三氟化-苯酚络合物(1:2)硼 | 106291-00-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三氟化-苯酚络合物(1:2)硼
• 英文名称: 3'-fluoro-4'-n-decyloxybiphenyl-4-carboxylic acid
• 英文别名: 4'-decyloxy-3'-fluorobiphenyl-4-carboxylic acid；3'-fluoro-4'-decyloxybiphenyl-4-carboxylic acid；4-[4-(Decyloxy)-3-fluorophenyl]-benzoic acid；4-(4-decoxy-3-fluorophenyl)benzoic acid
• CAS: 106291-00-3
• 化学式: C₂₃H₂₉FO₃
• 分子量: 372.48
• InChiKey: TWLXKGVJNYLMFX-UHFFFAOYSA-N

物化性质

• 沸点：
  510.7±45.0 °C(Predicted)
• 密度：
  1.082±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  27
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  三氟化-苯酚络合物(1:2)硼 生成 4-(4-Decoxy-3-fluorophenyl)benzoyl chloride
  参考文献：
  名称：

  SUDZUKI, GIITI;XAGIVARA, TAKASI

  摘要：

  DOI：
• 作为产物：
  描述：

  3'-氟-4'-羟基-4-联苯基羧酸 、 癸基溴 生成 三氟化-苯酚络合物(1:2)硼
  参考文献：
  名称：

  SHOJI, TADAO;TAKEHARA, SADAO;FUJISAWA, TORU;OSAWA, MASASHI;OGAWA, HIROSHI+

  摘要：

  DOI：

文献信息

• Novel liquid crystal compounds
  申请人：Showa Shell Sekiyu K.K.

  公开号：US05167861A1

  公开（公告）日：1992-12-01

  Novel ferroelectric liquid crystal compounds showing three stable liquid crystal states so as to give particular optical response wave shape as well as particular optical and electric responses to impressed voltage of triangle wave shape in comparison with usual ferroelectric liquid crystals of bistable phase, whereby it is possible to provide electrooptical devices having larger picture area at lower cost. Typical compounds are represented by ##STR1## wherein n is an integer of 3-18 and m is an integer of 5-12.

  这段文字是在介绍一种新型的铁电液晶化合物，它可以表现出三种稳定的液晶状态，从而在光学响应波形和电压响应方面与通常的双稳相铁电液晶相比，提供特定的光学和电学响应。这样可以在更低的成本下提供具有更大画面面积的电光设备。其中典型的化合物可以用##STR1##表示，其中n是3-18的整数，m是5-12的整数。
• Optically active carboxylic acid derivatives and liquid crystalline
  申请人：Dainippon Ink and Chemicals, Inc.

  公开号：US04911862A1

  公开（公告）日：1990-03-27

  An optically active carboxylic acid derivative represented by the general formula ##STR1## wherein R represents a normal alkyl group having 1 to 20 carbon atoms, m and n represent 0 or 1 but are not 1 at the same time, X represents a hydrogen or halogen atom, Y represents a hydrogen or fluorine atom, provided that when Y is a hydrogen atom, X is a halogen atom, and that when n is 0, Y is a hydrogen atom, and Q* represents an optically active alkyl or 1-alkoxyethyl group having an asymmetric carbon atom.

  一种光学活性的羧酸衍生物，其通式表示为##STR1## 其中，R代表具有1至20个碳原子的正常烷基基团，m和n表示0或1，但不能同时为1，X代表氢或卤素原子，Y代表氢或氟原子，前提是当Y是氢原子时，X是卤素原子，当n为0时，Y是氢原子，Q *代表具有不对称碳原子的光学活性烷基或1-烷氧乙基基团。
• Optically active carboxylic acid derivatives and liquid crystalline compositions comprising them
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0231853A2

  公开（公告）日：1987-08-12

  An optically active carboxylic acid derivative represented by the general formula wherein R represents a normal alkyl group having l to 20 carbon atoms, m and n represent 0 or l but are not l at the same time, X represents a hydrogen or halogen atom, Y represents a hydrogen or fluorine atom, provided that when Y is a hydrogen atom, X is a halogen atom, and that when n is 0, Y is a hydrogen atom, and Q* represents an optically active alkyl or l-alkoxyethyl group having an asymmetric carbon atom.

  由通式表示的光学活性羧酸衍生物 其中 R 代表具有 l 至 20 个碳原子的普通烷基，m 和 n 代表 0 或 l，但不同时为 l，X 代表氢原子或卤素原子，Y 代表氢原子或氟原子，条件是当 Y 为氢原子时，X 为卤素原子，当 n 为 0 时，Y 为氢原子，Q* 代表具有不对称碳原子的光学活性烷基或 l-烷氧基乙基。
• Liquid crystal compounds
  申请人：Showa Shell Sekiyu Kabushiki Kaisha

  公开号：EP0350330A2

  公开（公告）日：1990-01-10

  Novel ferroelectric liquid crystal compounds showing three stable liquid crystal states so as to give particular optical response wave shape as well as particular optical and electric responses to impressed voltage of triangle wave shape in comparison with usual ferroelectric liquid crystals of bistable phase, whereby it is possible to provide electrooptical devices having larger picture area at lower cost. Typical compounds are represented by wherein n is an integer of 3-18 and m is an integer of 5-12.

  新型铁电液晶化合物显示出三种稳定的液晶状态，与通常的双稳态铁电液晶相比，具有特殊的光学响应波形，以及对三角波形电压的特殊光学和电学响应，从而能够以更低的成本提供具有更大图像面积的电光器件。典型的化合物有 其中 n 是 3-18 的整数，m 是 5-12 的整数。
• Novel liquid cristalline compounds having substituents
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0188222B1

  公开（公告）日：1992-04-29