申请人:Ghyzel Peter J.
公开号:US20080161493A1
公开(公告)日:2008-07-03
The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.
本发明揭示了一种制备核-壳聚合物颗粒的方法,包括通过衍生化含有相邻碳原子上羟基的聚合物形成含有连接基团的聚合物,使用一种同时包含醛基团和胺基团的化合物作为连接试剂,其中在连接基团聚合物中形成一个或多个缩醛基团,每个缩醛基团由连接试剂中的醛基团与连接基团聚合物中的两个羟基反应形成,从而使胺基团成为从连接基团聚合物中悬垂的连接基团,其中连接基团能够与前体聚合物中的前体基团反应。还揭示了由该方法制备的不溶性核-壳颗粒的组成。