1-[(4-Chlorophenyl)(cyclopropyl)methyl]-1-ethylpyrrolidin-1-ium | 764664-36-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-[(4-Chlorophenyl)(cyclopropyl)methyl]-1-ethylpyrrolidin-1-ium
• 英文别名: 1-[(4-chlorophenyl)-cyclopropylmethyl]-1-ethylpyrrolidin-1-ium
• CAS: 764664-36-0
• 化学式: C16H23ClN+
• 分子量: 264.81
• InChiKey: NNXFNCYIRIHCDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Hydrocarbon conversion using molecular sieve SSZ-65
  申请人：——

  公开号：US20040188324A1

  公开（公告）日：2004-09-30

  The present invention relates to new crystalline molecular sieve SSZ-65 prepared using 1-[1-(4-chlorophenyl)-cyclopropylmethyl]-1-ethyl-pyrrolidinium or 1-ethyl-1-(1-phenyl-cyclopropylmethyl)-pyrrolidinium cation as a structure-directing agent, methods for synthesizing SSZ-65 and processes employing SSZ-65 in a catalyst.

  本发明涉及使用1-[1-(4-氯苯基)-环丙基甲基]-1-乙基吡咯烷或1-乙基-1-(1-苯基-环丙基甲基)-吡咯烷阳离子作为结构指向剂制备的新型晶体分子筛SSZ-65，以及合成SSZ-65的方法和在催化剂中应用SSZ-65的过程。
• Catalyst for Conversion of Hydrocarbons, Process of Making and Process of Using Thereof - Incorporation-1
  申请人：Khanmamedova Alla K.

  公开号：US20080293989A1

  公开（公告）日：2008-11-27

  This invention is for a catalyst for conversion of hydrocarbons. The catalyst contains a zeolite having germanium and at least one selected from the group consisting of tin and boron incorporated into the zeolite framework and at least one metal selected from Group 10 deposited on the zeolite. The catalyst is prepared by synthesizing a zeolite having germanium and at least one selected from the group consisting of tin and boron incorporated into the zeolite framework; depositing the metal; and calcining after preparation of the zeolite and before or after depositing the metal. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with alkanes having 2 to 12 carbon atoms per molecule and recovering the product.

  这项发明是关于用于转化碳氢化合物的催化剂。该催化剂包含一种沸石，其中含有锗以及至少从锡和硼组成的一种被纳入到沸石框架中，并且至少从第10族金属中选择的一种金属沉积在沸石上。该催化剂的制备方法包括合成含有锗以及至少从锡和硼组成的一种被纳入到沸石框架中的沸石；沉积金属；并在制备沸石之后或之前以及沉积金属之后进行焙烧。该催化剂可用于碳氢化合物的转化过程，例如将丙烷转化为芳香烃，通过将催化剂与每个分子含有2到12个碳原子的烷烃接触，并回收产物。
• Catalyst for Conversion of Hydrocarbons, Process of Making and Process of Using Thereof - Incorporation 2
  申请人：Mitchell Scott F.

  公开号：US20080293988A1

  公开（公告）日：2008-11-27

  This invention is for a catalyst for conversion of hydrocarbons. The catalyst contains a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework. At least one Group 10 metal, such as platinum, is deposited on the zeolite. Examples of the elements in the framework are tin, boron, iron or titanium. The catalyst is prepared by synthesizing a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework; depositing the metal; and calcining after preparation of the zeolite and before or after depositing the metal. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with alkanes having 2 to 12 carbon atoms per molecule and recovering the product.

  这项发明是为了一种用于转化碳氢化合物的催化剂。该催化剂包含一种具有来自第13组、第14组或第一系列过渡金属中的一种元素的沸石，并且在沸石框架中可选地含有锗和/或铝。至少一种第10组金属，如铂，被沉积在沸石上。框架中元素的示例是锡、硼、铁或钛。该催化剂是通过合成一种具有来自第13组、第14组或第一系列过渡金属中的一种元素的沸石，并且在沸石框架中可选地含有锗和/或铝；沉积金属；在制备沸石之后或之前以及沉积金属之后进行焙烧制备的。该催化剂可以用于碳氢化合物的转化过程，例如将丙烷转化为芳香烃，通过将催化剂与具有每个分子2到12个碳原子的烷烃接触并回收产物。
• Catalyst for Conversion of Hydrocarbons, Process of Making and Process of Using Thereof - Ge Zeolites
  申请人：Stevenson Scott A.

  公开号：US20080293990A1

  公开（公告）日：2008-11-27

  This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes having 2 to 12 carbon atoms per molecule and recovering the product.

  本发明涉及一种用于转化碳氢化合物的催化剂。该催化剂是一种中孔锗沸石、锗铝磷酸盐（AlPO）或锗硅铝磷酸盐（SAPO）。至少从第10族金属中选择一种金属沉积在中孔沸石上，并可选地沉积在锗铝磷酸盐（AlPO）或锗硅铝磷酸盐（SAPO）上。通过合成中孔沸石、铝磷酸盐（AlPO）或硅铝磷酸盐（SAPO）并将锗纳入框架中，然后煅烧中孔锗沸石、锗铝磷酸盐（AlPO）或锗硅铝磷酸盐（SAPO）来制备该催化剂。至少可以在锗沸石、锗铝磷酸盐（AlPO）或锗硅铝磷酸盐（SAPO）上沉积一种金属。该催化剂可用于将碳氢化合物（例如丙烷）转化为芳香烃的过程中，通过将催化剂与含有每个分子2到12个碳原子的烷烃的碳氢化合物流接触并回收产物。
• Catalyst for Conversion of Hydrocarbons, Process of Making and Process of Using Thereof - Bimetallic Deposition
  申请人：Khanmamedova Alla K.

  公开号：US20080293987A1

  公开（公告）日：2008-11-27

  This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a germanium zeolite, such as Ge-ZSM-5, on which at least two metals, platinum and at least one other metal selected from Group 7, Group 8, Group 9, Group 10 and tin, are deposited on the germanium zeolite. Examples of the other metal are iridium, rhenium, palladium, ruthenium, rhodium, iron, cobalt and tin. The catalyst is prepared by synthesizing a germanium zeolite; depositing platinum and at least one other metal on the germanium zeolite; and calcining after preparation of the zeolite, before depositing the metals or after depositing the metals. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with a hydrocarbon stream containing alkanes, olefins and mixtures thereof having 2 to 12 carbon atoms per molecule and recovering the product.

  本发明是关于一种用于转化碳氢化合物的催化剂。该催化剂是一种锗沸石，例如Ge-ZSM-5，其中至少有两种金属，铂和来自第7组、第8组、第9组、第10组和锡的至少一种其他金属，被沉积在锗沸石上。其他金属的例子包括铱、铼、钯、钌、铑、铁、钴和锡。该催化剂通过合成锗沸石；在锗沸石上沉积铂和至少一种其他金属；并在制备沸石后，沉积金属之前或之后进行焙烧。该催化剂可用于碳氢化合物的转化过程，例如将丙烷转化为芳香烃，通过将催化剂与含有2至12个碳原子/分子的烷烃、烯烃和其混合物的碳氢化合物流接触，并回收产物。