2-Deca-4,7-dienoxyoxane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: 2-Deca-4,7-dienoxyoxane
• 化学式: C₆H₅N₂*O₃PolS
• 分子量: 238.37
• InChiKey: VSNQOZMEYPCLNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Deca-4,7-dienoxyoxane 在 sodium azide 作用下， 以 水 为溶剂， 反应 0.08h， 生成 叠氮苯
  参考文献：
  名称：

  One-pot, efficient, and regioselective syntheses of 1,4-disubstituted 1,2,3-triazoles using aryldiazonium silica sulfates in water

  摘要：

  A one-pot, efficient, and straightforward procedure for the copper-catalyzed synthesis of 1,4-disubstituted 1,2,3-triazoles is studied by in situ generation of aryl azides via the reaction of aryldiazonium silica sulfates and sodium azide, followed by coupling with a terminal alkyne. These reactions are carried out in water at room temperature without using any additional ligands. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.07.081
• 作为产物：
  描述：

  pent-2-yn-1-yl 4-methylbenzenesulfonate 在 喹啉 、 乙基溴化镁 作用下， 以 四氢呋喃 为溶剂， 生成 2-Deca-4,7-dienoxyoxane
  参考文献：
  名称：

  Identification of the sex pheromone of the lesser date moth, Batrachedra amydraula, using sequential SPME auto-sampling

  摘要：

  The identification of the sex pheromone of the lesser date moth, Batrachedra amydraula (Meyrick) was based on GC-MS analysis of volatiles released by virgin females using sequential SPME auto-sampling of headspace and by synthesis of the key component, (4Z,7Z)-4,7-decadien-1-yl acetate. Substantial capture of males in a date palm plantation using a bait consisting of the key component and 5Z-decen-1-yl acetate in a ratio of 1:2 indicated that these are the essential components of the sex pheromone. Addition of 4Z-decen-1-yl acetate and decan-1-yl acetate, which were also identified, did not affect trap-capture. The lesser date moth is the first member of the Batrachedridae whose sex pheromone has been identified. (4Z,7Z)-4,7-Decadien-1-yl acetate is a novel compound among moth sex pheromones. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.06.091

文献信息

• Aryldiazonium silica sulfates as efficient reagents for Heck-type arylation reactions under mild conditions
  作者：Amin Zarei、Leila Khazdooz、Azadeh Pirisedigh、Abdol R. Hajipour、Hojjat Seyedjamali、Hamidreza Aghaei

  DOI：10.1016/j.tetlet.2011.06.095

  日期：2011.8

  An efficient and straightforward procedure for Heck-type arylation reactions was studied using aryldiazonium silica sulfates and olefins in the presence of a catalytic amount of Pd(OAc)(2). These reactions were carried out in water at room temperature without using a base or additional ligands. The use of a non-toxic solvent, a simple and clean work-up, short reaction times, and good yields are advantages of this method. (C) 2011 Elsevier Ltd. All rights reserved.