decyl 3'-methylbiphenyl-3-carboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: decyl 3'-methylbiphenyl-3-carboxylate
• 英文别名: Decyl 3-(3-methylphenyl)benzoate；decyl 3-(3-methylphenyl)benzoate
• 化学式: C₂₄H₃₂O₂
• 分子量: 352.517
• InChiKey: ATXXBLWLCQBLPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  26
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  癸醇 、 3'-甲基联苯-3-羧酸 2.0~250.0 ℃ 、4.24 MPa 条件下， 反应 4.0h， 以100%的产率得到decyl 3'-methylbiphenyl-3-carboxylate
  参考文献：
  名称：

  [EN] AROMATIC ESTERS AND POLYESTERS, PRODUCTION WITHOUT ESTERIFICATION CATALYST, AND USE
  [FR] ESTERS ET POLYESTERS AROMATIQUES, PRODUCTION SANS CATALYSEUR D'ESTÉRIFICATION, ET UTILISATION

  摘要：

  这份披露涉及生产芳香酯的方法，这些芳香酯可用作增塑剂，而无需使用酯化催化剂，还涉及到含有这些芳香酯的聚合物组合物。它还涉及在不使用酯化催化剂的情况下生产芳香聚酯。这些芳香酯和聚酯可以通过在高温高压下，即在温度为100°C至350°C、压力≥100 psig（最好≥600 psig）的条件下，无需催化剂地通过羧酸与醇的酯化来生产。这些芳香酯和聚酯也可以通过在不使用酯化催化剂的情况下，将羧酸与甲醇或乙醇酯化，将产生的甲醇或乙醇酯与羧酸和任何副产物杂质分离，然后通过酯化或不酯化催化剂与醇和/或二醇进行酯交换来生产。

  公开号：

  WO2017222692A1

文献信息

• ALKYL AROMATIC HYDROALKYLATION FOR THE PRODUCTION OF PLASTISIZERS
  申请人：ENGINEERING COMPANY EXXONMOBIL RESEARCH AND

  公开号：US20140213709A1

  公开（公告）日：2014-07-31

  Provided are compounds of the following: wherein R 1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R 2 is the residue of a C 4 to C 14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
• Alkyl Aromatic Hydroalkylation for the Production of Plasticizers
  申请人：EXXONMOBIL CHEMICAL PATENTS INC.

  公开号：US20140212666A1

  公开（公告）日：2014-07-31

  Provided are compounds of the following: wherein R 1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R 2 is a C 4 to C 14 hydrocarbyl, preferably the residue of a C 4 to C 14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
• Indane and/or Tetralin Ester Plasticizers, and Blends Therefrom
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20160280884A1

  公开（公告）日：2016-09-29

  Plasticizers of indane and or tetralin esters and blends thereof with thermoplastic polymers, such as PVC, are disclosed.
• Alkyl Aromatic Hydroalkylation For The Production of Plasticizers
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20180022689A1

  公开（公告）日：2018-01-25

  Provided are compounds of the following: wherein R 1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R 2 is a C 4 to C 14 hydrocarbyl, preferably the residue of a C 4 to C 14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
• US8829093B2
  申请人：——

  公开号：US8829093B2

  公开（公告）日：2014-09-09