zinc bis(2-methylphenoxyacetate)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: zinc bis(2-methylphenoxyacetate)
• 英文别名: zinc bis(o-methylphenoxyacetate)；zinc di(2-methylphenoxyacetate)；zinc(II) 2-methylphenoxyacetate；Zn(MPAA)2
• 化学式: 2C₉H₉O₃*Zn
• 分子量: 395.727
• InChiKey: MFOCCUAVEDVBIZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.12
• 重原子数：
  13.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  49.36
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  zinc bis(2-methylphenoxyacetate) 、 甲硝唑 以 甲醇 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Novel complexes of 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole with metal acetates and arylchalcogenylacetates

  摘要：

  The reaction of 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole (Metronidazole) with salts of biologically active arylchalcogenylacetic acids affords novel perspective physiologically active metal complexes.

  DOI：

  10.1016/j.mencom.2014.09.015
• 作为产物：
  描述：

  2-甲基苯氧基乙酸 、 zinc(II) oxide 以 苯 为溶剂， 以97%的产率得到zinc bis(2-methylphenoxyacetate)
  参考文献：
  名称：

  Synthesis of new biologically active O-hydrometalatranes

  摘要：

  DOI：

  10.1134/s1070363209010320

文献信息

• New complexes of triethanolamine N-oxide with metal salts
  作者：S. N. Adamovich、G. A. Kuznetsova、I. A. Ushakov、A. N. Mirskova

  DOI：10.1007/s11172-016-1646-y

  日期：2016.11

  New potentially pharmacologically active complexes of general formula n[(HOCH2CH2)3N—O]·MX2 (M = Zn, Co, Ni, Cu; X = Cl, MeCO2, ArOCH2CO2; n = 1, 2) were synthesized by the reaction of triethanolamine N-oxide with essential metal salts.

  通过以下反应合成了具有通式 n[(HOCH2CH2)3N-O]·MX2 (M = Zn, Co, Ni, Cu; X = Cl, MeCO2, ArOCH2CO2; n = 1, 2) 的新型潜在药理活性配合物三乙醇胺 N-氧化物与必需的金属盐。
• Complex compounds of biogenic metals, aroxyacetic acids, and triethanolamine
  作者：S. N. Adamovich、T. V. Kashik、N. N. Chipanina、R. G. Mirskov、A. N. Mirskova、M. G. Voronkov

  DOI：10.1134/s1070427209050218

  日期：2009.5

  A series of previously unknown promising biologically active compounds, complexes of biogenic metal salts, aroxyacetic acid salts, and triethanolamine, were prepared. The structure and acid-base properties of these compounds were studied by NMR and IR spectroscopy and by potentiometric titration.
• Reaction of tris(2-hydroxyethyl)amine hydrochloride with zinc diacetate and bis(2-methylphenoxy)acetate
  作者：S. N. Adamovich、R. G. Mirskov、A. N. Mirskova、M. G. Voronkov

  DOI：10.1134/s1070363210100154

  日期：2010.10

  Reaction of tris(2-hydroxyethyl)amine hydrochloride Cl- N+H(CH2CH2OH)(3) with zinc diacetate and bis(2-methylphenoxy)acetate in the molar ratio 2: 1 results in complexes 2[Cl- N+H(CH2CH2OH)(3)](center dot) Zn (OCOR)(2) (I, II) R= Me (I), 2-MeC6H4OCH2 (II), which contain two protatrane cations linked with zinc diacylate by two coordination bonds HO -> Zn. Complexes I and II are also formed by the reaction of the corresponding tris(2-hydroxyethyl)amine hydrochloride acylate RCOO-N+H(CH2CH2OH)(3) with ZnCl2. The structure of complexes I, II is proved by elemental analysis, IR and H-1, C-13, N-15 NMR spectroscopy.
• Biologically active aprotic (2-hydroxyethyl)ammonium ionic liquids. Choline derivatives
  作者：S. N. Adamovich、R. G. Mirskov、A. N. Mirskova、M. G. Voronkov

  DOI：10.1007/s11172-012-0173-8

  日期：2012.6
• Synthesis of triethanolamine complexes with zinc organylheteroacetates, promising biologically active compounds
  作者：S. N. Adamovich、G. A. Kuznetsova、A. N. Mirskova、R. G. Mirskov、M. G. Voronkov

  DOI：10.1134/s1070363209110103

  日期：2009.11

  A series of two- and three-component complexes was synthesized of triethanolamine with zinc salts of organylheteroacetic acids, promising biologically active compounds for the search for immunomodulating, antistressor, antitumor, etc. drugs.