抗污染性和高硬度。例如，本发明是通过使特定的两种二元醇与碳酸二酯在转酯化催化剂（使用元素周期表中第 1 或第 2 族金属的化合物）存在下发生反应而获得的。本发明提供了一种聚碳酸酯二元醇（其中酯交换催化剂的金属含量为 100 重量ppm 或更少）、一种可通过使用这种聚碳酸酯二元醇获得的聚氨酯，以及一种含有从聚碳酸酯二元醇中获得的聚氨酯（甲基）丙烯酸酯低聚物的主动能辐射固化聚合物组合物。
• Polycarbonate diol and producing method thereof, and polyurethane and active energy ray-curable polymer composition both formed using same
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US10907012B2

  公开（公告）日：2021-02-02

  A novel polycarbonate diol is useful as a raw material for producing a polycarbonate diol-based polyurethane with a high degree of hardness, superior abrasion resistance, and superior hydrophilicity. The polyurethane is useful in paints, coating agents, synthetic leathers, artificial leathers, and highly-functional elastomers, or the like. The polycarbonate diol is also useful for producing an active-energy radiation curable polymer composition giving a cured film having superior contamination resistance and high degree of hardness. The curable polymer composition contains a urethane(meth)acrylate oligomer obtained from the polycarbonate diol. The polycarbonate diol is obtained, for example, by reacting two specific types of diols with diester carbonate in the presence of a transesterification catalyst. The catalyst has a metal of Group 1 or 2 on the periodic table. A metal content of the transesterification catalyst is 100 weight ppm or less.

  一种新型聚碳酸酯二元醇可用作生产聚碳酸酯二元醇基聚氨酯的原料，该聚氨酯具有高硬度、优异的耐磨性和亲水性。这种聚氨酯可用于油漆、涂层剂、合成皮革、人造皮革和高功能弹性体等。聚碳酸酯二元醇还可用于生产活性能量辐射固化聚合物组合物，使固化膜具有优异的抗污染性和高硬度。这种可固化聚合物组合物含有从聚碳酸酯二元醇中获得的聚氨酯（甲基）丙烯酸酯低聚物。例如，聚碳酸酯二元醇是通过两种特定类型的二元醇与碳酸二酯在酯交换催化剂的存在下发生反应而得到的。催化剂为元素周期表中的第 1 族或第 2 族金属。酯交换催化剂的金属含量不超过 100 重量ppm。
• Catalyst for Producing Polyester and Method for Producing Polyester
  申请人：Qi Hua

  公开号：US20100305296A1

  公开（公告）日：2010-12-02

  The invention relates to an improved linear microdialysis probe comprising a continuous length of flexible tubing ( 1 ) having at least one window ( 4 ) formed therein, said window covering at least one pan of the circumference of the tubing, while the remaining part forms at least one unbroken connection between a first end of said tubing and a second end of said tubing, said ends adapted to be attached to an inlet for perfusion liquid and the other end forming an outlet for the dialysate, said at least one window ( 4 ) exposing a tubular semipermeable membrane ( 2 ).
• US8829087B2
  申请人：——

  公开号：US8829087B2

  公开（公告）日：2014-09-09