6-(5-(4-N,N'-diphenylaminophenyl)-1,3,4-oxadiazol-2-yl) quinoxalino[2,3-f] phenanthroline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 6-(5-(4-N,N'-diphenylaminophenyl)-1,3,4-oxadiazol-2-yl) quinoxalino[2,3-f] phenanthroline
• 英文别名: N,N-diphenyl-4-(5-quinoxalino[3,2-f][1,10]phenanthrolin-11-yl-1,3,4-oxadiazol-2-yl)aniline
• 化学式: C₃₈H₂₃N₇O
• 分子量: 593.647
• InChiKey: BCPVTVSMGRYFCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  46
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93.7
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 在 吡啶 、 氯化亚砜 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 96.0h， 生成 6-(5-(4-N,N'-diphenylaminophenyl)-1,3,4-oxadiazol-2-yl) quinoxalino[2,3-f] phenanthroline
  参考文献：
  名称：

  Synthesis of efficient blue and red light emitting phenanthroline derivatives containing both hole and electron transporting properties

  摘要：

  Two phenanthroline derivatives containing a hole transporting triphenylamine and an electron transporting 1,3,4-oxadiazole unit have been prepared with high yield. UV-vis absorption and fluorescence measurement indicated they are high efficient light-emitting materials. The compounds are 6-(5-(4-N,N'-diphenylaminophenyl)-1,3,4-oxadiazol-2-yl) quinoxalino[2,3-f] phenanthroline (9, lambda(max)=635nm, 40% quantum yield), and 1-ethyl-2-(4-(5-(4-N,N'-diphenylaminophenyl)-1,3,4-oxadiazol-2-yl)phenyl)imidazo[4,5-f]phenanthroline (14, lambda(max)=461 nm, 78% quantum yield). Preliminary study on electroluminescence for the two fluorescent dyes prepared from vacuum evaporation resulted in blue and red light emitting organic light emitting diodes (OLED). (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.06.087