申请人:KURARAY CO., LTD.
公开号:EP0408357A2
公开(公告)日:1991-01-16
Provided are polymerizable compositions comprising:
(a) a sulfinate represented by the general formula [I]
wherein R¹ and R⁵ each represents a substituent having 2 to 6 carbon atoms, R², R³ and R⁴ each represents an atom or substituent inert to the monomer (b) referred to below, Mn+ represents a n-valent cation, and n represents an integer of 1 to 4; and
(b) a monomer.
(a) is an aromatic sulfinate substituted with bulky groups at its positions 2 and 6. Since the bulky substituents dramatically suppress the addition of the sulfinate to the double bond of the monomers, e.g. (meth)acrylates, (meth)acrylamides and derivatives thereof, the compositions can be stored at room temperature for at least 1 year and thus are of great industrial value and, in particular very useful as dental adhesive compositions.
提供的可聚合组合物包括
(a) 由通式[I]代表的亚硫酸盐
其中 R¹ 和 R⁵ 各自代表具有 2 至 6 个碳原子的取代基,R²、R³ 和 R⁴ 各自代表对下文所述单体(b)惰性的原子或取代基,Mn+ 代表正价阳离子,n 代表 1 至 4 的整数;以及
(b) 单体。
(a) 是一种在其 2 号和 6 号位置被大基团取代的芳香族亚硫酸盐。由于笨重的取代基极大地抑制了亚硫酸盐与单体(如(甲基)丙烯酸酯、(甲基)丙烯酰胺及其衍生物)双键的加成,因此这种组合物可以在室温下储存至少 1 年,具有极大的工业价值,尤其是作为牙科粘合剂组合物非常有用。