3-(3-oxo-2,3-dihydro-1H-isoindol-1-ylidenemethyl)-1H-isoindol-1-one | 205944-06-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 3-(3-oxo-2,3-dihydro-1H-isoindol-1-ylidenemethyl)-1H-isoindol-1-one
• 英文别名: 1-oxo-1H-3-(1-oxoisoindolin-3-ylidenemethyl)isoindole；3-oxoisoindenyl-3'-oxoisoindolinylidene-1,1'-methylidine；3,3-[1-(1-oxo-1H-isoindol-3-yl)methylene]-2,3-dihydro-1H-isoindol-1-one；3,3'-[1-(1-oxo-1H-isoindol-3-yl)methyl]-2,3-dihydro-1H-isoindol-1-one；1-[(1-oxo-1H-isoindol-3-yl)methyl]isoindolin-3-one；3-[(3-Oxo-2,3-dihydro-1H-isoindol-1-ylidene)methyl]-1H-isoindol-1-one；3-[(3-oxoisoindol-1-ylidene)methyl]isoindol-1-one
• CAS: 205944-06-5
• 化学式: C₁₇H₁₀N₂O₂
• 分子量: 274.279
• InChiKey: DIYGLLIKBDUTBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  邻苯二甲酰甘氨酸 、 3-(3-oxo-2,3-dihydro-1H-isoindol-1-ylidenemethyl)-1H-isoindol-1-one 在 zinc(II) oxide 作用下， 反应 0.83h， 以32%的产率得到zinc 5,15-di(N-phthalimidyl)tetrabenzoporphyrinate
  参考文献：
  名称：

  5,15-diaminotetrabenzoporphyrins: Synthesis and spectral properties

  摘要：

  A zinc complex of 5,15-di(N-phthalimidyl)tetrabenzoporphyrin was obtained by the reaction of Ncarboxymethylphthalimide with 1-oxo-1H-3-(1-oxoisoindolin-3-ylidenemethyl)isoindole and zinc oxide. The complex demetallation affords 5,15-di(N-phthalimidyl)tetrabenzoporphyrin. The reaction of N-phthalimidylsubstituted tetrabenzoporphyrins with hydrazine hydrate leads to the formation of 5,15-diaminotetrabenzoporphyrins. Spectral properties of these compounds were studied.

  DOI：

  10.1134/s1070363212030206
• 作为产物：
  描述：

  邻苯二甲酸亚胺 、 zinc diacetate 反应 0.33h， 以29.9%的产率得到3-(3-oxo-2,3-dihydro-1H-isoindol-1-ylidenemethyl)-1H-isoindol-1-one
  参考文献：
  名称：

  Kudrik; Islyaikin; Frantseva, Russian Journal of General Chemistry, 1997, vol. 67, # 7, p. 1132 - 1135

  摘要：

  DOI：

文献信息

• Synthesis and Induction of Mesomorphic Properties of Tetrabenzoporphine Derivatives
  作者：V. Bykova、N. Usol'tseva、E. Kudrik、N. Galanin、G. Shaposhnikov、L. Yakubov

  DOI：10.1080/15421400802429986

  日期：2008.12.2

  Zinc complexes of meso-alkyl-substituted tetrabenzoporphines and their aza-derivatives have been. synthesized using the interaction of phthalimide or its derivatives with zinc salts of the carboxylic acids. The porphyrin-ligands were obtained on the basis of the above mentioned compounds. The spectral and mesomorphic properties of the synthesized compounds were studied.
• Sandwich complexes of yttrium, neodymium, gadolinium, and dysprosium with meso-trans-di(hexadecyl)-tetrabenzoporphyrin and phthalocyanine fragments. Synthesis and spectral properties
  作者：N. E. Galanin、G. P. Shaposhnikov

  DOI：10.1134/s1070363212040275

  日期：2012.4

  Sandwich-type asymmetric complexes of yttrium, neodymium, gadolinium, and dysprosium were synthesized by the reaction of the corresponding meso-trans-bis(hexadecyl)tetrabenzoporphyrinates with dilithium phthalocyianine. Spectral properties of these compounds were investigated.
• ——
  作者：N. E. Galanin、E. V. Kudrik、G. P. Shaposhnikov

  DOI：10.1023/a:1020715202738

  日期：——

  meso-Monophenyltetrabenzoporphine and its zinc complex were synthesized starting from 3-(3-oxo-2,3-dihydro-1H-isoindol-1-yiidenemethyl)-1H-isoindol-1-one. The effect of unsymmetrical meso-substitution on physical and spectral properties of the products is discussed. The results of quantum-chemical calculations suggest spatial distortion of the porphyrin macroring.
• Galanin; Kudrik; Shaposhnikov, Russian Journal of General Chemistry, <hi>2000</hi>, vol. 70, # 8, p. 1292 - 1295
  作者：Galanin、Kudrik、Shaposhnikov

  DOI：——

  日期：——