mercaptophenyl methacrylate | 1113062-67-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: mercaptophenyl methacrylate
• 英文别名: (2-sulfanylphenyl) 2-methylprop-2-enoate
• CAS: 1113062-67-1
• 化学式: C₁₀H₁₀O₂S
• 分子量: 194.254
• InChiKey: NJSDEJCXZWPHQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  27.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-trimethylsilanyloxy-2-trimethylsilanylsulfanyl-benzene 、 甲基丙烯酰氯 以 二氯甲烷 为溶剂， 反应 4.0h， 以50%的产率得到mercaptophenyl methacrylate
  参考文献：
  名称：

  A new strategy for chemoselective O-acylation of β-mercapto alcohols via alkylsilyl and stannyl protection

  摘要：

  Chemoselective preparation of O-acylated derivatives from bis-protected mercapto alcohols was described. Trialkylsilyl and trialkylstannyl chloride are used to generate an intermediate with O- and S-protection. The intermediates from beta-mercapto alcohols are reactive toward acylating agents and selective to provide O-acylated derivatives. The present preparation involves the direct conversion of alcohol to the corresponding O-acylated compounds without deprotection. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.11.047

文献信息

• Acrylic ester compound and usage thereof
  申请人：——

  公开号：US20020061995A1

  公开（公告）日：2002-05-23

  An acrylic ester compound represented by the general formula (1): 1 wherein, R 1 and R 2 represent independently a hydrogen atom, an alkyl group which may have a substituent, an aromatic alkyl group which may have a substituent or an aromatic residue which may have a substituent, respectively; R 3 represents a hydrogen atom or an alkyl group; A represents a divalent organic group; and X represents a sulfur atom or an oxygen atom; provided that when X is an oxygen atom, R 1 represents an aromatic residue that may have a substituent, a polymerizable composition comprising the compound, and a cured article and optical components obtained by polymerizing the polymerizable composition.

  一种由通用公式（1）表示的丙烯酸酯化合物：1其中，R1和R2分别独立地代表一个氢原子、一个可能含有取代基的烷基团、一个可能含有取代基的芳香烷基团或一个可能含有取代基的芳香残基；R3代表一个氢原子或一个烷基团；A代表一个二价有机团；X代表一个硫原子或一个氧原子；当X是氧原子时，R1代表一个可能含有取代基的芳香残基，包含该化合物的可聚合组合物，以及通过聚合该可聚合组合物得到的固化产品和光学元件。
• US6794471B2
  申请人：——

  公开号：US6794471B2

  公开（公告）日：2004-09-21
• A new strategy for chemoselective O-acylation of β-mercapto alcohols via alkylsilyl and stannyl protection
  作者：Muchchintala Maheswara、Mirae Kim、Sun-Ju Yun、Jung Jin Ju、Jung Yun Do

  DOI：10.1016/j.tetlet.2008.11.047

  日期：2009.1

  Chemoselective preparation of O-acylated derivatives from bis-protected mercapto alcohols was described. Trialkylsilyl and trialkylstannyl chloride are used to generate an intermediate with O- and S-protection. The intermediates from beta-mercapto alcohols are reactive toward acylating agents and selective to provide O-acylated derivatives. The present preparation involves the direct conversion of alcohol to the corresponding O-acylated compounds without deprotection. (C) 2008 Elsevier Ltd. All rights reserved.