dioctylethanolamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: dioctylethanolamine
• 英文别名: 2-Amino-2-octyldecan-1-ol
• 化学式: C₁₈H₃₉NO
• 分子量: 285.514
• InChiKey: XIYVNDHMWAMTII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  46.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  月桂酸 、 dioctylethanolamine 、 氯甲烷 在 盐酸 作用下， 以 异丙醇 为溶剂， 生成 N,N-Dioctyl-N-methyl-[1-oxododecyl(tetradecyl)oxyethyl]-ammonium chloride
  参考文献：
  名称：

  Low-melting ester quats

  摘要：

  以下是公式（1）中描述的Ester quats的中文翻译：其中RCO是具有6至22个碳原子的脂肪酰基基团，R.sup.1是甲基基团，R.sup.2是C.sub.1-C.sub.6-烷基基团，R.sup.3是C.sub.3-C.sub.6-烷基基团，X.sup.-是卤素阴离子。它们通过在溶剂存在或不存在的情况下，用甲基卤化物对应的羧酸乙醇胺酯化合物进行季铵化而制备。该发明的酯季铵化合物具有较低的熔点。此外，即使在高浓度下它们也具有高水溶性，并且由于其制备方法，其纯度高且不含有毒成分。这些酯季铵化合物可以用于许多方式，并且适用于制备具有高表面活性效果的固体或水性配方。

  公开号：

  US06072063A1

文献信息

• [EN] NITRATED HYDROCARBONS, DERIVATIVES, AND PROCESSES FOR THEIR MANUFACTURE<br/>[FR] HYDROCARBURES NITRÉS, DÉRIVÉS ET LEURS PROCÉDÉS DE PRODUCTION
  申请人：ANGUS CHEMICAL

  公开号：WO2009129097A1

  公开（公告）日：2009-10-22

  Provided is a process for the formation of nitrated compounds by the nitration of hydrocarbon compounds with dilute nitric acid. Also provided are processes for preparing industrially useful downstream derivatives of the nitrated compounds, as well as novel nitrated compounds and derivatives, and methods of using the derivatives in various applications.

  提供了一种通过稀硝酸对碳氢化合物进行硝化形成硝化化合物的过程。还提供了制备工业上有用的硝化化合物下游衍生物的过程，以及新颖的硝化化合物和衍生物，以及在各种应用中使用衍生物的方法。
• NITRATED HYDROCARBONS, DERIVATIVES, AND PROCESSES FOR THEIR MANUFACTURE
  申请人：ANGUS Chemical Company

  公开号：US20160039843A1

  公开（公告）日：2016-02-11

  Provided is a process for the formation of nitrated compounds by the nitration of hydrocarbon compounds with dilute nitric acid. Also provided are processes for preparing industrially useful downstream derivatives of the nitrated compounds, as well as novel nitrated compounds and derivatives, and methods of using the derivatives in various applications.

  提供了一种通过使用稀硝酸对碳氢化合物进行硝化形成硝基化合物的过程。还提供了制备硝基化合物的工业上有用的下游衍生物的过程，以及新颖的硝基化合物和衍生物，以及在各种应用中使用衍生物的方法。
• Carbazole photoinitiators for the photopolymerization of unsaturated compounds
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0171600A1

  公开（公告）日：1986-02-19

  Carbazole photoinitiators for the photopolymerization of unsaturated compounds are provided, having the formulae: wherein: R1 and R2 are each alkyl having from one to about eighteen carbon atoms; or are taken together to form alkylene having from about two to about twelve carbon atoms; R3 is selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; and acyl having from about two to about twelve carbon atoms; in which R5 is selected from the group consisting of hydrogen; alkyl and alkenyl having from one to about eighteen carbon atoms; and R6 and R7 are selected from the group consisting of alkyl; hydroxyalkyl having from one to about eighteen carbon atoms; and R6 and R7 taken together to form alkylene having from about two to about twelve carbon atoms; and oxadialkylene and iminodialkylene having from four to about twenty-four carbon atoms: Y2 is selected from the group consisting of hydrogen. halogen, and nitro; R4 is a direct linkage (-) or alkylene having from about two to about twelve carbon atoms; in which: R8 is alkylene having from about two to about twelve carbon atoms; R9 and R10 are alkyl having from one to about eighteen carbon atoms; or are taken together to form alkylene having from about two to about twelve carbon atoms.

  本发明提供了用于不饱和化合物光聚合的咔唑光引发剂，其化学式为 其中 R1 和 R2 分别是具有 1 至约 18 个碳原子的烷基；或共同形成具有约 2 至约 12 个碳原子的亚烷基； R3 选自氢、具有 1 至 18 个碳原子的烷基和具有 2 至 12 个碳原子的酰基组成的组； 其中 R5 选自由氢、具有 1 至约 18 个碳原子的烷基和烯基组成的组；R6 和 R7 选自由烷基、具有 1 至约 18 个碳原子的羟基烷基、R6 和 R7 共同形成的具有约 2 至约 12 个碳原子的亚烷基、以及具有 4 至约 24 个碳原子的氧二亚烷基和亚二亚烷基组成的组： Y2 选自氢、卤素和硝基组成的组； R4 是直接连接（-）或具有约 2 至约 12 个碳原子的亚烷基； 其中 R8 是具有约 2 至约 12 个碳原子的亚烷基； R9 和 R10 是具有 1 至约 18 个碳原子的烷基；或共同形成具有约 2 至约 12 个碳原子的亚烷基。
• SUBSTITUTED ACRIDINE DERIVATIVES AND THEIR USE
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0305545A1

  公开（公告）日：1989-03-08

  Substituted acridine derivatives represented by general formula (I) (wherein R,, R2, R3, R4, R5, R6, R7, and Ra each independently represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a halogen atom or an alkoxy group, and Z1 represents a six-membered heterocyclic aromatic group containing one or two nitrogen atoms in the ring and optionally having a 1 ~ 8C alkyl substituent or a quinolyl group) and a photopolymerizable composition containing 0.01 to 10 parts by weight of said derivative, 100 parts by weight of a photopolymerizable compound having a boiling point of 100°C or above under ordinary pressure and having at least one ethylenically unsaturated group, and 0 to 400 parts by weight of a thermoplastic organic polymer are disclosed.

  通式(I)代表的取代吖啶衍生物 (其中 R、、R2、R3、R4、R5、R6、R7 和 Ra 各自独立地代表氢原子、烷基、取代的烷基、芳基、取代的芳基、卤素原子或烷氧基，Z1 代表在环中含有一个或两个氮原子的六元杂环芳基，并可选择地具有 1 ~ 8C 烷基取代基或醌基)和一种可光聚合的组合物，该组合物含有 0.本发明公开了一种可光聚合的组合物，该组合物含有0.01至10份重量的所述衍生物、100份重量的在常压下沸点为100°C或以上并具有至少一个乙烯不饱和基团的可光聚合化合物，以及0至400份重量的热塑性有机聚合物。
• WATER-SOLUBLE METALWORKING OIL AGENT, METALWORKING FLUID, AND METALWORKING METHOD
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2781585A1

  公开（公告）日：2014-09-24

  The invention provides a water-soluble metal-working oil agent, including a component A, a component B, a component C, and a component D, wherein the component A is an ester compound which has a characteristic temperature, as measured in accordance with JIS K2242, of 570°C or higher and which is contained in the water-soluble metal-working oil agent in an amount of 10 mass% or more with respect to the entire amount of the agent; the component B is at least one condensed fatty acid which is selected from a condensed fatty acid (1), produced through dehydration condensation of a hydroxycarboxylic acid, and a condensed fatty acid (2), produced through dehydration condensation of an alcoholic hydroxyl group of the condensed fatty acid (1) with a monovalent carboxylic acid, which has a characteristic temperature, as measured in accordance with JIS K2242, of 650°C or higher, and which is contained in the water-soluble metal-working oil agent in an amount of 7.5 mass% or more with respect to the entire amount of the agent; the component C is a carboxylic acid which is contained in the water-soluble metal-working oil agent in an amount of 2 mass% or more with respect to the entire amount of the agent; and the component D is a basic compound contained in such a neutralization equivalent that at least the component B and component C are neutralized to cancel out the sum of the acid values thereof. The agent can provide excellent workability with a hard-to-work material and can prolong tool life.

  本发明提供了一种水溶性金属加工油剂，包括 A 组分、B 组分、C 组分和 D 组分，其中 A 组分是一种酯类化合物，根据 JIS K2242 测量，其特征温度为 570°C 或更高，且在水溶性金属加工油剂中的含量占整个油剂的 10 质量％或更多；组分 B 是至少一种缩合脂肪酸，选自羟基羧酸脱水缩合生成的缩合脂肪酸 (1) 和缩合脂肪酸 (2)、通过缩合脂肪酸（1）的醇羟基与一价羧酸脱水缩合生成的缩合脂肪酸（2），其特征温度（根据 JIS K2242 测量）为 650°C 或更高，其在水溶性金属加工油剂中的含量为 7.组分 C 是一种羧酸，其在水溶性金属加工油剂中的含量为该油剂总量的 2 质量％或更高；组分 D 是一种碱性化合物，其中和当量至少为组分 B 和组分 C 的中和量，以抵消其酸值之和。该剂可为难加工材料提供出色的加工性，并可延长工具寿命。