Benzyl(trioctyl)phosphanium chloride | 34376-33-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzyl(trioctyl)phosphanium chloride
• 英文别名: benzyl(trioctyl)phosphanium;chloride
• CAS: 34376-33-5
• 化学式: C31H58ClP
• 分子量: 497.2
• InChiKey: VUUQSOCJUCSVBN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  8.29
• 重原子数：
  33
• 可旋转键数：
  23
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• POLYFLUORO-1-ALKENE AND METHOD FOR PRODUCING THE SAME
  申请人：Sato Katsuyuki

  公开号：US20110077435A1

  公开（公告）日：2011-03-31

  A polyfluoro-1-alkene represented by the general formula: CF 3 (CF 2 ) n CH 2 (CF 2 ) m CH═CH 2 [I], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, is produced by reacting a polyfluoroalkyl iodide represented by the general formula: CF 3 (CF 2 ) n CH 2 (CF 2 ) m (CH 2 CH 2 )I [II], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, with an inorganic basic compound in the presence of a phase transfer catalyst. Alternatively, the polyfluoro-1-alkene is produced by reacting the polyfluoroalkyl iodide [II] with a nitrogen-containing organic basic compound, and is obtained product [I] as one fraction thereof. By the copolymerization of the polyfluoro-1-alkene with other fluorinated olefin monomers, a fluorine-containing copolymer having excellent light transmittance in the visible light range is formed.

  通式表示的多氟-1-烯烃：CF3(CF2)nCH2(CF2)mCH═CH2[I]，其中n为0至5的整数，m为1至7的整数，通过将通式表示的多氟烷基碘化物：CF3(CF2)nCH2(CF2)m(CH2CH2)I [II]，其中n为0至5的整数，m为1至7的整数，与无机碱性化合物在相转移催化剂的存在下反应而制得。另外，通过将多氟烷基碘化物[II]与含氮有机碱性化合物反应，得到产物[I]的一部分。通过将多氟-1-烯烃与其他氟代烯烃单体共聚合，形成具有在可见光范围内优异透光性的含氟共聚物。
• Process for modifying a polymeric surface
  申请人：3M Innovative Properties Company

  公开号：US20030159915A1

  公开（公告）日：2003-08-28

  This invention concerns a process for modifying a polymeric substrate by contacting the surface with a photoreactive solution of an inorganic photochemical electron donor while irradiating the surface with actinic radiation. Patterns of modified and unmodified surfaces can be produced. Polymeric substrates with modified surfaces may be effectively bonded to polymer films to form composite articles. The process has particular applicability to the surface modification of fluorinated polymers.

  这项发明涉及一种通过将聚合物基底与无机光化学电子供体的光反应性溶液接触，并在表面照射活性辐射的过程来修改聚合物基底的方法。可以制备经过修改和未经修改的表面图案。具有修改表面的聚合物基底可以有效地与聚合物薄膜粘合，形成复合制品。该过程特别适用于氟化聚合物的表面改性。
• Process for coagulating fluoroelastomers
  申请人：Lyons Donald F.

  公开号：US20080194769A1

  公开（公告）日：2008-08-14

  In a process for the manufacture of fluoroelastomers, a coagulant is employed that is a water-soluble polymer having at least 2 quaternary onium centers. Specific examples of such coagulants include, but are not limited to poly(diallyldimethylammonium chloride), poly(epichlorohydrin-co-dimethyl amine), and poly(acrylamide-co-diallyldimethylammonium chloride).

  在制造氟弹性体的过程中，使用一种凝固剂，该凝固剂是一种水溶性聚合物，具有至少2个季铵中心。这种凝固剂的具体例子包括但不限于聚二甲基丙烯酰胺-二烯丙基二甲基铵盐、聚环氧氯丙烷-二甲基胺和聚丙烯酰胺-二烯丙基二甲基铵盐。
• CURABLE FLUOROPOLYMER COMPOSITIONS
  申请人：Oriani Steven R.

  公开号：US20100069554A1

  公开（公告）日：2010-03-18

  Polyhydroxy curable fluoropolymer compositions comprise polyhydroxy curable fluoropolymer, a β-fluoroalcohol having the formula R—(CF 2 )n-CH 2 —OH, wherein R is H, F or CH 3 O and n is an integer from 2 to 7, a polyhydroxy curative, acid acceptor and accelerator.

  聚羟基可固化氟聚合物组合物包括聚羟基可固化氟聚合物、具有以下公式的β-氟醇R—（CF2）n-CH2—OH，其中R是H，F或CH3O，n是从2到7的整数，聚羟基固化剂、酸接受剂和加速剂。
• A process for rapidly curing a brominated fluoroelastomer
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0140207A2

  公开（公告）日：1985-05-08

  A process for rapidly curing a fluoroelastomer which comprises mixing and heating a fluoroelastomer copolymer whose interpolymerized units consist essentially of vinylidene fluoride, at least one other fluorine-containing monomer copolymerizable therewith, said monomer being a compound which contains 2-7 carbon atoms, contains no bromine, and contains at least as many fluorine atoms as carbon atoms and contains up to 3 mole percent of units derived from a bromine-containing olefin; a quaternary phosphonium compound; a bisphenol or an ammonium or phosphonium salt thereof; and a dialkylaminopyridine or a diazabicyclo compound having the formula where n is 2-8 or 0.2-0.8 parts by weight per hundred parts fluoroelastomer of a carboxylic acid salt of (a) or (b).

  一种快速固化氟弹性体的工艺，包括混合并加热一种氟弹性体共聚物，其间聚单元主要由偏氟乙烯、至少一种可与之共聚的其他含氟单体组成，所述单体是一种含有2-7个碳原子的化合物，不含溴，至少含有与碳原子数量相同的氟原子，并含有高达3摩尔％的由含溴烯烃衍生的单元；季鏻化合物；双酚或其铵盐或鏻盐；以及二烷基氨基吡啶或二氮杂双环化合物，其式为 其中 n 为 2-8 或 每 100 份氟橡胶中含 0.2-0.8 份（按重量计）(a)或(b)的羧酸盐。