1,1'-[(3,4,5,6-Tetrabromo-1,2-phenylene)bis(oxy)]bis(pentabromobenzene) | 113588-14-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1'-[(3,4,5,6-Tetrabromo-1,2-phenylene)bis(oxy)]bis(pentabromobenzene)
• 英文别名: 1,2,3,4,5-pentabromo-6-[2,3,4,5-tetrabromo-6-(2,3,4,5,6-pentabromophenoxy)phenoxy]benzene
• CAS: 113588-14-0
• 化学式: C₁₈Br₁₄O₂
• 分子量: 1366.8
• InChiKey: PJPJSHUNZMHBRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• [EN] HYDROSILYLATION REACTION CURABLE COMPOSITIONS AND METHODS FOR THEIR PREPARATION AND USE<br/>[FR] COMPOSITIONS DURCISSABLES PAR UNE RÉACTION D'HYDROSILYLATION ET LEURS PROCÉDÉS DE PRÉPARATION ET D'UTILISATION
  申请人：DOW CORNING

  公开号：WO2013000788A1

  公开（公告）日：2013-01-03

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a platinum-ligand complex that can be prepared by reacting a platinum precursor and a ligand.

  一种组合物包含（A）氢硅烷化反应催化剂和（B）一种脂肪族不饱和化合物，每分子平均含有一个或多个能够进行氢硅烷化反应的脂肪族不饱和有机基团。该组合物能够通过氢硅烷化反应反应形成反应产物，如硅烷、树胶、凝胶、橡胶或树脂。成分（A）包含一种铂配体络合物，可通过反应铂前体和配体制备。
• [EN] ACRYLATE-FUNCTIONAL BRANCHED ORGANOSILICON COMPOUND, METHOD OF PREPARING SAME, AND COPOLYMER FORMED THEREWITH<br/>[FR] COMPOSÉ D'ORGANOSILICIUM RAMIFIÉ À FONCTION ACRYLATE, SON PROCÉDÉ DE PRÉPARATION ET COPOLYMÈRE FORMÉ AVEC CELUI-CI
  申请人：DOW SILICONES CORP

  公开号：WO2020142474A1

  公开（公告）日：2020-07-09

  A method of preparing an acrylate-functional branched organosilicon compound ("compound") is provided, and comprises reacting (A) a branched organosilicon compound and (B) an acrylate compound in the presence of (C) a catalyst, wherein component (A) has the general formula X-Si(R1)3, where X comprises a halogen-functional moiety and each R1 is selected from R and –OSi(R4)3, with the proviso that at least one R1 is –OSi(R4)3; each R4 is selected from R, –OSi(R5)3, and –[OSiR2]mOSiR3; each R5 is selected from R, –OSi(R6)3, and –[OSiR2]mOSiR3; each R6 is selected from R and –[OSiR2]mOSiR3; each R is an independently selected hydrocarbyl group; and 0≤m≤100; with the proviso that at least one of R4, R5 and R6 is –[OSiR2]mOSiR3. The compound prepared by the method, a copolymer comprising the reaction product of the compound and a second compound, a method of forming the copolymer, and a composition comprising the copolymer are each also provided.

  提供了一种制备丙烯酸酯官能化分支有机硅化合物（“化合物”）的方法，包括在催化剂存在下，使（A）分支有机硅化合物和（B）丙烯酸酯化合物发生反应，其中组分（A）具有一般式X-Si（R1）3，其中X包括卤素官能基，每个R1从R和–OSi（R4）3中选择，但至少一个R1为–OSi（R4）3；每个R4从R、–OSi（R5）3和–[OSiR2]mOSiR3中选择；每个R5从R、–OSi（R6）3和–[OSiR2]mOSiR3中选择；每个R6从R和–[OSiR2]mOSiR3中选择；每个R是独立选择的烃基；且0≤m≤100；但至少一个R4、R5和R6为–[OSiR2]mOSiR3。还提供了通过该方法制备的化合物，包括化合物和第二化合物的反应产物的共聚物，形成共聚物的方法，以及包含共聚物的组合物。
• Hydrosilylation Reaction Catalysts and Curable Compositions and Methods for Their Preparation and Use
  申请人：Dow Corning Corporation

  公开号：US20140296468A1

  公开（公告）日：2014-10-02

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains an iron-organosilicon ligand complex that can be prepared by reacting an iron carbonyl compound and an organosilicon ligand.

  一种组合物包含（A）一个氢硅烷基化反应催化剂和（B）一种脂肪族不饱和化合物，每个分子平均含有一个或多个能够进行氢硅烷基化反应的脂肪族不饱和有机基团。该组合物能够通过氢硅烷基化反应反应形成反应产物，如硅烷、树脂、凝胶、橡胶或树脂。成分（A）包含一种铁-有机硅配体络合物，可通过反应铁羰基化合物和有机硅配体制备。
• [EN] BRANCHED ORGANOSILICON COMPOUND, METHOD OF PREPARING SAME, AND COPOLYMER FORMED THEREWITH<br/>[FR] COMPOSÉ D'ORGANOSILICIUM RAMIFIÉ, SON PROCÉDÉ DE PRÉPARATION ET COPOLYMÈRE FORMÉ AVEC CELUI-CI
  申请人：DOW SILICONES CORP

  公开号：WO2020142370A1

  公开（公告）日：2020-07-09

  A branched organosilicon compound ("compound") having the general formula (R1)3Si- X-Y is provided. In the formula: each R1 is selected from R and -OSi(R4)3, with the proviso that at least one R1 is -OSi(R4)3; each R is independently a substituted or unsubstituted hydrocarbyl group; each R4 is selected from R, -OSi(R5)3, and -[OSiR2]mOSiR3; each R5 is selected from R, -OSi(R6)3, and -[OSiR2]mOSiR3; each R6 is selected from R and -[OSiR2]mOSiR3; with the proviso that at least one of R4, R5 and R6 is -[OSiR2]mOSiR3; 0

  提供具有一般式（R1）3Si-X-Y的分支有机硅化合物（“化合物”）。在该式中：每个R1从R和-OSi（R4）3中选择，但至少有一个R1为-OSi（R4）3；每个R都是独立的取代或未取代的烃基团；每个R4从R、-OSi（R5）3和-[OSiR2]mOSiR3中选择；每个R5从R、-OSi（R6）3和-[OSiR2]mOSiR3中选择；每个R6从R和-[OSiR2]mOSiR3中选择；但至少有一个R4、R5和R6为-[OSiR2]mOSiR3；0
• [EN] FLAME RETARDANT HALOGENATED PHENYL ETHERS<br/>[FR] ÉTHERS DE PHÉNYLE HALOGÉNÉS IGNIFUGES
  申请人：CHEMTURA CORP

  公开号：WO2011090631A1

  公开（公告）日：2011-07-28

  A halogenated non-polymeric phenyl ether is described having the general formula (I): wherein each X is independently Cl or Br, n is an integer of 1 or 2, each m is independently an integer of 1 to 5 and each p is independently an integer of 1 to 4, provided that, when X is Cl, the total amount halogen in the ether is from about 50 to about 65 wt% and when, X is Br, the total amount halogen in the ether is from at least 70 wt % to about 79 wt%.

  描述了具有通式（I）的卤代非聚合物苯醚，其中每个X独立地是Cl或Br，n是1或2的整数，每个m独立地是1到5的整数，每个p独立地是1到4的整数，前提是，当X为Cl时，醚中卤素的总量约为50至65重量％，当X为Br时，醚中卤素的总量至少为70重量％至约79重量％。