Di-n-propyl-n-tridecylamin

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Di-n-propyl-n-tridecylamin
• 英文别名: N,N-dipropyltridecan-1-amine
• 化学式: C₁₉H₄₁N
• 分子量: 283.541
• InChiKey: ZLSHOPRZWCWMDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二正丙胺 、 硬脂基溴 以 乙腈 为溶剂， 生成 Di-n-propyl-n-tridecylamin
  参考文献：
  名称：

  Fused organic salts. 8. Properties of molten straight-chain isomers of tetra-n-pentylammonium salts

  摘要：

  DOI：

  10.1021/ja00492a001

文献信息

• Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydroaminomethylation of olefins
  作者：Kaoxue Li、Yanhua Wang、Yicheng Xu、Wenjiang Li、Mingming Niu、Jingyang Jiang、Zilin Jin

  DOI：10.1016/j.catcom.2013.01.018

  日期：2013.4

  Rh nanoparticles used as catalysts for hydroaminomethylation reaction is reported for the first time. An efficient and recyclable Rh nanoparticle catalyst stabilized by thermoregulated ligand Ph2P(CH2CH2O)nCH3 (n = 16) was studied for the hydroaminomethylation of olefins in the aqueous/1-butanol biphasic system through thermoregulated phase-transfer catalysis, which allows not only for a homogeneous

  首次报道了用作氢氨甲基化反应催化剂的Rh纳米粒子。通过温度调节配体Ph 2 P（CH 2 CH 2 O）n CH 3稳定的高效可循环利用的Rh纳米颗粒催化剂（n = 16）研究了通过温度调节相转移催化在水/ 1-丁醇双相体系中烯烃的氢氨甲基化，该方法不仅可以进行均相催化反应，而且还易于进行双相分离。在优化的条件下，1-辛烯的转化率和产物胺的选择性分别高达99％和97％。反应后，可以通过简单的相分离将Rh纳米颗粒催化剂从产物中分离出来，并直接循环用于下一次运行。
• RAPID CURING THIOL EPOXY RESIN WITH IMPROVED COMPRESSION STRENGTH PERFORMANCE
  申请人：The Boeing Company

  公开号：EP3165561A1

  公开（公告）日：2017-05-10

  Aspects described herein generally describe epoxy resins and methods of epoxy resin formation. In some embodiments, a resin includes the reaction product of one or more polythiols, one or more polyepoxides, one or more fillers and one or more amine catalysts. Polythiols have between two and about ten thiol moieties. Polyepoxides have between two and about ten epoxy moieties. One or more amine catalysts of the formula NR1R2R3, wherein each of R1, R2, and R3 is independently linear or branched C1-20 alkyl or two or more of R1, R2, and R3 combine to form cycloalkyl. The resin has a compressive strength of at least 14 ksi at 2% offset at 70°F and at least 8 ksi at 2% offset at 190°F.

  本文所述各方面一般描述环氧树脂和环氧树脂的形成方法。在某些实施例中，树脂包括一种或多种聚硫醇、一种或多种聚环氧化物、一种或多种填料和一种或多种胺催化剂的反应产物。聚硫醇具有两个到十个硫醇分子。聚环氧化物有两个到十个环氧基。一种或多种式 NR1R2R3 的胺催化剂，其中 R1、R2 和 R3 中的每一个都是独立的直链或支链 C1-20 烷基，或两个或两个以上的 R1、R2 和 R3 结合形成环烷基。该树脂在 70°F 时，偏移 2% 时的抗压强度至少为 14 ksi，在 190°F 时，偏移 2% 时的抗压强度至少为 8 ksi。
• FUEL COMPOSITION
  申请人：BASF SE

  公开号：EP3241882A1

  公开（公告）日：2017-11-08

  The use of an alkoxylated polytetrahydrofurane of formula wherein m, m', n, n', p, p' and k are integers in the range of ≥ 1, R1 denotes an unsubstituted linear or branched alkyl radical, R2 denotes -CH2-CH3, and R3 denotes a hydrogen atom or -CH3, as an additive in a fuel for reducing fuel consumption in the operation of an internal combustion engine with this fuel.

  使用式中的烷氧基化聚四氢呋喃 其中 m、m'、n、n'、p、p'和 k 为≥1 范围内的整数，R1 表示未取代的直链或支链烷基，R2 表示 -CH2-CH3，R3 表示氢原子或 -CH3，作为燃料中的添加剂，用于降低使用该燃料的内燃机运行时的燃料消耗量。
• Use of a complex ester to reduce fuel consumption
  申请人：BASF SE

  公开号：US10030206B2

  公开（公告）日：2018-07-24

  The use of a complex ester obtainable by esterification reaction between aliphatic linear or branched C2- to C12-dicarboxylic acids, aliphatic linear or branched polyhydroxy alcohols with 3 to 6 hydroxyl groups, and, as chain stopping agents, aliphatic linear or branched C1- to C30-monocarboxylic acids or aliphatic linear or branched monobasic Ci- to C30-alcohols, as an additive in a fuel.

  通过脂肪族直链或支链 C2- 至 C12 二羧酸、具有 3 至 6 个羟基的脂肪族直链或支链多羟基醇，以及作为链阻断剂的脂肪族直链或支链 C1 至 C30 单羧酸或脂肪族直链或支链 Ci- 至 C30 单基性醇之间的酯化反应而获得的复合酯，用作燃料添加剂。
• Rapid curing thiol epoxy resin with improved compression strength performance
  申请人：THE BOEING COMPANY

  公开号：US10035873B2

  公开（公告）日：2018-07-31

  Aspects described herein generally describe epoxy resins and methods of epoxy resin formation. In some embodiments, a resin includes the reaction product of one or more polythiols, one or more polyepoxides, one or more fillers and one or more amine catalysts. Polythiols have between two and about ten thiol moieties. Polyepoxides have between two and about ten epoxy moieties. One or more amine catalysts of the formula NR1R2R3, wherein each of R1, R2, and R3 is independently linear or branched C1-20 alkyl or two or more of R1, R2, and R3 combine to form cycloalkyl. The resin has a compressive strength of at least 14 ksi at 2% offset at 70° F. and at least 8 ksi at 2% offset at 190° F.

  本文所述各方面一般描述环氧树脂和环氧树脂的形成方法。在某些实施例中，树脂包括一种或多种聚硫醇、一种或多种聚环氧化物、一种或多种填料和一种或多种胺催化剂的反应产物。聚硫醇具有两个到十个硫醇分子。聚环氧化物有两个到十个环氧基。一种或多种式 NR1R2R3 的胺催化剂，其中 R1、R2 和 R3 中的每一个都是独立的直链或支链 C1-20 烷基，或两个或两个以上的 R1、R2 和 R3 结合形成环烷基。该树脂在华氏 70 度、偏移 2% 时的抗压强度至少为 14 ksi，在华氏 190 度、偏移 2% 时的抗压强度至少为 8 ksi。