乙基3-(2-氨基-5-溴-3-吡啶基)丙烯酸酯 | 943419-35-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 乙基3-(2-氨基-5-溴-3-吡啶基)丙烯酸酯
• 中文别名: 3-(2-氨基-5-溴-3-吡啶基)丙烯酸乙酯
• 英文名称: (E)-Ethyl 3-(2-amino-5-bromopyridin-3-YL)acrylate
• 英文别名: ethyl (E)-3-(2-amino-5-bromopyridin-3-yl)prop-2-enoate
• CAS: 943419-35-0
• 化学式: C₁₀H₁₁BrN₂O₂
• 分子量: 271.11
• InChiKey: HSKGBWXXHWXUPV-ONEGZZNKSA-N

物化性质

• 沸点：
  364.2±42.0 °C(Predicted)
• 密度：
  1.518±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  65.2
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2933399090
• 危险性防范说明：
  P261,P264,P271,P280,P302+P352,P304+P340,P305+P351+P338,P312,P362,P403+P233,P501
• 危险性描述：
  H315,H319,H335

文献信息

• Method of forming an exfoliated or intercalated filler material
  申请人：Agency for Science, Technology and Research

  公开号：US11248106B2

  公开（公告）日：2022-02-15

  According to the present disclosure, a method of forming an exfoliated or intercalated filler material is provided, wherein the said method comprises the steps of mixing particles of filler material such as montmorillonite (MMT), mica, layered double hydroxide (LDH), and attapulgite (AT) dispersed in an aqueous medium with cationic acrylate monomers to form modified particles comprising positively charged ions, dispersing the modified particles in organic medium to form a dispersion, contacting said dispersion with an organo-silicate such as tetraethyl orthosilicate (TEOS) and a functionalizing agent comprising an organo-silane such as aminopropyltrimethoxysilane (APTMS), in the presence of a basic catalyst to form a layer of silica on the modified particles. The present disclosure also relates to an exfoliated or intercalated filler material obtained by the said method as well as a method of forming a resin/clay nanocomposite.

  根据本公开，提供了一种形成剥落或插层填料材料的方法，其中所述方法包括以下步骤：将分散在水介质中的填料材料颗粒，如蒙脱土(MMT)、云母、层状双氢氧化物(LDH)和阿塔波来石(AT)与阳离子丙烯酸酯单体混合，以形成包含带正电离子的改性颗粒、将改性颗粒分散在有机介质中以形成分散液，在碱性催化剂存在下，将所述分散液与有机硅酸盐（如正硅酸四乙酯（TEOS））和由有机硅烷（如氨基丙基三甲氧基硅烷（APTMS））组成的官能化剂接触，以在改性颗粒上形成二氧化硅层。本公开还涉及通过上述方法获得的剥离或插层填料材料，以及形成树脂/粘土纳米复合材料的方法。
• METHOD OF FORMING AN EXFOLIATED OR INTERCALATED FILLER MATERIAL
  申请人：Agency for Science, Technology and Research

  公开号：US20210108050A1

  公开（公告）日：2021-04-15

  According to the present disclosure, a method of forming an exfoliated or intercalated filler material is provided, wherein the said method comprises the steps of mixing particles of filler material such as montmorillonite (MMT), mica, layered double hydroxide (LDH), and attapulgite (AT) dispersed in an aqueous medium with cationic acrylate monomers to form modified particles comprising positively charged ions, dispersing the modified particles in organic medium to form a dispersion, contacting said dispersion with an organo-silicate such as tetraethyl orthosilicate (TEOS) and a functionalizing agent comprising an organo-silane such as aminopropyltrimethoxysilane (APTMS), in the presence of a basic catalyst to form a layer of silica on the modified particles. The present disclosure also relates to an exfoliated or intercalated filler material obtained by the said method as well as a method of forming a resin/clay nanocomposite.
• [EN] METHOD OF FORMING AN EXFOLIATED OR INTERCALATED FILLER MATERIAL<br/>[FR] PROCÉDÉ DE FORMATION D'UN MATÉRIAU DE REMPLISSAGE EXFOLIÉ OU INTERCALÉ
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2018182522A1

  公开（公告）日：2018-10-04

  According to the present disclosure, a method of forming an exfoliated or intercalated filler material is provided, wherein the said method comprises the steps of mixing particles of filler material such as montmorillonite (MMT), mica, layered double hydroxide (LDH), and attapulgite (AT) dispersed in an aqueous medium with cationic acrylate monomers to form modified particles comprising positively charged ions, dispersing the modified particles in organic medium to form a dispersion, contacting said dispersion with an organo-silicate such as tetraethyl orthosilicate (TEOS) and a functionalizing agent comprising an organo-silane such as aminopropyltrimethoxysilane (APTMS), in the presence of a basic catalyst to form a layer of silica on the modified particles. The present disclosure also relates to an exfoliated or intercalated filler material obtained by the said method as well as a method of forming a resin/clay nanocomposite.
• [EN] A REINFORCED POLYOLEFIN COMPOSITE<br/>[FR] COMPOSITE DE POLYOLÉFINE RENFORCÉ
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2019190407A1

  公开（公告）日：2019-10-03

  A reinforced polyolefin composite is provided. The reinforced polyolefin composite comprises a polyolefin such as polyethylene or polypropylene, a rigid fibre micro filler such as glass fiber, carbon or cellulosic fibers, and at least one nano filler such as clay. The reinforced polyolefin composite may also comprise a modified polyolefin, which has a polar functional group such as maleate monoester, an acid anhydride or an acrylate grafted thereon. The clay nano filler may also be modified with an organosilane. The reinforced polyolefin composite may also comprise a stabilizer or other additives. A method of producing the reinforced polyolefin composite is also provided, comprising mixing a polyolefin, a rigid micro filler and at least one nano filler to form a mixture, melting the mixture and kneading the melted mixture. The obtained reinforced polyolefin composite is used in transportation, infrastructure, consumer goods and construction.