Reversibly thermochromic ultraviolet ray-hardening ink composition and reversibly thermochromic laminate using the same
申请人:THE PILOT INK CO., LTD.
公开号:US20040077743A1
公开(公告)日:2004-04-22
This invention provides a reversibly thermochromic ultraviolet ray-hardening type ink having good color change sensitivity and excellent light resistance and fastness, and a reversibly thermochromic laminate produced using the same. The present invention also provides a reversibly thermochromic laminate produced by forming a reversibly thermochromic layer on a support using the same. The ink comprises:
(1) a microencapsulated pigment comprising a reversibly thermochromic composition comprising (A) an electron-donating compound, (B) an electron-accepting compound and (C) a color change temperature-controlling agent which controls color reaction generation temperature of the former two compounds; and (D) a light resistance-providing agent represented by a specific formula, and
(2) a photo-polymerizable composition comprising an ultraviolet ray absorbent, a reactive oligomer, a reactive monomer, and an acylphosphine oxide photo-polymerization initiator,
wherein said microencapsulated pigment is dispersed in said photo-polymerizable composition.
本发明提供了一种可逆热致变色紫外线硬化型油墨,具有良好的变色敏感性和优异的耐光性和牢度,以及使用该油墨生产的可逆热致变色层压板。本发明还提供了一种可逆热致变色层压板,该层压板是利用可逆热致变色油墨在支撑物上形成可逆热致变色层而制成的。该墨水包括
(1) 包含可逆热致变色组合物的微胶囊颜料,该组合物包括:(A) 电子供体化合物;(B) 电子受体化合物;(C) 变色温度控制剂,该控制剂可控制前两种化合物的颜色反应生成温度;以及 (D) 由特定配方表示的光阻提供剂,以及
(2) 由紫外线吸收剂、活性低聚物、活性单体和酰基氧化膦光聚合引发剂组成的可光聚合组合物、
其中,所述微胶囊颜料分散在所述光聚合组合物中。