三异丙醇胺环硼酸酯 | 101-00-8

• 物质功能分类: 化学试剂 - 有机试剂 - 硼酸
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 三异丙醇胺环硼酸酯
• 中文别名: 三异丙醇胺环硼酸盐
• 英文名称: Triisopropylamin-borat
• 英文别名: 3,7,10-Trimethyl-2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane
• CAS: 101-00-8
• 化学式: C₉H₁₈BNO₃
• mdl: MFCD03791298
• 分子量: 199.058
• InChiKey: IWKGJTDSJPLUCE-UHFFFAOYSA-N

物化性质

• 熔点：
  150 °C
• 沸点：
  135°C/0.2mmHg(lit.)
• 密度：
  1.05±0.1 g/cm3(Predicted)
• 溶解度：
  溶于丙酮
• 稳定性/保质期：

  与强氧化剂反应。

计算性质

• 辛醇/水分配系数(LogP)：
  2.54
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 安全说明：
  S24/25
• 海关编码：
  2934999090
• 危险品运输编号：
  25kgs
• RTECS号：
  ED5787000

SDS

Name:	Triisopropanolamine borate 98+% Material Safety Data Sheet
Synonym:
CAS:	101-00-8

Section 1 - Chemical Product MSDS Name:Triisopropanolamine borate 98+% Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
101-00-8	Triisopropanolamine borate, 98+%	98+%	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Can burn in a fire, releasing toxic vapors.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide. Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

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Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 101-00-8: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 150 - 152 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H19NO3.H3BO3
Molecular Weight: 251.08

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 101-00-8: ED5787000 LD50/LC50:
CAS# 101-00-8: Draize test, rabbit, eye: 10 mg Mild; Oral, mouse: LD50 = 7200 mg/kg.
Carcinogenicity:
Triisopropanolamine borate, 98+% - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 101-00-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 101-00-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 101-00-8 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

用途

三异丙醇胺环硼酸酯可用作汽油腐蚀抑制剂、金属工作液、汽油脱水剂、聚硅氧烷弹性橡胶稳定剂、粘合剂以及聚合物交联剂。

反应信息

• 作为反应物：
  描述：

  三异丙醇胺环硼酸酯 在 三乙氧基硅烷 、 aluminum ethoxide 作用下， 以 xylene 为溶剂， 生成 3,7,10-Trimethylsilatran
  参考文献：
  名称：

  Atranes XI. 1-hydrosilatranes

  摘要：

  DOI：

  10.1007/bf01172574
• 作为产物：
  描述：

  三异丙醇胺 在 硼酸 作用下， 以 异戊醇 为溶剂， 生成 三异丙醇胺环硼酸酯
  参考文献：
  名称：

  Atranes XI. 1-hydrosilatranes

  摘要：

  DOI：

  10.1007/bf01172574

文献信息

• Preparation and Rate of Hydrolysis of Boric Acid Esters
  作者：Howard Steinberg、D. L. Hunter

  DOI：10.1021/ie50566a023

  日期：1957.2
• Dicko, Amadou; Coste, Camille; Bastide, Jean, Bulletin de la Societe Chimique de France, 1982, vol. II, p. 153 - 158
  作者：Dicko, Amadou、Coste, Camille、Bastide, Jean

  DOI：——

  日期：——