N-benzyl-N-ferrocenylmethyl amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzyl-N-ferrocenylmethyl amine
• 英文别名: (η5-C5H5)Fe(η5-C5H4CH2NHCH2C6H5)；[(η5-C5H5)Fe(η5-C5H4CH2NHCH2Ph)]
• 化学式: C₁₈H₁₉FeN
• 分子量: 305.203
• InChiKey: CZQXQAGAVNAYML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 N-benzyl-N-ferrocenylmethyl amine 在 sodium cyanoborohydride 、 acetic acid 作用下， 以 水 、 乙腈 为溶剂， 以75%的产率得到(N,N-benzylmethylaminomethyl)ferrocene
  参考文献：
  名称：

  Synthesis, characterization of [{(N-methyl-N-benzyl)amino}methyl]ferrocenes and their cyclopalladated complexes: Crystal structure of σ-Pd[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4NO2-4)]Cl(PPh3)

  摘要：

  Condensation of aminomethylferrocene (1) and substituted benzaldehydes resulted in aldimines 2a-c which followed by reduction with sodium borohydride to give 3a-c. N-methylation of 3a-c with HCHO/NaCNBH3/HOAc led to 4a-c. Treatment of 4a-c with sodium palladium tetrachloride in the presence of sodium acetate afforded cleanly cyclopalladated 5a-c in which configurations consisted of the RNRC, SNSC. The preferable activation Of C-Ferrocenyl-H bond over C-Phenyl-H bond was also observed. All compounds 2-5 were characterized by elemental analysis, IR and H-1 NMR. In addition, the molecular structure of 5c was confirmed by single crystal X-ray diffraction. The possible mechanism for the formation of 5 was also discussed. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.05.019
• 作为产物：
  描述：

  N-benzyl-ferrocenylidenamine 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 生成 N-benzyl-N-ferrocenylmethyl amine
  参考文献：
  名称：

  Synthesis, characterization and light harvesting properties of Sb(III) and Bi(III) ferrocenyl dithiocarbamate complexes

  摘要：

  New Sb(III) and Bi(III) ferrocenyl dithiocarbamate complexes viz. [Sb(FcCH(2)Bzdtc)(3)] (Sb) and [Bi(FcCH(2)Bzdtc)(3)] (Bi) (Fc = C5H5FeC5H4-; Bz = C6H5CH2-) have been synthesized and characterized by elemental analyses, IR, H-1 and C-13 NMR spectroscopies. The optical, electrochemical and photovoltaic properties of the synthesized complexes were investigated. The light harvesting properties of both of the compounds have been studied using these compounds as photosensitizers in TiO2-based DSSCs. The photovoltaic devices fabricated by Sb and Bi showed a maximum current conversion efficiency of 1.51% and 0.97%, respectively under 1.5 AM illumination (100 mW cm(-2)) and having incident photon to current efficiency (IPCE) of 38% and 31%, respectively. The reason for the higher efficiency of Sb is due its higher dye loading. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2015.06.012

文献信息

• Synthesis of 2-<i>N</i>/<i>S</i>/<i>C</i>-Substituted Benzothiazoles via Intramolecular Cyclative Cleavage of Benzotriazole Ring
  作者：Dhananjay Kumar、Bhuwan B. Mishra、Vinod K. Tiwari

  DOI：10.1021/jo4024107

  日期：2014.1.3

  The synthesis of numerous 2-N/S/C-substituted benzothiazoles was achieved from substituted thiocarbonylbenzotriazoles via free-radical intramolecular cyclative cleavage of the benzotriazole ring in the presence of (TMS)3SiH and AIBN under mild conditions. The developed methodology demonstrates significant compatibility under microwave conditions and is important as it avoids the use of toxic metals

  在温和条件下，在（TMS）3SiH和AIBN的存在下，通过苯并三唑环的自由基分子内环化裂解，由取代的硫代羰基苯并三唑实现了许多2-N / S / C-取代的苯并噻唑的合成。所开发的方法论证明了在微波条件下的显着兼容性，并且由于避免了使用有毒金属进行自由基环化，因此非常重要。
• Syntheses, crystal, photoluminescence and electrochemical investigation of some new phenylmercury(ii) dithiocarbamate complexes involving ferrocene
  作者：Nanhai Singh、Abhinav Kumar、Rajendra Prasad、Kieran C. Molloy、Mary F. Mahon

  DOI：10.1039/b917871f

  日期：——

  phenylmercury(II) dithiocarbamate complexes incorporating the ferrocenyl moiety (C5H5)Fe(C5H4) (Fc), namely PhHgS2CN(CH2Fc)CH2C6H5, (1), PhHgS2CN(CH2Fc)CH(CH3)2, (2), PhHgS2CN(CH2Fc)(CH2)3CH3, (3) and [PhHgS2CN(CH2Fc)]2(CH2C6H4CH2), (4) have been prepared and characterized by elemental analysis, UV-Vis, IR, 1H and 13C NMR spectroscopies. The crystal structures of 1, 2 and 4 showed a linear core at the

  一系列新的异双金属 苯汞（II）二硫代氨基甲酸酯含有二茂铁基部分（C 5 H 5）Fe（C 5 H 4）的配合物（Fc），即PhHgS 2 CN（CH 2 Fc）CH 2 C 6 H 5，（1），PhHgS 2 CN（CH 2 Fc）CH（CH 3）2，（2），PhHgS 2 CN（CH 2 Fc）（ CH 2）3 CH 3，（3）和[PhHgS 2 CN（CH 2 Fc）] 2（CH 2 C 6 H 4 CH 2），（4已通过元素分析，UV-Vis，IR，1 H和13 C NMR光谱法制备并表征。的晶体结构1，2和4显示了在汞（线性芯II分子的）中心，由所述结合的硫 的原子 二硫代氨基甲酸酯 配体和 碳芳环的原子。在1和2的情况下，弱分子间Hg⋯S相互作用形成“头对尾”二聚体。4形成相似的二聚体结构，形成两对Hg⋯S相互作用以生成四金属单元。通过计算中性原子及其在理论密度函数水平（DFT
• Organometallic derivatives. Part III. The displacement of hydroxy- and similar groups from α-substituted ferrocenylmethanes by aniline
  作者：G. Marr、B. W. Rockett、A. Rushworth

  DOI：10.1039/j39710004000

  日期：——

  Hydroxy-, dimethylamino-, phenoxy-, and piperidino-groups have been displaced by aniline from the corresponding α-substituted ferrocenylmethanes. The anilino-group has been displaced from anilinomethylferrocene by p-methoxyaniline. The nucleophilic character of the attacking group has been shown to be important in this displacement.

  羟基，二甲基氨基，苯氧基和哌啶子基已被苯胺从相应的α-取代的二茂铁基甲烷中取代。苯胺基已被对甲氧基苯胺从苯胺甲基二茂铁取代。已经证明攻击基团的亲核特性在这种置换中很重要。
• Ditopic redox-active polyferrocenyl zinc(ii) dithiocarbamate macrocyclic receptors: synthesis, coordination and electrochemical recognition properties
  作者：Wallace W. H. Wong、David Curiel、Siu-Wai Lai、Michael G. B. Drew、Paul D. Beer

  DOI：10.1039/b416851h

  日期：——

  polyferrocenyl zinc(II) dithiocarbamate macrocyclic receptors containing ferrocene groups on the macrocycle's periphery and/or as part of the cyclic cavity is reported. The assemblies have been characterised by a range of spectroscopic techniques, electrochemical studies and in two cases by X-ray structure determination. The ability of these host systems to bind and sense electrochemically anionic guest species

  报道了一系列在大环的外围和/或作为环状腔的一部分包含二茂铁基团的二位聚二茂铁基锌（II）二硫代氨基甲酸酯大环受体的合成。组件已通过一系列光谱技术，电化学研究以及两种情况下的X射线结构确定来进行了表征。通过1H NMR和循环伏安滴定研究，研究了这些宿主系统结合和检测电化学阴离子客体物质，异烟酸酯和苯甲酸酯以及中性4-甲基吡啶客体的能力。在异烟酸根阴离子和双核锌（II）受体之间发现最强的缔合，后者的大环腔具有互补大小，以协同方式使该双齿客体复合。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.2.2, page 32 - 36
  作者：

  DOI：——

  日期：——