A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes
Photoinduced reactions of arylboronic acids with electron deficient alkenes under mild organic photoredox catalysis conditions lead to the formation of Meerwein arylation type adducts via the generation of aryl radicals.
作者:Ruud H. A. Bosma、Arjan P. Kouwenhoven、Johannes C. Mol
DOI:10.1039/c39810001081
日期:——
Unsaturatednitriles of general formula CH2CH[CH2]nCN, where I ⩽n⩽ 4, undergo metathesis in the presence of the catalyst system tungsten hexachloride-tetramethyltin with maximum reactivity for n= 2