试剂2-[2-(3-Prop-1-en-2-ylphenyl)propan-2-ylcarbamoyloxy]ethylmethacrylate | 126710-08-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 试剂2-[2-(3-Prop-1-en-2-ylphenyl)propan-2-ylcarbamoyloxy]ethylmethacrylate
• 英文名称: 2-[2-(3-Prop-1-en-2-ylphenyl)propan-2-ylcarbamoyloxy]ethyl methacrylate
• 英文别名: 2-[2-(3-prop-1-en-2-ylphenyl)propan-2-ylcarbamoyloxy]ethyl 2-methylprop-2-enoate
• CAS: 126710-08-5
• 化学式: C₁₉H₂₅NO₄
• 分子量: 331.4
• InChiKey: XZWLUVUMBIRBOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• [EN] FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME<br/>[FR] POLYMERSOMES ET NANORÉACTEURS SENSIBLES À LA FORCE; PROCÉDÉS LES UTILISANT
  申请人：ADOLPHE MERKLE INSTITUTE UNIV OF FRIBOURG

  公开号：WO2019034597A1

  公开（公告）日：2019-02-21

  The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled into polymersomes. The nucleobases formed hydrogen bonds which were disrupted upon force stimulation. The exposure of the disconnected nucleobases to the hydrophobic matrix of the membranes lead to a change of permeability which permitted the exchange of water-soluble molecules throughout the polymer matrix. Moreover, the encapsulation of horseradish peroxidase enabled the reaction of luminol with hydrogen peroxide to yield a luminescence producing species similar to the marine bioluminescence. Moreover, the same nano-reactors were employed to catalyze the formation of a polyacrylamide gel when force was applied. Insights into the change of permeability of supramolecular networks upon force are provided. These systems are useful for drug delivery, as nanoreactors and for the selective release of curing agents for 3D printing, or fragrances.

  DNA的机械诱导熔化特性被用来实现易受力破裂的膜。核碱基对被用作机械感受器。腺嘌呤和胸腺嘧啶功能化的互补两性分块共聚物自组装成聚合体囊。核碱基形成氢键，在受力刺激下被破坏。断开的核碱基暴露在膜的疏水基质中，导致渗透性的改变，从而允许水溶性分子在聚合物基质中交换。此外，封装辣根过氧化物酶使得辣根酰胺与过氧化氢反应产生类似海洋生物发光的发光物种。此外，当施加力时，相同的纳米反应器被用来催化聚丙烯酰胺凝胶的形成。提供了关于受力下超分子网络渗透性变化的见解。这些系统可用于药物传递、纳米反应器以及用于3D打印的固化剂或香料的选择性释放。
• 高熱伝導性封止材用組成物
  申请人：——

  公开号：JP2002265930A

  公开（公告）日：2002-09-18

  (57)【要約】\n【課題】 微細な備品に適用可能な、熱伝導性の高い封止材を提供する。\n【解決手段】 フィラーと樹脂を含む封止材形成用組成物において、封止材のマトリックスを構成する樹脂用に下式\n【化１】\nで表されるN-(3-イソプロペニル-α，α-ジメチルベンジル)-2-メタクリロイルオキシエチルカルバメートを用いる。\n

  (57) [摘要] Јn[主题事项] 提供一种适用于微小固定装置的高导热性封装材料。\在一种用于形成含有填料和树脂的封装材料的组合物中，使用了 N-(3-异丙烯基-α,α-二甲基苄基)-2-甲基丙烯酰氧乙基氨基甲酸酯，该化合物由下式ἀn[式 1]表示，用于构成封装材料基体的树脂。\n
• THERMAL INSULATION COMPONENTS AND METHODS OF MANUFACTURING THERMAL INSULATION COMPONENTS
  申请人：GM GLOBAL TECHNOLOGY OPERATIONS LLC

  公开号：US20210187903A1

  公开（公告）日：2021-06-24

  A thermal insulation component according to various aspects of the present disclosure includes a matrix, a crosslinking precursor, and a crosslinking initiator. The matrix includes a thermal insulation material having a thermal conductivity of less than or equal to about 5 W/mK. The crosslinking precursor is embedded in the matrix. The crosslinking precursor includes at least one of an acrylate functional group or a methacrylate functional group. The crosslinking initiator is embedded in the matrix. The crosslinking initiator is configured to decompose to initiate crosslinking of the crosslinking precursor. In certain aspects, the present disclosure also provides an electronics assembly including an electronic component and a thermal insulation material in thermal communication with the electronic component. In certain aspects, the present disclosure also provides methods of manufacturing the thermal insulation component.