丙烯酸羧乙醇脂 | 51727-47-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 丙烯酸羧乙醇脂
• 英文名称: 2-methyl-acrylic acid 2-phenylcarbamoyloxy-ethyl ester
• 英文别名: 2-(((Phenylamino)carbonyl)oxy)ethyl methacrylate；2-(phenylcarbamoyloxy)ethyl 2-methylprop-2-enoate
• CAS: 51727-47-0
• 化学式: C₁₃H₁₅NO₄
• 分子量: 249.266
• InChiKey: UQFMGLLQCSSNQM-UHFFFAOYSA-N

物化性质

• 熔点：
  58-60 °C(Solv: ethyl acetate (141-78-6); hexane (110-54-3))
• 沸点：
  337.1±25.0 °C(Predicted)
• 密度：
  1.188±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  64.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 、 异氰酸苯酯 在 三乙烯二胺 作用下， 以 二氯甲烷 为溶剂， 生成 丙烯酸羧乙醇脂
  参考文献：
  名称：

  含恶唑烷酮结构的甲基丙烯酸酯的立体定向自由基聚合及聚氨酯甲基丙烯酸酯共聚物玻璃化转变温度的提高

  摘要：

  我们合成了具有恶唑烷酮结构的新型甲基丙烯酸酯单体（M1 ），并通过传统方法对M1进行了自由基聚合。所获得的聚合物( P1 )的玻璃化转变温度( T g )与聚(甲基丙烯酸甲酯)和典型的聚(氨基甲酸酯甲基丙烯酸酯)的玻璃化转变温度(T g )相比是显着高的值。M1和衍生自甲基丙烯酸2-羟乙酯和异氰酸苯酯( M2 )的单官能氨基甲酸酯甲基丙烯酸酯的共聚物(M2)表现出取决于M1的组成比的T g值线性上升。NMR分析以及单体反应率和Q - e值的估计表明，玻璃化转变温度的提高是由于立构规整性导致的，这意味着共聚物的间同立构规整度随着M1的组成比的增加而提高。此外， M1或M2与双官能聚氨酯丙烯酸酯的热固化反应成功进行， M1的固化产物的T g值远高于M2的固化产物。

  DOI：

  10.1002/pol.20230210

文献信息

• PIGMENT DISPERSION COMPOSITION, COLORED CURABLE COMPOSITION, COLOR FILTER FOR SOLID-STATE IMAGE SENSOR AND METHOD OF PRODUCING THE SAME, AND SOLID-STATE IMAGE SENSOR
  申请人：Kuge Toshihito

  公开号：US20120286145A1

  公开（公告）日：2012-11-15

  The invention provides a pigment dispersion composition including an azo pigment represented by formula (1), in which the azo pigment represented by formula (1) does not have an ionic hydrophilic group, an azo pigment derivative and a dispersant. In formula (1), G represents a hydrogen atom, an aliphatic group, an aryl group or a heterocyclic group; R 1 represents an amino group, an aliphatic oxy group, an aliphatic group, an aryl group or a heterocyclic group; R 2 represents a substituent; A represents a heterocyclic group; m represents an integer of 0 to 5; and n represents an integer of 1 to 4, wherein: when n=2, the azo pigment is a dimer formed via R 1 , R 2 , A or G; when n=3, the azo pigment is a a trimer formed via R 1 , R 2 , A or G; and when n=4, the azo pigment is a tetramer formed via R 1 , R 2 , A or G.

  本发明提供了一种颜料分散组合物，包括由公式（1）表示的偶氮颜料，其中由公式（1）表示的偶氮颜料不具有离子亲水基团，还包括偶氮颜料衍生物和分散剂。在公式（1）中，G表示氢原子，脂肪族基团，芳基基团或杂环基团；R1表示氨基基团，脂肪氧基团，脂肪族基团，芳基基团或杂环基团；R2表示取代基；A表示杂环基团；m表示0至5的整数；n表示1至4的整数，其中：当n=2时，偶氮颜料是通过R1、R2、A或G形成的二聚体；当n=3时，偶氮颜料是通过R1、R2、A或G形成的三聚体；当n=4时，偶氮颜料是通过R1、R2、A或G形成的四聚体。
• EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0947562A1

  公开（公告）日：1999-10-06

  In order to realise the objectives stated above, the thermosetting resin composition for carbon fibre reinforced composite materials of the present invention chiefly comprises the following components. (A) Thermosetting resin (B) Compound containing one functional group which can react with thermosetting resin (A) or its curing agent, and a moiety selected from the following formulae (1) to (4) Furthermore, the present invention also relates to a prepreg formed by impregnating reinforcing fibre with the aforesaid resin composition and to carbon fibre reinforced composite materials comprising reinforcing fibre and a cured aforesaid thermosetting resin composition. In accordance with the present invention, there can be obtained a thermosetting resin composition where the adhesion to reinforcing fibre by the cured material and the elastic modulus of the cured material are excellent, and by using this resin composition there can be obtained carbon fibre reinforced composite materials which are excellent in their 0° compressive strength, 90° tensile strength and interlaminar shear strength, and which also have outstanding impact resistance.

  为了实现上述目标，本发明用于碳纤维增强复合材料的热固性树脂组合物主要包括以下成分。 (A) 热固性树脂 (B) 含有一个可与热固性树脂（A）或其固化剂发生反应的官能团和一个选自下式 （1）至（4）的分子的化合物 此外，本发明还涉及用上述树脂组合物浸渍增强纤维而形成的预浸料，以及由增强纤维和固化的上述热固性树脂组合物组成的碳纤维增强复合材料。 根据本发明，可以获得一种热固性树脂组合物，在这种组合物中，固化材料与增强纤维的粘附性和固化材料的弹性模量都非常好，使用这种树脂组合物可以获得 0°抗压强度、90°抗拉强度和层间剪切强度都非常好的碳纤维增强复合材料，这种材料还具有出色的抗冲击性。
• Carbonate copolymers
  申请人：Tyco Healthcare Group LP

  公开号：EP2028210A1

  公开（公告）日：2009-02-25

  Copolymer compositions are provided which include a cyclic monomer and an aromatic cyclic carbonate. The copolymer may be produced, in embodiments, by a ring-opening polymerization reaction initiated by the aromatic cyclic carbonate. The resulting copolymer may be utilized in producing medical devices, drug delivery devices, and/or coatings for medical devices.

  共聚物组合物包括环状单体和芳香族环状碳酸酯。共聚物可通过芳香族环状碳酸酯引发的开环聚合反应生产。生成的共聚物可用于生产医疗器械、给药装置和/或医疗器械涂层。
• Processed pigment, pigment-dispersed composition, colored photosensitive composition, color filter, liquid crystal display element, and solid image pickup element
  申请人：FUJIFILM Corporation

  公开号：EP2048539A1

  公开（公告）日：2009-04-15

  Provided are a processed pigment excellent in dispersibility and dispersion stability, a pigment-dispersed composition excellent in dispersibility and dispersion stability of a pigment that uses the processed pigment, a colored photosensitive composition using the pigment-dispersed composition, and a color filter having improved color properties that uses the colored photosensitive composition, in which a pigment is covered with at least one of a specific polymer compound selected from the following (SP-1) to (SP-3); (SP-1) A polymer compound having a heterocycle on a side chain, (SP-2) A graft polymer compound having a weight average molecular weight of from 1,000 to 100000, (SP-3) A polymer compound represented by the following formula (3-1), wherein, RC , RD, A1 and P1 respectively represent an organic linkage group, a single bond or a divalent organic linkage group, a monovalent organic group containing such as an organic dye structure, and a polymer skeleton.

  本发明提供了一种分散性和分散稳定性优异的加工颜料、一种使用该加工颜料的分散性和分散稳定性优异的颜料分散组合物、一种使用该颜料分散组合物的彩色感光组合物以及一种使用该彩色感光组合物的颜色特性得到改善的滤色片，其中，颜料被至少一种选自以下(SP-1)至(SP-3)的特定高分子化合物覆盖； (SP-1) 侧链上有杂环的聚合物化合物、 (SP-2) 一种接枝聚合物化合物，其重量平均分子量为 1,000 至 100000、 (SP-3) 下式(3-1)所代表的聚合物化合物、 其中，RC、RD、A1 和 P1 分别代表有机连接基团、单键或二价有机连接基团、含有诸如有机染料结构的一价有机基团和聚合物骨架。
• PIGMENT DISPERSION COMPOSITION, CURABLE COLOR COMPOSITION, COLOR FILTER AND METHOD FOR PRODUCING THE SAME
  申请人：FUJIFILM Corporation

  公开号：EP2218756A1

  公开（公告）日：2010-08-18

  The present invention provides: a pigment dispersion composition including (A) an organic pigment, (B) a pigment derivative represented by Formula (I) below and (C) a polymer compound having a pigment-adsorptive functional group; a curable color composition including the pigment dispersion composition, a polymerizable compound and a polymerization initiator; and a color filter having a color region formed using the curable color composition and a method for producing the same. Q represents an organic colorant residue; A represents an ethylene group or the like; and R represents a hydroxyl group or a group represented by -NH-A-Z; Z represents -SO3H, -COOH or a salt thereof; and n represents an integer of from 1 to 4. When R represents -NH-A-Z, the structures represented by the two -NH-A-Zs bonded to the triazine ring contained in each of the n partial structures bonded to Q may be the same as each other or different from each other.

  本发明提供：一种颜料分散组合物，包括(A)有机颜料、(B)下式(I)代表的颜料衍生物和(C)具有颜料吸附官能团的高分子化合物；一种可固化颜色组合物，包括该颜料分散组合物、可聚合化合物和聚合引发剂；以及一种具有使用该可固化颜色组合物形成的颜色区域的彩色滤光片及其生产方法。Q 代表有机着色剂残基；A 代表乙烯基或类似基团；R 代表羟基或由-NH-A-Z 代表的基团；Z 代表-SO3H、-COOH 或其盐；n 代表 1 至 4 的整数。 当 R 代表-NH-A-Z 时，与 Q 键合的 n 个部分结构中的每个部分结构所包含的与三嗪环键合的两个-NH-A-Z 所代表的结构可以彼此相同，也可以彼此不同。