二丁基二氮烯 | 2159-75-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 二丁基二氮烯
• 英文名称: dibutyldiazene
• 英文别名: Diazene, dibutyl
• CAS: 2159-75-3
• 化学式: C₈H₁₈N₂
• 分子量: 142.244
• InChiKey: SZNDPAPNQABPGR-UHFFFAOYSA-N

物化性质

• 沸点：
  249.85°C (rough estimate)
• 密度：
  0.8694 (rough estimate)
• 保留指数：
  962

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2927000090

反应信息

• 作为反应物：
  描述：

  二丁基二氮烯 在 盐酸 作用下， 生成 Butyraldehyd-butylhydrazon
  参考文献：
  名称：

  Ohme,R.; Preuschhof,H., Justus Liebigs Annalen der Chemie, 1968, vol. 713, p. 74 - 86

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二-N-丁基肼 在 sodium hydroxide 、 sodium hypochlorite 作用下， 生成 二丁基二氮烯
  参考文献：
  名称：

  Ohme,R.; Preuschhof,H., Justus Liebigs Annalen der Chemie, 1968, vol. 713, p. 74 - 86

  摘要：

  DOI：

文献信息

• Novel Syntheses of Bis(trialkylsilyl)amines by Reductive Trialkylsilylation of Azo Compounds
  作者：Mitsuo Kira、Satoshi Nagai、Mitsushi Nishimura、Hideki Sakurai

  DOI：10.1246/cl.1987.153

  日期：1987.1.5

  Reduction of azo compounds with a system of a trialkylchlorosilane and lithium has been found to afford bis(trialkylsilyl)amines in the presence of a transition metal halide as a catalyst in THF. The reaction course was significantly modified by using t-butyldimethylchlorosilane as a trialkylchlorosilane.

  已经发现，在作为催化剂的 THF 中的过渡金属卤化物存在下，用三烷基氯硅烷和锂的系统还原偶氮化合物可得到双（三烷基甲硅烷基）胺。通过使用叔丁基二甲基氯硅烷作为三烷基氯硅烷显着改变了反应过程。
• Nitrones from addition of benzyl and allyl Grignard reagents to alkyl nitro compounds: chemo-, regio-, and stereoselectivity of the reaction
  作者：Giuseppe Bartoli、Enrico Marcantoni、Marino Petrini

  DOI：10.1021/jo00048a012

  日期：1992.10

  Reaction of allyl and benzyl Grignard reagents with functionalized nitroalkanes affords nitrones in good yield. This process shows considerable chemoselectivity; carbonyl groups and other highly reactive electrophilic functions are unaffected by the reaction conditions (THF, -70-degrees-C). A mixture of regioisomers 4 and 5 is usually obtained, and the product distribution depends on the nature of the alkyl framework. An intermediate 3 is postulated, and the isomeric pair of nitrones arises, very likely through a selective syn elimination. Alpha-substituted alkyl chains give mostly conjugated products 4 while unbranched chains afford predominantly the nonconjugated nitrones 5. The 4/5 ratio can be strongly modified by using a proton source of suitable strength; trichloroacetic acid produces 4 exclusively in the reaction of nitroethane with benzyl Grignard, while 2,6-dimethylphenol affords completely the nonconjugated nitrone 5. The stereochemistry of the double bond is affected by the nature of the reagent used. Benzyl Grignard gives only Z nitrones 4 and 5; 2-butenylmagnesium chloride gives nonconjugated Z nitrones and a predominance of E isomer in the conjugated nitrone 5.
• Synthesis of Azoalkanes
  作者：J. W. TIMBERLAKE、M. L. HODGES、K. BETTERTON

  DOI：10.1055/s-1972-21965

  日期：——
• Meesters, A. C. M.; Rueerger, H.; Rajeswari, K., Canadian Journal of Chemistry, 1981, vol. 59, p. 264 - 268
  作者：Meesters, A. C. M.、Rueerger, H.、Rajeswari, K.、Benn, M. H.

  DOI：——

  日期：——
• The heat of oxidation of 1,2-di-n-butylhydrazine to azo-n-butane
  作者：Paul S. Engel、Walter H. Owens、Chengrong Wang

  DOI：10.1021/j100142a036

  日期：1993.10

  1,2-Di-n-butylhydrazine in hexane solution has been oxidized to azo-n-butane with oxygen and Pd/C catalyst and with red mercuric oxide. Both methods led to the same calculated heat of hydrogenation (DELTAH(H)) of the azo group in hexane, -1 6.4 +/- 0.3 kcal/mol. This value is 10.6 kcal/mol less exothermic than the DELTAH(H) of carbon-carbon double bonds.