4-[1-[3-(4-hydroxyphenyl)-4-methylcyclohexyl]-1-methylethyl] phenol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[1-[3-(4-hydroxyphenyl)-4-methylcyclohexyl]-1-methylethyl] phenol
• 英文别名: 2,8-bis-4-hydroxyphenylmenthane；4-[5-[2-(4-Hydroxyphenyl)propan-2-yl]-2-methylcyclohexyl]phenol
• 化学式: C₂₂H₂₈O₂
• 分子量: 324.463
• InChiKey: IZHWVJYOHQYQQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯酚 、 limonene. 在 (2-trihydroxysilyl)propanesulfonic acid and (3-mercaptopropyl)triethoxysilane functionalized zirconia catalyst 作用下， 反应 22.0h， 生成 1,3-bis-4-hydroxyphenylmenthane 、 4-[1-[3-(4-hydroxyphenyl)-4-methylcyclohexyl]-1-methylethyl] phenol
  参考文献：
  名称：

  Process for preparing bisphenols

  摘要：

  一种制备芳香双酚的方法，其中该方法包括在催化剂系统的存在下，将芳香羟基化合物与具有双重官能团的烷基化剂反应。用于该过程的催化剂系统选自包括杂多酸化合物、粘土、功能化金属氧化物催化剂和上述催化剂的组合的群体。

  公开号：

  US20060135825A1

文献信息

• Method for the preparation of aromatic chloroformates
  申请人：Davis Charles Gary

  公开号：US20060293535A1

  公开（公告）日：2006-12-28

  A method for preparing an aromatic chloroformate comprising, introducing a mixture of at least one aromatic hydroxyl compound, phosgene, at least one solvent, and at least one organic base into a flow reactor to obtain a unidirectionally flowing reaction mixture. The unidirectionally flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aromatic chloroformate.

  一种制备芳香氯甲酸酯的方法包括，将至少一种芳香羟基化合物、光气、至少一种溶剂和至少一种有机碱的混合物引入流动反应器中，以获得单向流动的反应混合物。将单向流动的反应混合物保持在约0°C至约60°C的温度下，以产生包含芳香氯甲酸酯的单一产物流。
• Method for the preparation of aliphatic chloroformates
  申请人：Davis Charles Gary

  公开号：US20060084822A1

  公开（公告）日：2006-04-20

  A method for preparing an aliphatic chloroformate comprising, introducing a mixture of at least one aliphatic hydroxyl compound, phosgene, at least one solvent, and optionally at least one organic base into a flow reactor to obtain a unidirectional flowing reaction mixture. The at least one aliphatic hydroxyl compound comprises at least one aliphatic hydroxyl group. The unidirectional flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aliphatic chloroformate.

  制备脂肪基氯甲酸酯的方法包括，将至少一种脂肪基羟基化合物、光气、至少一种溶剂以及可选的至少一种有机碱的混合物引入流动反应器中，以获得单向流动的反应混合物。至少一种脂肪基羟基化合物包括至少一种脂肪基羟基。将单向流动的反应混合物保持在约0°C至约60°C的温度下，以产生包含脂肪基氯甲酸酯的单一产物流。
• Methods for producing and purifying 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine monomers and polycarbonates derived therefrom
  申请人：Rai Kumar Vinod

  公开号：US20050288517A1

  公开（公告）日：2005-12-29

  Disclosed herein is a method for producing a 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine. The method comprises forming a reaction mixture comprising at least one substituted or unsubstituted phenolphthalein compound, at least one substituted or unsubstituted primary hydrocarbyl amine, and an acid catalyst; and heating the reaction mixture to form 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine. An adduct of the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine is formed either by using an excess of the primary hydrocarbyl amine in the first heating step, or by isolating crude 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine after the heating step and then reacting with a further amount of the primary hydrocarbyl amine. The 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine has a formula: where R 1 is selected from the group consisting of a hydrogen and a hydrocarbyl group, and R 2 is selected from the group consisting of a hydrogen, a hydrocarbyl group, and a halogen.

  本文公开了一种制备2-烃基-3,3-双(4-羟基芳基)邻苯二酰亚胺的方法。该方法包括形成一个反应混合物，其中包括至少一种取代或未取代的苯酞化合物、至少一种取代或未取代的一次烃基胺和酸催化剂；并加热反应混合物以形成2-烃基-3,3-双(4-羟基芳基)邻苯二酰亚胺。2-烃基-3,3-双(4-羟基芳基)邻苯二酰亚胺的加合物可通过在第一次加热步骤中使用过量的一次烃基胺来形成，或者通过在加热步骤后分离粗糙的2-烃基-3,3-双(4-羟基芳基)邻苯二酰亚胺然后与进一步的一次烃基胺反应来形成。2-烃基-3,3-双(4-羟基芳基)邻苯二酰亚胺具有以下化学式：其中R1选自氢和烃基团组成的群，R2选自氢、烃基团和卤素组成的群。
• Process for preparing bisphenols
  申请人：Kishan Gurram

  公开号：US20060135825A1

  公开（公告）日：2006-06-22

  A process for preparing aromatic bisphenols, wherein the method comprises reacting an aromatic hydroxy compound with an alkylating agent having a functionality of two in the presence of a catalyst system. The catalyst system used for the process is selected from the group consisting of a heteropolyacid compound, a clay, a functionalized metal oxide catalyst and combinations of the foregoing.

  一种制备芳香双酚的方法，其中该方法包括在催化剂系统的存在下，将芳香羟基化合物与具有双重官能团的烷基化剂反应。用于该过程的催化剂系统选自包括杂多酸化合物、粘土、功能化金属氧化物催化剂和上述催化剂的组合的群体。
• Method for depolymerizing aromatic polycarbonate
  申请人：——

  公开号：US20040054238A1

  公开（公告）日：2004-03-18

  An aromatic polycarbonate depolymerization method comprising reacting an aromatic polycarbonate with water, an aliphatic alcohol having 1 to 6 carbon atoms or a phenol which may be substituted by a hydrocarbon group having 1 to 10 carbon atoms in the critical fluid of carbon dioxide or with the critical fluid of an aliphatic alcohol having 1 to 6 carbon atoms or a phenol which may be substituted by a hydrocarbon group having 1 to 10 carbon atoms. With this depolymerization method, the aromatic polycarbonate is depolymerized at a high reaction rate and effective components formed by depolyemrization can be recovered at a high rate. Therefore, the effective components are recovered from the scrapped or used aromatic polycarbonate by this method and recycled.

  一种芳香族聚碳酸酯解聚方法，包括在二氧化碳的临界流体中，将芳香族聚碳酸酯与水、具有1至6个碳原子的脂肪醇或可由具有1至10个碳原子的烃基取代的酚，或与具有1至6个碳原子的脂肪醇或可由具有1至10个碳原子的烃基取代的酚的临界流体反应。使用该解聚方法，芳香族聚碳酸酯可以高速解聚，解聚后的有效组分可以高效地回收。因此，通过该方法可以从废弃或使用过的芳香族聚碳酸酯中回收有效组分并进行再循环利用。