1-vinyl-((6,6',6''-tribromo)-3,4,6,7,10,11-tribenzo)silatrane

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-vinyl-((6,6',6''-tribromo)-3,4,6,7,10,11-tribenzo)silatrane
• 英文别名: 5,13,20-Tribromo-9-ethenyl-8,10,23-trioxa-1-aza-9-silapentacyclo[7.7.7.02,7.011,16.017,22]tricosa-2(7),3,5,11(16),12,14,17(22),18,20-nonaene；5,13,20-tribromo-9-ethenyl-8,10,23-trioxa-1-aza-9-silapentacyclo[7.7.7.02,7.011,16.017,22]tricosa-2(7),3,5,11(16),12,14,17(22),18,20-nonaene
• 化学式: C₂₀H₁₂Br₃NO₃Si
• 分子量: 582.118
• InChiKey: AAZPLCRESPSIAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.27
• 重原子数：
  28
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  tris(2-methoxyphenyl)amine 在 溴 、 三溴化硼 作用下， 以 二氯甲烷 、 二丁醚 为溶剂， 反应 56.5h， 生成 1-vinyl-((6,6',6''-tribromo)-3,4,6,7,10,11-tribenzo)silatrane
  参考文献：
  名称：

  The synthesis of bromo and iodo trifunctionalised tribenzosilatranes

  摘要：

  In this report we present a direct synthesis of bromo 8 and iodo 9 trisubstituted tribenzosilatranes. Cornmercially available o-anisidine I was transformed into the triarylamine 3 in a two-step sequence. which was halogenated to furnish;h the tribromo 4 or the triiodo 5 substituted triamines, respectively. Subsequent deprotection of the methyl ethers furnished the novel tripod ligands 6 and 7. A transilylation reaction in the last step led to the synthesis of the desired para-halogenated tribenzosilatrane 8 and 9. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.034

文献信息

• The synthesis of bromo and iodo trifunctionalised tribenzosilatranes
  作者：Rubén Alvarez、Georg H. Mehl

  DOI：10.1016/j.tetlet.2004.11.034

  日期：2005.1

  In this report we present a direct synthesis of bromo 8 and iodo 9 trisubstituted tribenzosilatranes. Cornmercially available o-anisidine I was transformed into the triarylamine 3 in a two-step sequence. which was halogenated to furnish;h the tribromo 4 or the triiodo 5 substituted triamines, respectively. Subsequent deprotection of the methyl ethers furnished the novel tripod ligands 6 and 7. A transilylation reaction in the last step led to the synthesis of the desired para-halogenated tribenzosilatrane 8 and 9. (C) 2004 Elsevier Ltd. All rights reserved.