1,2-bis{4-[(1-naphthyl)(phenyl)amino]phenyl}-3,3,4,4,5,5-hexafluorocyclopentene

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,2-bis{4-[(1-naphthyl)(phenyl)amino]phenyl}-3,3,4,4,5,5-hexafluorocyclopentene
• 英文别名: N-[4-[3,3,4,4,5,5-hexafluoro-2-[4-(N-naphthalen-1-ylanilino)phenyl]cyclopenten-1-yl]phenyl]-N-phenylnaphthalen-1-amine
• 化学式: C₄₉H₃₂F₆N₂
• 分子量: 762.797
• InChiKey: ALJFGJJHECNSAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.7
• 重原子数：
  57
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  全氟环戊烯 、 N-(4-溴苯基)-N-苯基-1-萘胺 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 8.5h， 以79%的产率得到1,2-bis{4-[(1-naphthyl)(phenyl)amino]phenyl}-3,3,4,4,5,5-hexafluorocyclopentene
  参考文献：
  名称：

  Green Light-Emitting Diodes (LED) Based on Diarylethene

  摘要：

  A novel class of diarylethene derivatives, (diaryl = N-7-azaindolylpheny, naphthylphenylamine, m-tolylphenylamine, ethene = perfluorocyclopentene) were synthesized and experiments were performed their usage in organic light-emitting diodes (OLEDs). Compound 3 , 1,2-Bis{4-[(phenyl)(m-tolyl)amino]biphenyl}-3,3,4,4,5,5-hexafluorocyclopentene, exhibits a strong green emission in both a solution and a thin film at similar to 540 nm. The device with 3 as an emitting material (structure: ITO/TPD/3/Alq 3 (q = tris-(8-hydroxyquinolinolate))/Al:Li) shows high quantum efficiency with 7677 cd/m(2) at similar to 13 V.

  DOI：

  10.1080/15421400500365334

文献信息

• Green Light-Emitting Diodes (LED) Based on Diarylethene
  作者：Youngjin Kang、Taegweon Lee、Il Jung、Jaejung Ko、Soon-Ki Kwon、Ki-Min Park、Seokjong Lee

  DOI：10.1080/15421400500365334

  日期：2006.2.1

  A novel class of diarylethene derivatives, (diaryl = N-7-azaindolylpheny, naphthylphenylamine, m-tolylphenylamine, ethene = perfluorocyclopentene) were synthesized and experiments were performed their usage in organic light-emitting diodes (OLEDs). Compound 3 , 1,2-Bis4-[(phenyl)(m-tolyl)amino]biphenyl}-3,3,4,4,5,5-hexafluorocyclopentene, exhibits a strong green emission in both a solution and a thin film at similar to 540 nm. The device with 3 as an emitting material (structure: ITO/TPD/3/Alq 3 (q = tris-(8-hydroxyquinolinolate))/Al:Li) shows high quantum efficiency with 7677 cd/m(2) at similar to 13 V.