6-diphenylamino-2-naphthol

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 6-diphenylamino-2-naphthol
• 英文别名: 6-(diphenylamino)naphthalen-2-ol；6-(N-phenylanilino)naphthalen-2-ol
• 化学式: C₂₂H₁₇NO
• 分子量: 311.383
• InChiKey: MWZIHHMMMJYEDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-diphenylamino-2-naphthol 在 四(三苯基膦)钯 、 4-甲基苯磺酸吡啶 、 potassium carbonate 、 原甲酸三甲酯 作用下， 以 四氢呋喃 、 氯仿 、 水 为溶剂， 反应 9.0h， 生成 4'-(8-(diphenylamino)-3-phenyl-3H-benzo[f]chromen-3-yl)-[1,1'-biphenyl]-4-carbaldehyde
  参考文献：
  名称：

  유기 광변색성 염료 및 염료감응형 태양전지를 위한 이들의 용도

  摘要：

  This is the Chinese translation of the text you provided: 本发明涉及有机染料，其中包括表示电子给体片段的片段-eD和表示电子受体片段的片段-L-A，其中片段-L-A表示共轭或空间片段，特别是表示π-共轭空间片段的-L-和能够形成与半导体和共轭的-A。本发明涉及用作感光剂的光电器件以及涉及所述光电器件。

  公开号：

  KR20200010260A
• 作为产物：
  描述：

  2-溴-6-甲氧基萘 在 乙基溴化镁 、 三溴化硼 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 38.0h， 生成 6-diphenylamino-2-naphthol
  参考文献：
  名称：

  Bismuth(III)-Catalyzed Dehydrative Etherification and Thioetherification of Phenolic Hydroxy Groups

  摘要：

  Use of a bismuth catalyst allowed efficient dehydrative substitution of phenolic hydroxy groups with alcohols and thiols to form C-O and C-S bonds. The reaction required equimolar amounts of two readily available substrates that generated H2O as the only byproduct. The relatively mild reaction conditions were compatible with the functional groups selected, and provided excellent chemoselectivity.

  DOI：

  10.1021/ol501744g

文献信息

• Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with naphthols: a reaction sequence to larger π-conjugated naphthopyrans with aggregation-induced emission characters
  作者：Jinlong Zhang、Lu Zhu、Kang Shen、Huameng Yang、Xiao-Chun Hang、Gaoxi Jiang

  DOI：10.1039/c8sc03837f

  日期：——

  A practical and readily scalable reaction sequence was developed for the straightforward synthesis of a new family of larger π-conjugated naphthopyrans by a Brønsted acid-catalyzed aromatic annulation of alkoxyallenes with inert naphthols. The cascade pathway involves allylation/cyclization/debenzyloxylation/isomerization/dehydration. The new class of solid state diphenylmethylene substituted naphthopyrans

  开发了一种实用且易于扩展的反应序列，用于通过布朗斯台德酸与惰性萘并烷氧基烯丙酸酯的芳族环化反应，直接合成较大的π-共轭萘并吡喃的新家族。级联途径涉及烯丙基化/环化/脱苄氧基化/异构化/脱水。新型的固态二苯基亚甲基取代的萘并吡喃具有荧光发射作用，并被证明具有聚集诱导发射（AIE）行为。
• ELECTROLUMINESCENT DEVICES HAVING PENDANT NAPHTHYLANTHRACENE-BASED POLYMERS
  申请人：Zheng Shiying

  公开号：US20070187673A1

  公开（公告）日：2007-08-16

  A naphthylanthracene-based polymer comprising a repeating unit of the formula wherein: Ar is an aryl or substituted aryl of from 6 to 60 carbon atoms; or a heteroaryl or substituted heteroaryl of from 4 to 60 carbon atoms; R 1 , R 2 , and R 3 are the same or different, and are each individually hydrogen, or alkyl, or alkenyl, or alkynyl, or alkoxy, or amino, or thioalkyl, or carboxyl, or carbonyl, wherein the alkyl, alkenyl, alkynyl, alkoxy, amino, thioalkyl, carboxy, or carbonyl can have from 1 to 40 carbon atoms; or aryl of from 6 to 60 carbon atoms; or heteroaryl of from 4 to 60 carbon atoms; or F, or Cl , or Br; or a cyano group; or a nitro group, or a sulfonate group; and L is a direct bond between naphthylanthracene and polymer backbone or a carbon linking group having 1 to 40 carbon atoms or a non-carbon linking group.

  一种基于萘并蒽的聚合物，包括如下重复单元，其中：Ar是含6至60个碳原子的芳基或取代芳基；或含4至60个碳原子的杂芳基或取代杂芳基；R1、R2和R3相同或不同，分别为氢、烷基、烯基、炔基、烷氧基、氨基、硫代烷基、羧基、酰基，其中烷基、烯基、炔基、烷氧基、氨基、硫代烷基、羧基或酰基可含有1至40个碳原子；或含6至60个碳原子的芳基；或含4至60个碳原子的杂芳基；或F、Cl、Br；或氰基；或硝基；或磺酸盐基；L是萘并蒽与聚合物骨架之间的直接键合或含有1至40个碳原子或非碳原子键合基。
• ORGANIC PHOTOCHROMIC DYE AND USES THEREOF FOR DYE SENSITIZED SOLAR CELLS
  申请人：Commissariat à l'Energie Atomique et aux Energies Alternatives

  公开号：EP3406691A1

  公开（公告）日：2018-11-28

  The present invention concerns an organic dye comprising a photochromic entity, a segment -eD representing an electron donor segment and a segment -L-A with -L- representing a covalent bond or a spacer segment and particularly a pi-conjugated spacer segment, and -A representing an electron attractor segment able to form a covalent bond with a semi-conductor. The present invention concerns the use thereof as photosensitizer in a photovoltaic device and said photovoltaic device.

  本发明涉及一种有机染料，包括一个光致变色实体、一个代表电子供体段的段-eD和一个段-L-A，其中-L-代表共价键或间隔段，特别是π-共轭间隔段，-A代表能够与半导体形成共价键的引电子段。本发明涉及将其用作光伏设备中的光敏剂以及所述光伏设备。
• Organic photochromic dye and uses thereof for dye sensitized solar cells
  申请人：COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES

  公开号：US11248123B2

  公开（公告）日：2022-02-15

  The present invention concerns an organic dye comprising a photochromic entity, a segment -eD representing an electron donor segment and a segment -L-A with -L- representing a covalent bond or a spacer segment and particularly a pi-conjugated spacer segment, and -A representing an electron attractor segment able to form a covalent bond with a semi-conductor. The present invention concerns the use thereof as photosensitizer in a photovoltaic device and said photovoltaic device.

  本发明涉及一种有机染料，包括一个光致变色实体、一个代表电子供体段的段-eD和一个段-L-A，其中-L-代表共价键或间隔段，特别是π-共轭间隔段，-A代表能够与半导体形成共价键的引电子段。本发明涉及将其用作光伏设备中的光敏剂以及所述光伏设备。
• ORGANIC PHOTOCHROMIC DYE AND USES THEREOF FOR DYE SENSITIZED SOLAR CELLS
  申请人：Commissariat à l'Énergie Atomique et aux Énergies Alternatives

  公开号：EP3609976A1

  公开（公告）日：2020-02-19