1-Butylanthracene-9,10-dione | 56854-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-Butylanthracene-9,10-dione
• CAS: 56854-76-3
• 化学式: C₁₈H₁₆O₂
• 分子量: 264.3
• InChiKey: BVEIKFLZWBDLJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Acid- and radical-generating agent and method for generating acid and radical
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10451967B2

  公开（公告）日：2019-10-22

  It is a subject of the present invention to provide an acid- and radical-generating agent which has high sensitivity to an active energy ray having a wavelength of around 300 to 450 nm, and can exert both high acid-generating performance and high radical-generating performance, and has heat resistance; and a method for generating an acid and a radical. The present invention relates to a compound represented by the general formula (A); an acid- and radical-generating agent comprising the compound; and a method for generating an acid and a radical: wherein n pieces of R1 each independently represent an alkyl group, which may have a specific functional group in the chain, or in which a hydrogen atom may be substituted by a halogen atom; an alkoxy group, in which a hydrogen atom may be substituted by a halogen atom; an aryl group or an aryloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; or an arylalkyl group or an arylalkyloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; n pieces of R2 and R3 each independently represent a hydrogen atom, an alkyl group or an alkoxycarbonyl group; R4 to R7 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkenyl group, an aryl group, an alkoxycarbonyl group, a dialkylamino group or a nitro group; Y represents an oxygen atom, a sulfur atom, or a carbonyl group; n pieces of Z each independently represent a sulfonyl group or an alkoxyphosphoryl group; n represents 1 or 2.

  本发明的一个目的是提供一种对波长约为300至450纳米的活性能量射线具有高灵敏度的酸和自由基生成剂，能够发挥高酸生成性能和高自由基生成性能，并具有耐热性；以及一种生成酸和自由基的方法。本发明涉及一种由通式（A）表示的化合物；包括该化合物的酸和自由基生成剂；以及生成酸和自由基的方法：其中n个R1分别独立表示一种烷基基团，该烷基基团可能在链中具有特定的功能基团，或者氢原子可能被卤原子取代；一种烷氧基团，其中氢原子可能被卤原子取代；一种芳基或芳氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；或一种芳基烷基或芳基氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；n个R2和R3分别独立表示氢原子，烷基基团或烷氧羰基团；R4到R7分别独立表示氢原子，卤原子，烷基基团，烷氧基团，烯基基团，芳基，烷氧羰基团，二烷基氨基团或硝基；Y表示氧原子，硫原子或羰基；n个Z分别独立表示磺酰基或烷氧基磷酰基；n表示1或2。
• [EN] PROCESS FOR MANUFACTURING AN ALKYL SUBSTITUTED CYCLOHEXANECARBONITRILE<br/>[FR] PROCÉDÉ DE FABRICATION D'UN CYCLOHEXANE CARBONITRILE SUBSTITUÉ PAR ALKYLE
  申请人：SOLVAY

  公开号：WO2021048365A1

  公开（公告）日：2021-03-18

  A process for manufacturing an alkyl substituted cyclohexanecarbonitrile, said process comprising the following steps: - reaction of cyanoisophorone with an organometallic compound comprising an alkyl group in order to transform the ketone moiety into its corresponding alcohol; - reduction of the alcohol in order to obtain the alkyl substituted cyclohexanecarbonitrile.

  一种制造烷基取代环己基腈的过程，该过程包括以下步骤：-将氰异橙酮与含有烷基的有机金属化合物反应，以将酮基转化为相应的醇基；-还原醇基以获得烷基取代的环己基腈。
• [EN] PROCESS FOR MANUFACTURING A SUBSTITUTED CYCLOHEXANECARBONITRILE<br/>[FR] PROCÉDÉ DE FABRICATION D'UN CYCLOHEXANECARBONITRILE SUBSTITUÉ
  申请人：SOLVAY

  公开号：WO2021048364A1

  公开（公告）日：2021-03-18

  A process for manufacturing a substituted cyclohexanecarbonitrile said process comprising the following steps: - reacting the corresponding substituted cyclohexanecarboxylic acid with thionyl chloride to make the corresponding acyl chloride; and simultaneously or subsequently - reacting the chloride with sulfonamide in sulfolane as solvent to make the substituted cyclohexanecarbonitrile.

  制造一种取代环己基碳腈的过程包括以下步骤：- 将相应的取代环己基羧酸与氯化亚磺酰反应，制得相应的酰氯；同时或随后 - 将氯化物与磺胺酰胺在硫代磺酸乙烷作为溶剂中反应，制得取代环己基碳腈。
• [EN] METHOD FOR PRODUCING PROPYLENE OXIDE USING A NOBLE METAL CATALYST SUPPORTED ON SILYLATED ACTIVE CARBON<br/>[FR] PROCÉDÉ DE FABRICATION D'OXYDE DE PROPYLÈNE À L'AIDE D'UN CATALYSEUR DE MÉTAL NOBLE DÉPOSÉ SUR DU CHARBON ACTIF SILYLATÉ
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2010087519A1

  公开（公告）日：2010-08-05

  A method for producing propylene oxide which comprises reacting propylene, oxygen and hydrogen, in the presence of a titanosilicate and a noble metal supported on silylated active carbon, in a solvent.

  一种生产环氧丙烷的方法，包括在溶剂中，在钛硅酸盐和负载在硅烷化活性碳上的贵金属的存在下，将丙烯、氧气和氢气反应。
• Photo radical generator, photo sensitive resin composition and article
  申请人：Sakayori Katsuya

  公开号：US20050119432A1

  公开（公告）日：2005-06-02

  A photoradical generator which produces no low-molecular decomposition material but a radical during a photoradical generating process, does not generate a radical during a heating process, exists in a chemically stable state in a resulting product of a radical reaction such as a cured coating layer or the like, has high heat resistance, stability and preserving ability, and is excellent in compatibility or solubility is provided. The photoradical generator is comprised of a compound (a) having a seven-membered ring imide structure-containing group represented by the following formula (1), wherein, R 1 to R 8 respectively represent a hydrogen atom or a substituent and may be a cyclic structure in which they are bonded to each other.

  一种光致自由基发生器，其在光致自由基生成过程中不产生低分子分解物质，而是产生自由基，在加热过程中不生成自由基，在自由基反应的产物中（如固化涂层层等）处于化学稳定状态，具有高耐热性，稳定性和保持能力，并且在兼容性或溶解性方面表现出色。该光致自由基发生器由以下式（1）所表示的含有七元环酰亚胺结构基团的化合物（a）组成，其中，R1至R8分别表示氢原子或取代基，可以是它们彼此相连的环状结构。