24-nor-lupane | 134501-94-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: 24-nor-lupane
• 英文别名: (1S,3aR,5aR,5bR,7aS,8R,11aS,11bR,13aR,13bR)-3a,5a,5b,8,11a-pentamethyl-1-propan-2-yl-2,3,4,5,6,7,7a,8,9,10,11,11b,12,13,13a,13b-hexadecahydro-1H-cyclopenta[a]chrysene
• CAS: 134501-94-3
• 化学式: C₂₉H₅₀
• 分子量: 398.716
• InChiKey: WJTOJWMWTGCGEF-JXKYYQBPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  29
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  lupan-3-one oxime 在 吡啶 、 sodium tetrahydroborate 、 lithium aluminium tetrahydride 、 titanium(III) chloride 、 ammonium acetate 、 sodium carbonate 作用下， 以 四氢呋喃 、 甲醇 、 乙醚 、 乙醇 、 水 为溶剂， 反应 144.0h， 生成 24-nor-lupane
  参考文献：
  名称：

  Characterisation of 24-nor-triterpenoids occurring in sediments and crude oils by comparison with synthesized standards

  摘要：

  A series of 24-nor-triterpenoids; 24-nor-urs-12-ene, 24-nor-olean-12-ene and 24-nor-lupane have been identified in sediments and crude oils by comparison with standards obtained by synthesis. A further suite of 24-nor-oleanenes has also been identified by comparison with the acid-catalysed rearrangement products of 24-nor-olean-12-ene. The presence of these components in sedimentary organic matter points to an important new pathway of terrigenous triterpenoid diagenesis.

  DOI：

  10.1016/s0040-4020(01)80903-0

文献信息

• Characterisation of 24-nor-triterpenoids occurring in sediments and crude oils by comparison with synthesized standards
  作者：Torren M. Peakman、H.Lo ten Haven、Jürgen Rullkötter、Joseph A. Curiale

  DOI：10.1016/s0040-4020(01)80903-0

  日期：——

  A series of 24-nor-triterpenoids; 24-nor-urs-12-ene, 24-nor-olean-12-ene and 24-nor-lupane have been identified in sediments and crude oils by comparison with standards obtained by synthesis. A further suite of 24-nor-oleanenes has also been identified by comparison with the acid-catalysed rearrangement products of 24-nor-olean-12-ene. The presence of these components in sedimentary organic matter points to an important new pathway of terrigenous triterpenoid diagenesis.