9,9-bis-(4-amino-3-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl)phenyl)fluorene

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-bis-(4-amino-3-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl)phenyl)fluorene
• 英文别名: 2-[2-Amino-5-[9-[4-amino-3-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)phenyl]fluoren-9-yl]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-ol；2-[2-amino-5-[9-[4-amino-3-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)phenyl]fluoren-9-yl]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-ol
• 化学式: C₃₁H₂₀F₁₂N₂O₂
• 分子量: 680.493
• InChiKey: JFVJSADCTNEOGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  47
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  92.5
• 氢给体数：
  4
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  9,9-双(4-氨基苯基)芴 、 六氟丙酮 在 三氟乙酸 作用下， 反应 20.0h， 以96.3%的产率得到9,9-bis-(4-amino-3-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl)phenyl)fluorene
  参考文献：
  名称：

  含フッ素芳香族ジアミンの製造方法

  摘要：

  抑制芳香族二胺中的亚胺类副产物，提供一种高选择性和高收率地制备含氟芳香族二胺的方法，其中将六氟异丙醇基（-C（CF3）2OH）与芳香环中的芳香族二胺结合。通过在1,1,1,3,3,3-六氟-2-丙醇中使芳香族二胺和六氟丙酮反应，得到结合有六氟异丙醇基的含氟芳香族二胺的制备方法。芳香族二胺和含氟芳香族二胺可以是芳香族多环化合物或芳香族单环化合物。

  公开号：

  JP2019199459A

文献信息

• 함불소 중합성 단량체 및 그것을 이용한 고분자 화합물
  申请人：Central Glass Company, Limited 샌트랄 글래스 컴퍼니 리미티드(519990460345)

  公开号：KR20150046164A

  公开（公告）日：2015-04-29

  플루오렌디아민 화합물에 HFIP기를 도입한 식 (2)로 나타내어지는 HFIP기 함유 플루오렌디아민과, HFIP기 함유 고분자 화합물을 제공한다. [화학식 71] (식 중, R은 수소 원자, 불소 원자, 염소 원자, 브롬 원자, 탄소수 1∼4의 알킬기, 임의의 수의 수소 원자가 불소 원자로 치환된 탄소수 1∼4의 플루오로알킬기, 페닐기, 메톡시기, 니트로기로 이루어지는 군에서 선택되는 1종의 치환기를 나타낸다. R는 수소 원자, 불소 원자, 염소 원자, 브롬 원자, 요오드 원자, 페닐기, 나프틸기, 비페닐기, 술폰산기, -C≡C-C(CH)OH기, -C≡C-CH기, -C≡C-Si(CH)기로 이루어지는 군에서 선택되는 1종의 치환기를 나타낸다. HFIP는 -C(CF)OH기를 나타낸다. m, n은 각각 독립적으로 0∼2 중 어느 하나의 정수이고, 1≤m+n≤4이다.)

  这段文字是关于一种含有HFIP基团的氟芳胺化合物的化学式的描述。
• Fluorine-Containing Polymerizable Monomer And Polymer Compound Using Same
  申请人：Central Glass Company, Limited

  公开号：US20140148548A1

  公开（公告）日：2014-05-29

  The present invention provides a fluorine-containing fluorenediamine of the formula (2): where R 1 represents one kind of substituent group selected from the group consisting of a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a C 1 -C 4 alkyl group, a C 1 -C 4 fluoroalkyl group in which any number of hydrogen atoms can be substituted by a fluorine atom, a phenyl group, a methoxy group and a nitro group; R 2 represents one kind of substituent group selected from the group consisting of a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a phenyl group, a naphthyl group, a biphenyl group, a sulfonic acid group, a —C≡C—C(CH 3 ) 2 OH group, a —C≡C—C 6 H 5 group and a —C≡C—Si(CH 3 ) 3 group; HFIP represents a —C(CF 3 ) 2 OH group; and m and n each independently represent an integer of 0 to 2 and satisfy a condition of 1≦m+n≦4.

  本发明提供了一种具有如下公式（2）的含氟芴二胺：其中R1代表从氢原子、氟原子、氯原子、溴原子、C1-C4烷基、C1-C4氟烷基（其中任意数量的氢原子可被氟原子取代）、苯基、甲氧基和硝基等组成的一种取代基；R2代表从氢原子、氟原子、氯原子、溴原子、碘原子、苯基、萘基、联苯基、磺酸基、—C≡C—C(CH3)2OH基、—C≡C—C6H5基和—C≡C—Si(CH3)3基等组成的一种取代基；HFIP代表—C(CF3)2OH基；m和n分别独立地表示0到2的整数，并满足1≦m+n≦4的条件。
• GAS SEPARATION MEMBRANE
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP2716351B1

  公开（公告）日：2016-06-29
• Gas Separation Membrane
  申请人：Yamanaka Kazuhiro

  公开号：US20140174293A1

  公开（公告）日：2014-06-26

  [Problem] Diamine and carboxylic dianhydride for polymerizing a hexafluoroisopropylidene group-containing polyimide are limited in chemical structure when developed into a polyimide membrane, so that it is difficult to design a chemical structure with consideration paid to the strength and separation performance of a gas separation membrane. A gas separation membrane easily soluble in an organic solvent, excellent in formability so as to be readily usable for a gas separation membrane, and excellent in gas separation performance is obtained. [Solution] A gas separation membrane, including: a polyimide that contains a repeating unit represented by general formula (1). [In the formula (1), R 1 is a divalent organic group and R 2 is a tetravalent organic group, R 1 containing a 2-hydroxy-1,1,1,3,3,3-hexafluoroisopropyl group (—C(CF 3 ) 2 OH).]
• US9061253B2
  申请人：——

  公开号：US9061253B2

  公开（公告）日：2015-06-23