1-fluoroethyl phenyl carbonate | 1644075-06-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-fluoroethyl phenyl carbonate
• CAS: 1644075-06-8
• 化学式: C₉H₉FO₃
• 分子量: 184.167
• InChiKey: YZMJSEAMPXECSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-fluoroethyl fluoroformate 、 苯酚 在 perfluoroalkoxylalkane 、 柠檬酸 作用下， 以 吡啶 为溶剂， 反应 2.0h， 以The product was obtained as a colourless liquid (yield: 81%, GC purity>94%)的产率得到1-fluoroethyl phenyl carbonate
  参考文献：
  名称：

  FLUORINATED CARBONATES COMPRISING DOUBLE BOND-CONTAINING GROUPS, METHODS FOR THEIR MANUFACTURE AND USES THEREOF

  摘要：

  本文描述了制备含有双键基团的氟化碳酸盐，并将其用作溶剂添加剂或溶剂，用于锂离子电池、锂空气电池、锂硫电池和超级电容器。首选化合物含有至少一个烯基或至少一个（杂）芳基团。

  公开号：

  US20160145190A1

文献信息

• Fluorinated carbonates comprising double bond-containing groups, methods for their manufacture and uses thereof
  申请人：Solvay SA

  公开号：EP2824096A1

  公开（公告）日：2015-01-14

  Fluorinated carbonates comprising double-bond containing groups were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one alkenyl or at least one (hetero)aryl group.

  本文介绍了含有双键基团的氟化碳酸酯的制备方法，以及它们作为锂离子电池、锂空气电池、锂硫电池和超级电容器中的溶剂添加剂或溶剂的用途。首选化合物至少含有一个烯丙基或至少一个（杂）芳基团。
• [EN] FLUORINATED CARBONATES COMPRISING DOUBLE BOND-CONTAINING GROUPS, METHODS FOR THEIR MANUFACTURE AND USES THEREOF<br/>[FR] CARBONATES FLUORÉS COMPRENANT DES GROUPES CONTENANT UNE DOUBLE LIAISON, PROCÉDÉS DE FABRICATION ET D'UTILISATION ASSOCIÉS
  申请人：SOLVAY

  公开号：WO2015004195A1

  公开（公告）日：2015-01-15

  Fluorinated carbonates comprising double-bond containing groups were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one alkenyl or at least one (hetero)aryl group.

  本文描述了制备含有双键基团的氟化碳酸盐，并将其作为溶剂添加剂或溶剂用于锂离子电池、锂空气电池、锂硫电池和超级电容器中。首选化合物至少包含一个烯基或至少一个（杂）芳基团。
• FLUORINATED CARBONATES COMPRISING DOUBLE BOND-CONTAINING GROUPS, METHODS FOR THEIR MANUFACTURE AND USES THEREOF
  申请人：SOLVAY SA

  公开号：US20160145190A1

  公开（公告）日：2016-05-26

  Fluorinated carbonates comprising double-bond containing groups were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one alkenyl or at least one (hetero)aryl group.

  本文描述了制备含有双键基团的氟化碳酸盐，并将其用作溶剂添加剂或溶剂，用于锂离子电池、锂空气电池、锂硫电池和超级电容器。首选化合物含有至少一个烯基或至少一个（杂）芳基团。
• METHOD FOR PRODUCING FLUOROFORMATE COMPOUNDS
  申请人：Solvay SA

  公开号：EP3309143A1

  公开（公告）日：2018-04-18

  The invention relates to the preparation of fluorosubstituted fluoroformate from halosubstituted haloformate by reaction with at least one fluorinating agent in the presence of a catalyst. The further preparation of fluorosubstituted (fluoro)alkyl carbonates, fluorosubstituted (fluoro)alkyl polycarbonates, fluorosubstituted (fluoro)alkyl carbamates and fluorosubstituted (fluoro)alkyl polycarbamates is disclosed.

  本发明涉及在催化剂存在下，通过与至少一种氟化剂反应，从卤代卤甲酸酯制备氟代氟甲酸酯。本发明公开了进一步制备氟代（氟）烷基碳酸盐、氟代（氟）烷基聚碳酸酯、氟代（氟）烷基氨基甲酸酯和氟代（氟）烷基聚氨基甲酸酯的方法。
• [EN] METHOD FOR PRODUCING FLUOROFORMATE COMPOUNDS<br/>[FR] PROCÉDÉ DE PRODUCTION DE COMPOSÉS FLUOROFORMIATE
  申请人：SOLVAY

  公开号：WO2018073124A1

  公开（公告）日：2018-04-26

  The invention relates to the preparation of fluorosubstituted fluoroformate from halosubstituted haloformate by reaction with at least one fluorinating agent in the presence of a catalyst. The further preparation of fluorosubstituted (fluoro)alkyl carbonates, fluorosubstituted (fluoro)alkyl polycarbonates, fluorosubstituted (fluoro)alkyl carbamates and fluorosubstituted (fluoro)alkyl polycarbamates is disclosed.

  本发明涉及通过在催化剂存在下与至少一种氟化剂反应，从卤代卤酸酯制备氟代卤酸酯的方法。同时还公开了制备氟代（氟）烷基碳酸酯、氟代（氟）烷基聚碳酸酯、氟代（氟）烷基氨基甲酸酯和氟代（氟）烷基聚氨基甲酸酯的方法。