乙基 (1-萘基甲基)醚 | 58530-15-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 乙基 (1-萘基甲基)醚
• 中文别名: 乙基(1-萘基甲基)醚
• 英文名称: (α-naphthylmethyl) ethyl ether
• 英文别名: 1-(Ethoxymethyl)naphthalene
• CAS: 58530-15-7
• 化学式: C₁₃H₁₄O
• 分子量: 186.254
• InChiKey: FOVHZKQVNFYHQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙基 (1-萘基甲基)醚 在 bis(1,5-cyclooctadiene)nickel (0) 、 1,3-bis(adamantan-2-yl)imidazolin-2-yliden chloride 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 18.0h， 以69%的产率得到甲基萘
  参考文献：
  名称：

  在没有外部还原剂的情况下，镍催化的芳基烷基醚还原裂解为芳烃

  摘要：

  芳基醚的CO键的还原裂解在有机合成中具有许多潜力。尽管已经有几种可以促进芳基醚还原裂解的催化剂...

  DOI：

  10.1039/c5sc00305a
• 作为产物：
  描述：

  (氯甲基)萘 在 sodium ethanolate 作用下， 生成 乙基 (1-萘基甲基)醚
  参考文献：
  名称：

  Kruyt; Veldstra, 1951, vol. 63, p. 398,402, 403

  摘要：

  DOI：

文献信息

• AGENT FOR INTRODUCING PROTECTING GROUP FOR HYDROXY GROUP AND/OR MERCAPTO GROUP
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20170305809A1

  公开（公告）日：2017-10-26

  A novel agent for introducing a protecting group for a hydroxy group and/or a mercapto group that can be introduced and removed under mild conditions is provided. The agent for introducing a protecting group for a hydroxy group and/or mercapto group of a substrate compound having the hydroxy group and/or mercapto group is represented by the following formula (I), wherein A represents a ring structure having 1 to 5 rings in which two carbon atoms of an adjacent benzene ring are included, the ring structure comprises a substituted or unsubstituted five-membered ring or six-membered ring and optionally include a heterocycle; each of R 1 , R 2 , R 3 , and R 4 is independently a hydrogen atom or a linear or branched alkyl group having 1 to 5 carbon atoms; and X is a halogen atom or OSO 2 R 5 (R 5 =an aryl group or an alkyl group).

  提供了一种用于在温和条件下引入和去除保护羟基和/或巯基的新型试剂。用于引入底物化合物的具有羟基和/或巯基的保护基的试剂由以下式(I)表示，其中A代表含有1至5个环的环结构，其中包括相邻苯环的两个碳原子，该环结构包括取代或未取代的五元环或六元环，并且可以包括一个杂环；每个R1、R2、R3和R4独立地是氢原子或具有1至5个碳原子的直链或支链烷基基团；X是卤原子或OSO2R5（R5=芳基或烷基）。
• [EN] 2,3-DIHYDRO-6-NITROIMIDAZO (2,1-B) OXAZOLE COMPOUNDS FOR THE TREATMENT OF TUBERCULOSIS<br/>[FR] COMPOSES 2,3-DIHYDRO-6-NITROIMIDAZO (2,1-B) OXAZOLE POUR LE TRAITEMENT DE LA TUBERCULOSE
  申请人：OTSUKA PHARMA CO LTD

  公开号：WO2005042542A1

  公开（公告）日：2005-05-12

  The present invention provides a 2,3-dihydro-6-nitroimidazo[2,1-b]oxazole compound represented by the following general formula: (1)in the above formula (1), R1 represents a hydrogen atom or C1-C6 alkyl group, n represents an integer of 0 to 6, R1 and -(CH2)nR2 may form a spiro ring represented by the formula (30) below, together with the adjacent carbon atom (in the formula below, RRR represents a piperidyl group which may have substituents on the piperidine ring), (30)and R2 represents a benzothiazolyloxy group, quinolyloxy group, pyridyloxy group or the like. The present compound has an excellent bactericidal action against Mycobacterium tuberculosis, multi-drug-resistant Mycobacterium tuberculosis, and atypical acid-fast bacteria.

  本发明提供了一种由以下一般式表示的2,3-二氢-6-硝基咪唑[2,1-b]噁唑化合物：(1)在上述式(1)中，R1代表氢原子或C1-C6烷基，n代表0至6的整数，R1和-(CH2)nR2可以与下面的式(30)一起形成一个螺环，与相邻的碳原子一起（在下面的式中，RRR代表可能在哌啶环上具有取代基的哌啶基），(30)和R2代表苯并噻唑氧基、喹啉氧基、吡啶氧基或类似物。该化合物对结核分枝杆菌、多药耐药结核分枝杆菌和非典型耐酸细菌具有出色的杀菌作用。
• DISPERSANT AND PRINTING INK COMPOSITION
  申请人：Seiko Epson Corporation

  公开号：US20180273763A1

  公开（公告）日：2018-09-27

  A printing ink composition contains a disperse dye, a dispersant, and water, in which the dispersant contains one or more compounds represented by: wherein each Ar independently represents an aromatic ring having 6 to 24 carbon atoms, R1 and R2 independently represent a substituent selected from the group consisting of H, OCH 3 , OH, COOH, SO 3 H, OSO 3 H, an alkyl group having 1 to carbon atoms, and a salt thereof, R3 represents a substituent selected from the group consisting of OH, COOH, SO 3 H, OSO 3 H, and a salt thereof, R4 represents a substituent selected from the group consisting of H, OCH 3 , OC 2 H 5 , an alkyl group having 1 to 3 carbon atoms, and a salt thereof, the substituent introduction numbers a, b, c, and d each represent an integer of 1 to 8, and the number of repetitions m represents an integer of 1 to 50.

  一种印刷油墨组合物包含分散染料、分散剂和水，其中分散剂包含一个或多个由以下化合物表示的化合物：其中每个Ar独立地表示具有6到24个碳原子的芳香环，R1和R2独立地表示从H、OCH3、OH、COOH、SO3H、OSO3H、具有1到碳原子的烷基和其盐中选择的取代基，R3表示从OH、COOH、SO3H、OSO3H和其盐中选择的取代基，R4表示从H、OCH3、OC2H5、具有1到3个碳原子的烷基和其盐中选择的取代基，取代基引入数字a、b、c和d分别表示1到8的整数，重复次数m表示1到50的整数。
• PROPHYLACTIC OR AMELIORATING AGENT FOR PIGMENTATION
  申请人：Yamasaki Takashi

  公开号：US20120282203A1

  公开（公告）日：2012-11-08

  An object of the present invention is to provide a prophylactic or ameliorating agent for pigmentation having a novel scaffold and an external preparation for skin containing the same as a component. The object is achieved by providing a prophylactic or ameliorating agent for pigmentation comprising a compound represented by the following general formula (1), an isomer thereof, and/or a pharmacologically acceptable salt thereof and an external preparation for skin containing the same as a component: [wherein R 1 represents a hydrogen atom or a linear chain or branched alkyl group having 1 to 8 carbon atom(s); R 2 represents a hydrogen atom, a substituted or unsubstituted aliphatic hydrocarbon group having 1 to 8 carbon atom(s), a substituted or unsubstituted aromatic group, a substituted or unsubstituted polycyclic fused aromatic group, or a substituted or unsubstituted heterocyclic group having a 5 to 12 carbon atoms; R 3 represents a substituted or unsubstituted aromatic group, a substituted or unsubstituted polycyclic fused aromatic group, or a substituted or unsubstituted heterocyclic group having a 5 to 15 carbon atoms; n represents an integer of 1 or 2; and m represents an integer of 0 to 3.]

  本发明旨在提供一种具有新型支架的色素沉着预防或改善剂和含其作为组分的皮肤外用制剂。该目的通过提供以下通式（1）所表示的化合物、其异构体和/或其药理学上可接受的盐，并作为组分含有其皮肤外用制剂来实现：[式中，R1表示氢原子或具有1至8个碳原子的线性链或支链烷基；R2表示氢原子，具有1至8个碳原子的取代或未取代的脂肪烃基，取代或未取代的芳香族基，取代或未取代的多环融合芳香族基，或具有5至12个碳原子的取代或未取代的杂环基；R3表示取代或未取代的芳香族基，取代或未取代的多环融合芳香族基，或具有5至15个碳原子的取代或未取代的杂环基；n表示1或2的整数；m表示0至3的整数。]
• ACTINIC RAY-SENSITIVE OR RADIATION-SENSITIVE RESIN COMPOSITION, AND ACTINIC RAY-SENSITIVE OR RADIATION-SENSITIVE FILM AND PATTERN FORMING METHOD USING THE COMPOSITION
  申请人：INASAKI Takeshi

  公开号：US20130004888A1

  公开（公告）日：2013-01-03

  An object of the present invention is to provide an actinic ray-sensitive or radiation-sensitive resin composition that can form independent line patterns with high resolution and excellent shapes and shows excellent resist performances including roughness characteristics, and to provide an actinic ray-sensitive or radiation-sensitive film and a pattern forming method using the composition. The actinic ray-sensitive or radiation-sensitive resin composition contains a compound (P) that contains at least one phenolic hydroxyl group and at least one group in which a hydrogen atom of a phenolic hydroxyl group is substituted with a group represented by the following General Formula (1) (the respective symbols in the formula represent the same definitions as in the claims and the specification).

  本发明的目的是提供一种光致或辐射致敏树脂组合物，该组合物可以形成具有高分辨率和优秀形状的独立线型图案，并显示出包括粗糙特性在内的优异的抗阻性能，以及提供使用该组合物的光致或辐射致敏膜和图案形成方法。光致或辐射致敏树脂组合物包含一种化合物（P），该化合物含有至少一个酚羟基和至少一个氢原子被代表如下通式（1）的基团取代的酚羟基的基团（式中各符号与权利要求书和说明书中的定义相同）。